Isotope Separation by Selective Dissociative Electron Attachment. Final Technical Report

Isotope Separation by Selective Dissociative Electron Attachment. Final Technical Report
Author:
Publisher:
Total Pages:
Release: 1978
Genre:
ISBN:

A description of work performed on isotopically selective, photo-enhanced production of SF−5 from SF6 is included. The primary task under the present contract was the construction of a second-generation experimental apparatus for the study of the simultaneous interaction of electrons, photons, and molecules. The collinear electron and laser beam arrangement employed previously has been retained, but a new electron gun design has been adopted which avoids the troublesome interaction of the laser beam with the electron gun filament. The system has been designed for maximum compatibility with aggressive gases such as UF6. Details of the design and construction of this system are given. Proposals for future work include work on SF6 and UF6.

Isotope Separation by Photoselective Dissociative Electron Capture

Isotope Separation by Photoselective Dissociative Electron Capture
Author:
Publisher:
Total Pages:
Release: 1978
Genre:
ISBN:

A method of separating isotopes based on photoselective electron capture dissociation of molecules having an electron capture cross section dependence on the vibrational state of the molecule. A molecular isotope source material is irradiated to selectively excite those molecules containing a desired isotope to a predetermined vibrational state having associated therewith an electron capture energy region substantially non-overlapping with the electron capture energy ranges associated with the lowest vibration states of the molecules. The isotope source is also subjected to electrons having an energy corresponding to the non-overlapping electron capture region whereby the selectively excited molecules preferentially capture electrons and dissociate into negative ions and neutrals. The desired isotope may be in the negative ion product or in the neutral product depending upon the mechanism of dissociation of the particular isotope source used. The dissociation product enriched in the desired isotope is then separated from the reaction system by conventional means. Specifically, .sup. 235 UF.sub. 6 is separated from a UF.sub. 6 mixture by selective excitation followed by dissociative electron capture into .sup. 235 UF.sub. 5 - and F.

Fast Reactions in Energetic Systems

Fast Reactions in Energetic Systems
Author: Christos Capellos
Publisher: Springer Science & Business Media
Total Pages: 747
Release: 2012-12-06
Genre: Science
ISBN: 9400985118

This book presents the formal lectures and contributed papers given at the NATO Advanced Study Institute on Fast Reactions in Energetic Systems, which took place in Preveza, Greece, during the period 6-19 July 1980. The material describes experimental observations and the more advanced theoretical aspects of certain types of fast reactions and energy or charge transfer processes which are usually complete 6 12 in periods of 10- - 10- seconds. Furthermore, it discusses the role of macroscopic and molecular processes in the ignition, combustion, deflagration, and detonation of solid, liquid, and gaseous chemical systems. Various papers deal with the ability of molecules to absorb and transmit the different forms of energy provided by shock, light, thermal, or electron pulses, and to contribute to the propagation of reactions under high temperatures and pressures. The role of energy pumped or transferred to electronic or vibrational states is discussed in terms of excitation, ionization, bond scission, and the formation of free radicals. The dynamics and reactivity of ionic species, electronically and vibrationally excited states, and free radicals are described for various gaseous, liquid, and solid systems. The proceedings include presentations of theoretical and experimental techniques to describe and observe the phenomena.

ERDA Energy Research Abstracts

ERDA Energy Research Abstracts
Author: United States. Energy Research and Development Administration. Technical Information Center
Publisher:
Total Pages: 588
Release: 1976
Genre: Force and energy
ISBN: