The Chemistry of Plutonium

The Chemistry of Plutonium
Author: Jesse M. Cleveland
Publisher:
Total Pages: 688
Release: 1979
Genre: Science
ISBN:

Dr. Cleveland's monographs is a comprehensive and authoritative treatise on the theory and practice of plutonium chemistry and is of value to all chemists interested in the chemistry of the actinide elements.

Some Observations on the Basic Chemistry of Plutonium

Some Observations on the Basic Chemistry of Plutonium
Author: E. S. Maxwell
Publisher:
Total Pages: 8
Release: 1948
Genre: Plutonium
ISBN:

On prolonged heating in dilute nitric acid (0.5M to 6.8M) a considerable amount of Pu(+4) is oxidized to Pu(+8). Precipitation of the plus three plutonium oxalate is complete in fifteen minutes. Oxidation of Pu(+4) to Pu(+8) by bromine is quantitative at 105 deg C after 1/2 hour; at 50 deg C the rate of oxidation is slow, but measurable. At room temperature the rate is too slow to measure. A method of converting PuC13 to Pu(NO3)4 is given. A solubility of NaPuO2Ac3 increases with temperature the value at 25 deg C being 19.5 g/iiter and that at 95 deg C, 37.5 g/liter. Supersaturation was observed on slow cooling of a saturated solution. p2.

Uranium · Plutonium Transplutonic Elements

Uranium · Plutonium Transplutonic Elements
Author: Harold C. Hodge
Publisher: Springer Science & Business Media
Total Pages: 1037
Release: 2013-06-29
Genre: Medical
ISBN: 3642655513

More than a year ago the three editors sat down at a table and worked out a set of six chapter headings which they believed might serve, in turn, for each of the three sections of this handbook. (The reader will note a similarity in order of presentation and in emphasis.) However, as our editorial plans progressed it became apparent that for each element and for the element group, there were one or two special topics appropiate for that section alone. Accordingly, in the section on uranium the common pattern holds for Chaps. 1 through 6 which include: an introduction (Chap. 1), a discussion of the physical and chemical properties (Chap. 2), experimental data on animals (Chap. 3), ex perimental data on man (Chap. 4), the rationale and development of air con centration limits to control industrial worker exposure (Chap. 5), and the prac tical problems of applying such limits in the uranium industry (Chap. 6). Chap. 7 entitled "Uranium Mining Hazards" is the subject category which is special for uranium; the chapter brings up to date the account of an important occupational hazard which was first noted by GEORGIUS AGRICOLA (1490-1555).