Physical Chemistry of Gas-Liquid Interfaces

Physical Chemistry of Gas-Liquid Interfaces
Author: Jennifer A. Faust
Publisher: Elsevier
Total Pages: 0
Release: 2018-06-04
Genre: Science
ISBN: 9780128136416

Physical Chemistry of Gas-Liquid Interfaces, the first volume in the Developments in Physical & Theoretical Chemistry series, addresses the physical chemistry of gas transport and reactions across liquid surfaces. Gas-liquid interfaces are all around us, especially within atmospheric systems such as sea spry aerosols, cloud droplets, and the surface of the ocean. Because the reaction environment at liquid surfaces is completely unlike bulk gas or bulk liquid, chemists must readjust their conceptual framework when entering this field. This book provides the necessary background in thermodynamics and computational and experimental techniques for scientists to obtain a thorough understanding of the physical chemistry of liquid surfaces in complex, real-world environments.

Liquid Surfaces and Interfaces

Liquid Surfaces and Interfaces
Author: Peter S. Pershan
Publisher: Cambridge University Press
Total Pages: 335
Release: 2012-08-02
Genre: Science
ISBN: 0521814014

A practical guide for graduate students and researchers on all aspects of x-ray scattering experiments on liquid surfaces and interfaces.

Vapor-Liquid Interfaces, Bubbles and Droplets

Vapor-Liquid Interfaces, Bubbles and Droplets
Author: Shigeo Fujikawa
Publisher: Springer Science & Business Media
Total Pages: 235
Release: 2011-04-16
Genre: Technology & Engineering
ISBN: 3642180388

Physically correct boundary conditions on vapor-liquid interfaces are essential in order to make an analysis of flows of a liquid including bubbles or of a gas including droplets. Suitable boundary conditions do not exist at the present time. This book is concerned with the kinetic boundary condition for both the plane and curved vapor-liquid interfaces, and the fluid dynamics boundary condition for Navier-Stokes(fluid dynamics) equations. The kinetic boundary condition is formulated on the basis of molecular dynamics simulations and the fluid dynamics boundary condition is derived by a perturbation analysis of Gaussian-BGK Boltzmann equation applicable to polyatomic gases. The fluid dynamics boundary condition is applied to actual flow problems of bubbles in a liquid and droplets in a gas.

Non-Equilibrium Phenomena near Vapor-Liquid Interfaces

Non-Equilibrium Phenomena near Vapor-Liquid Interfaces
Author: Alexei Kryukov
Publisher: Springer Science & Business Media
Total Pages: 59
Release: 2013-03-28
Genre: Science
ISBN: 3319000837

This book presents information on the development of a non-equilibrium approach to the study of heat and mass transfer problems using vapor-liquid interfaces, and demonstrates its application to a broad range of problems. In the process, the following peculiarities become apparent: 1. At vapor condensation on the interface from gas-vapor mixture, non-condensable components can lock up the interface surface and condensation stops completely. 2. At the evolution of vapor film on the heater in superfluid helium (He-II), the boiling mass flux density from the vapor-liquid interface is effectively zero at the macroscopic scale. 3. In problems concerning the motion of He-II bridges inside capillaries filled by vapor, in the presence of axial heat flux the He-II bridge cannot move from the heater as would a traditional liquid, but in the opposite direction instead. Thus the heater attracts the superfluid helium bridge. 4. The shape of liquid-vapor interface at film boiling on the axis-symmetric heaters immersed in liquid greatly depends on heat flux in the interface. Thus a new type of hydrostatic problems appears when in contrast to traditional statements the shape of the liquid-vapor interface has a complex profile with a point of inflection and a smooth exit on a free liquid surface.

Interfaces in Materials

Interfaces in Materials
Author: James M. Howe
Publisher: Wiley-Interscience
Total Pages: 552
Release: 1997-02-27
Genre: Science
ISBN:

A thorough exploration of the atomic structures and properties of the essential engineering interfaces—an invaluable resource for students, teachers, and professionals The most up-to-date, accessible guide to solid-vapor, solid-liquid, and solid-solid phase transformations, this innovative book contains the only unified treatment of these three central engineering interfaces. Employing a simple nearest-neighbor broken-bond model, Interfaces in Materials focuses on metal alloys in a straightforward approach that can be easily extended to all types of interfaces and materials. Enhanced with nearly 300 illustrations, along with extensive references and suggestions for further reading, this book provides: A simple, cohesive approach to understanding the atomic structure and properties of interfaces formed between solid, liquid, and vapor phases Self-contained discussions of each interface—allowing separate study of each phase transformation A comparative look at the different interfaces, including atomic structure and crystallography; anisotropy, roughening, and melting; interfacial stability and segregation; continuous and ledge growth models; and atomistic modeling An analysis of nearest-neighbor broken-bond results against thermodynamic and kinetic descriptions of the interfaces Problem sets at the end of each chapter, emphasizing the key concepts detailed in the text Spanning the fields of chemical, electrical and computer engineering, materials science, solid-state physics, and microscopy, Interfaces in Materials bridges a major gap in the literature of surface and interface science.

