The Synthesis Characterization And Study Of Transition Metal Complexes For The Oxidation And Activation Of Hydrocarbons
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Author | : A.E. Shilov |
Publisher | : Springer Science & Business Media |
Total Pages | : 556 |
Release | : 2001-11-30 |
Genre | : Science |
ISBN | : 9781402004209 |
hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Author | : Fred Basolo |
Publisher | : Springer Science & Business Media |
Total Pages | : 204 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 1461345774 |
This conference on Catalysis was held under the auspices ofthe NATO Science Committee as part of its continuing effort to promote the useful progress of science through international cooperation. The Science Committee Conferences are deliberately designed and struc tured to focus expert attention on what is not known, rather than what is known. The participants are carefully selected to bring together a variety of complementary viewpoints. Through intensive group discussion, they seek to reach agreement on conclusions and recommendations for future research which will be of value to the scientific community. We believe that the endeavour has been particularly successful in the pre sent case. Some twenty-five papers, either in the form of reprints or specially written reviews were contributed by the participants for advance circulation, to outline the state-of-the art in the three areas ofheterogeneous, homogeneous and metalloenzyme catalysis and to focus attention on key problems. The availability of this background material precluded the need for lengthy intro ductory presentations and permitted rapid initiation of interdisciplinary discussions. All participants gave generously and enthusiastically of their expertise and effort during the week of the meeting, of ten long past normal bedtime hours, and we extend to them our deep gratitude.
Author | : |
Publisher | : |
Total Pages | : 788 |
Release | : 2004 |
Genre | : Dissertations, Academic |
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Publisher | : |
Total Pages | : 508 |
Release | : 1992-10 |
Genre | : Power resources |
ISBN | : |
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Publisher | : |
Total Pages | : 848 |
Release | : 1999 |
Genre | : Dissertation abstracts |
ISBN | : |
Author | : Walter Kaminsky |
Publisher | : Wiley-VCH |
Total Pages | : 0 |
Release | : 2006-08-18 |
Genre | : Technology & Engineering |
ISBN | : 9783527317424 |
With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.
Author | : H.K. Beyer |
Publisher | : Elsevier |
Total Pages | : 811 |
Release | : 1995-05-19 |
Genre | : Technology & Engineering |
ISBN | : 0080544673 |
ZEOCAT '95 is the eleventh in the series of symposia devoted to special fields of zeolite chemistry. Six plenary lectures, forty oral and forty-two poster presentations were included in the program. The accepted papers cover every aspect of catalysis on microporous materials. A significant number of the contributions describe the synthesis, modification, instrumental and chemical characterisation of zeolites and other micro- and mesoporous materials. Catalytic reactions involve hydrocarbon cracking, nucleophilic aromatic substitution, methanol to hydrocarbon conversion, hydration of acetylene, various alkylation reactions, redox transformations, Claisen rearrangement, etc.
Author | : Armando J. L. Pombeiro |
Publisher | : John Wiley & Sons |
Total Pages | : 680 |
Release | : 2019-03-11 |
Genre | : Science |
ISBN | : 111937880X |
Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.
Author | : |
Publisher | : |
Total Pages | : 668 |
Release | : 1983 |
Genre | : Power resources |
ISBN | : |
Author | : |
Publisher | : |
Total Pages | : 748 |
Release | : 1977 |
Genre | : Fossil fuels |
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