Sulfur Oxidation And Contrail Precursor Chemistry
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Sulfur Oxidation and Contrail Precursor Chemistry
Author | : National Aeronautics and Space Administration (NASA) |
Publisher | : Createspace Independent Publishing Platform |
Total Pages | : 34 |
Release | : 2018-06-11 |
Genre | : |
ISBN | : 9781721009893 |
Sulfuric acid (H2SO4), formed in commercial aircraft operations via fuel-S (goes to) SO2 (goes to) SO3 (goes to) H2SO4 plays an important role in the formation of contrails. It is believed that the first step occurs inside the combustor, the second step in the engine exit nozzle, and the third step in the exhaust plume. Thus, measurements of the sulfur oxidation rates are critical to the understanding of contrail formation. Field measurements of contrails formed behind commercial aircraft indicate that significantly greater conversion of fuel-bound sulfur to sulfate aerosol occurs than can be explained by our current knowledge of contrail physics and chemistry. The conversion of sulfur from S(IV) to S(VI) oxidation state, required for sulfate aerosol formation, is thermodynamically favored for the conditions that exist within jet engines but is kinetically disfavored. The principal reaction pathway is O+SO2+M (goes to) SO3+M. The rates of this reaction have never been measured in the temperature and pressure regimes available to aircraft operation. In the first year (FY02) of this project, we performed a series of experiments to elucidate the rate information for the O+SO2+M (goes to) SO3+M reaction. The work performed is described following the proposed work plan. Because we used the H2/O2 system for an O-atom source and rate coefficients were obtained via computer simulation, construction of a reaction mechanism and either recalculation or estimation of thermodynamic properties of H(x)SO(y) species are described first.DeWitt, Kenneth J.Glenn Research CenterCONTRAILS; SULFUR DIOXIDES; OXIDATION; REACTION KINETICS; COMBUSTION CHEMISTRY; COMPUTERIZED SIMULATION; EXHAUST GASES; JET ENGINES; TEMPERATURE DEPENDENCE; COMMERCIAL AIRCRAFT; SENSITIVITY ANALYSIS; THERMODYNAMIC PROPERTIES
Climate Intervention
Author | : National Research Council |
Publisher | : National Academies Press |
Total Pages | : 270 |
Release | : 2015-06-23 |
Genre | : Science |
ISBN | : 0309314852 |
The growing problem of changing environmental conditions caused by climate destabilization is well recognized as one of the defining issues of our time. The root problem is greenhouse gas emissions, and the fundamental solution is curbing those emissions. Climate geoengineering has often been considered to be a "last-ditch" response to climate change, to be used only if climate change damage should produce extreme hardship. Although the likelihood of eventually needing to resort to these efforts grows with every year of inaction on emissions control, there is a lack of information on these ways of potentially intervening in the climate system. As one of a two-book report, this volume of Climate Intervention discusses albedo modification - changing the fraction of incoming solar radiation that reaches the surface. This approach would deliberately modify the energy budget of Earth to produce a cooling designed to compensate for some of the effects of warming associated with greenhouse gas increases. The prospect of large-scale albedo modification raises political and governance issues at national and global levels, as well as ethical concerns. Climate Intervention: Reflecting Sunlight to Cool Earth discusses some of the social, political, and legal issues surrounding these proposed techniques. It is far easier to modify Earth's albedo than to determine whether it should be done or what the consequences might be of such an action. One serious concern is that such an action could be unilaterally undertaken by a small nation or smaller entity for its own benefit without international sanction and regardless of international consequences. Transparency in discussing this subject is critical. In the spirit of that transparency, Climate Intervention: Reflecting Sunlight to Cool Earth was based on peer-reviewed literature and the judgments of the authoring committee; no new research was done as part of this study and all data and information used are from entirely open sources. By helping to bring light to this topic area, this book will help leaders to be far more knowledgeable about the consequences of albedo modification approaches before they face a decision whether or not to use them.
Green Aviation
Author | : Ramesh Agarwal |
Publisher | : John Wiley & Sons |
Total Pages | : 536 |
Release | : 2016-09-20 |
Genre | : Technology & Engineering |
ISBN | : 1118866509 |
Green Aviation is the first authoritative overview of both engineering and operational measures to mitigate the environmental impact of aviation. It addresses the current status of measures to reduce the environmental impact of air travel. The chapters cover such items as: Engineering and technology-related subjects (aerodynamics, engines, fuels, structures, etc.), Operations (air traffic management and infrastructure) Policy and regulatory aspects regarding atmospheric and noise pollution. With contributions from leading experts, this volume is intended to be a valuable addition, and useful resource, for aerospace manufacturers and suppliers, governmental and industrial aerospace research establishments, airline and aviation industries, university engineering and science departments, and industry analysts, consultants, and researchers.
Aviation and the Global Atmosphere
Author | : Joyce E. Penner |
Publisher | : Cambridge University Press |
Total Pages | : 392 |
Release | : 1999-06-28 |
Genre | : Science |
ISBN | : 9780521663007 |
This Intergovernmental Panel on Climate Change Special Report is the most comprehensive assessment available on the effects of aviation on the global atmosphere. The report considers all the gases and particles emitted by aircraft that modify the chemical properties of the atmosphere, leading to changes in radiative properties and climate change, and modification of the ozone layer, leading to changes in ultraviolet radiation reaching the Earth. This volume provides accurate, unbiased, policy-relevant information and is designed to serve the aviation industry and the expert and policymaking communities.
Stable Isotopes
Author | : International Council of Scientific Unions. Scientific Committee on Problems of the Environment |
Publisher | : |
Total Pages | : 480 |
Release | : 1991-08-15 |
Genre | : Science |
ISBN | : |
This synthesis draws on the results of a major international scientific workshop held in Pushchino (Moscow Region) in summer 1983, organized jointly by the United Nations Environment Program (UNEP) and SCOPE, with major financial support from UNEP.
Radiative Forcing of Climate Change
Author | : National Research Council |
Publisher | : National Academies Press |
Total Pages | : 222 |
Release | : 2005-03-25 |
Genre | : Science |
ISBN | : 0309133505 |
Changes in climate are driven by natural and human-induced perturbations of the Earth's energy balance. These climate drivers or "forcings" include variations in greenhouse gases, aerosols, land use, and the amount of energy Earth receives from the Sun. Although climate throughout Earth's history has varied from "snowball" conditions with global ice cover to "hothouse" conditions when glaciers all but disappeared, the climate over the past 10,000 years has been remarkably stable and favorable to human civilization. Increasing evidence points to a large human impact on global climate over the past century. The report reviews current knowledge of climate forcings and recommends critical research needed to improve understanding. Whereas emphasis to date has been on how these climate forcings affect global mean temperature, the report finds that regional variation and climate impacts other than temperature deserve increased attention.