Physical Chemistry of Gas-Liquid Interfaces

Physical Chemistry of Gas-Liquid Interfaces
Author: Jennifer A. Faust
Publisher: Elsevier
Total Pages: 492
Release: 2018-05-31
Genre: Science
ISBN: 0128136421

Physical Chemistry of Gas-Liquid Interfaces, the first volume in the Developments in Physical & Theoretical Chemistry series, addresses the physical chemistry of gas transport and reactions across liquid surfaces. Gas–liquid interfaces are all around us, especially within atmospheric systems such as sea spry aerosols, cloud droplets, and the surface of the ocean. Because the reaction environment at liquid surfaces is completely unlike bulk gas or bulk liquid, chemists must readjust their conceptual framework when entering this field. This book provides the necessary background in thermodynamics and computational and experimental techniques for scientists to obtain a thorough understanding of the physical chemistry of liquid surfaces in complex, real-world environments. - 2019 PROSE Awards - Winner: Category: Chemistry and Physics: Association of American Publishers - Provides an interdisciplinary view of the chemical dynamics of liquid surfaces, making the content of specific use to physical chemists and atmospheric scientists - Features 100 figures and illustrations to underscore key concepts and aid in retention for young scientists in industry and graduate students in the classroom - Helps scientists who are transitioning to this field by offering the appropriate thermodynamic background and surveying the current state of research

Gas Transfer at Water Surfaces

Gas Transfer at Water Surfaces
Author: W. Brutsaert
Publisher: Springer Science & Business Media
Total Pages: 666
Release: 1983-12-31
Genre: Science
ISBN: 9789027716972

The transfer across the surface of environmental waters is of interest as an important phase in the geophysical and natural biochemical cycles of numer ous substances; indeed it governs the transition, one way or the other, be tween the dissolved state in the water and the gaseous state in the atmo sphere. Especially with increasing population and industrialization, gas transfer at water surfaces has become a critical factor in the understanding of the various pathways of wastes in the environment and of their engineering management. This interfacial mass transfer is, by its very nature, highly complex. The air and the water are usually in turbulent motion, and the interface be tween them is irregular, and disturbed by waves, sometimes accompanied by breaking, spray and bubble formation. Thus the transfer involves a wide variety of physical phenomena occurring over a wide range of scales. As a consequence, scientists and engineers from diverse disciplines and problem areas, have approached the problem, often with greatly differing analytical and experimental techniques and methodologies.

Physics and Chemistry of Interfaces

Physics and Chemistry of Interfaces
Author: Hans-Jürgen Butt
Publisher: John Wiley & Sons
Total Pages: 485
Release: 2023-02-07
Genre: Science
ISBN: 3527836160

Physics and Chemistry of Interfaces Comprehensive textbook on the interdisciplinary field of interface science, fully updated with new content on wetting, spectroscopy, and coatings Physics and Chemistry of Interfaces provides a comprehensive introduction to the field of surface and interface science, focusing on essential concepts rather than specific details, and on intuitive understanding rather than convoluted math. Numerous high-end applications from surface technology, biotechnology, and microelectronics are included to illustrate and help readers easily comprehend basic concepts. The new edition contains an increased number of problems with detailed, worked solutions, making it ideal as a self-study resource. In topic coverage, the highly qualified authors take a balanced approach, discussing advanced interface phenomena in detail while remaining comprehensible. Chapter summaries with the most important equations, facts, and phenomena are included to aid the reader in information retention. A few of the sample topics included in Physics and Chemistry of Interfaces are as follows: Liquid surfaces, covering microscopic picture of a liquid surface, surface tension, the equation of Young and Laplace, and curved liquid surfaces Thermodynamics of interfaces, covering surface excess, internal energy and Helmholtz energy, equilibrium conditions, and interfacial excess energies Charged interfaces and the electric double layer, covering planar surfaces, the Grahame equation, and limitations of the Poisson-Boltzmann theory Surface forces, covering Van der Waals forces between molecules, macroscopic calculations, the Derjaguin approximation, and disjoining pressure Physics and Chemistry of Interfaces is a complete reference on the subject, aimed at advanced students (and their instructors) in physics, material science, chemistry, and engineering. Researchers requiring background knowledge on surface and interface science will also benefit from the accessible yet in-depth coverage of the text.