Soft-Matter Characterization

Soft-Matter Characterization
Author: Redouane Borsali
Publisher: Springer Science & Business Media
Total Pages: 1490
Release: 2008-07-28
Genre: Science
ISBN: 140204464X

This 2-volume set includes extensive discussions of scattering techniques (light, neutron and X-ray) and related fluctuation and grating techniques that are at the forefront of this field. Most of the scattering techniques are Fourier space techniques. Recent advances have seen the development of powerful direct imaging methods such as atomic force microscopy and scanning probe microscopy. In addition, techniques that can be used to manipulate soft matter on the nanometer scale are also in rapid development. These include the scanning probe microscopy technique mentioned above as well as optical and magnetic tweezers.

Block Copolymers in Solution

Block Copolymers in Solution
Author: Ian W. Hamley
Publisher: John Wiley & Sons
Total Pages: 300
Release: 2005-12-13
Genre: Technology & Engineering
ISBN: 0470016973

This unique text discusses the solution self-assembly of block copolymers and covers all aspects from basic physical chemistry to applications in soft nanotechnology. Recent advances have enabled the preparation of new materials with novel self-assembling structures, functionality and responsiveness and there have also been concomitant advances in theory and modelling. The present text covers the principles of self-assembly in both dilute and concentrated solution, for example micellization and mesophase formation, etc., in chapters 2 and 3 respectively. Chapter 4 covers polyelectrolyte block copolymers - these materials are attracting significant attention from researchers and a solid basis for understanding their physical chemistry is emerging, and this is discussed. The next chapter discusses adsorption of block copolymers from solution at liquid and solid interfaces. The concluding chapter presents a discussion of selected applications, focussing on several important new concepts. The book is aimed at researchers in polymer science as well as industrial scientists involved in the polymer and coatings industries. It will also be of interest to scientists working in soft matter self-assembly and self-organizing polymers.

Processing, Structure and Properties of Block Copolymers

Processing, Structure and Properties of Block Copolymers
Author: M.J. Folkes
Publisher: Springer Science & Business Media
Total Pages: 219
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9400949367

Block copolymers represent an important class of multi-phase material, which have received very widespread attention, particularly since their successful commercial development in the mid-1960s. Much of the interest in these polymers has arisen because of their rather remarkable micro phase morphology and, hence, they have been the subject of extensive microstructural examination. In many respects, the quest for a comprehensive interpretation of their structure, both theoretically and experimentally, has not been generally matched by a corresponding enthusiasm for developing structure/property relationships in the context of their commercial application. Indeed, it has been left largely to the industrial companies involved in the development and utilization of these materials to fulfil this latter role. While it is generally disappointing that a much greater synergism does not exist between science and technology, it is especially sad in the case of block copolymers. Thus these materials offer an almost unique opportunity for the application of fundamental structural and property data to the interpretation of the properties of generally processed artefacts. Accordingly, in this book, the editor has drawn together an eminent group of research workers, with the specific intention of highlighting some of those aspects of the science and technology of block copolymers that are potentially important if further advances are to be made either in material formulation or utilization. For example, special consideration is given to the relationship between the flow properties of block copo lymers and their microstructure.

Amphiphilic Block Copolymers

Amphiphilic Block Copolymers
Author: P. Alexandridis
Publisher: Elsevier
Total Pages: 449
Release: 2000-10-18
Genre: Science
ISBN: 0080527108

It is the belief of the editors of this book that the recognition of block copolymers as being amphiphilic molecules and sharing common features with other well-studied amphiphiles will prove beneficial to both the surfactant and the polymer communities. An aim of this book is to bridge the two communities and cross-fertilise the different fields. To this end, leading researchers in the field of amphiphilic block copolymer self-assembly, some having a background in surfactant chemistry, and others with polymer physics roots, have agreed to join forces and contribute to this book.The book consists of four entities. The first part discusses theoretical considerations behind the block copolymer self-assembly in solution and in the melt. The second part provides case studies of self-assembly in different classes of block copolymers (e.g., polyethers, polyelectrolytes) and in different environments (e.g., in water, in non-aqueous solvents, or in the absence of solvents). The third part presents experimental tools, ranging from static (e.g., small angle neutron scattering) to dynamic (e.g., rheology), which can prove valuable in the characterization of block copolymer self-assemblies. The fourth part offers a sampling of current applications of block copolymers in, e.g., formulations, pharmaceutics, and separations, applications which are based on the unique self-assembly properties of block copolymers.

Handbook of Multiphase Polymer Systems

Handbook of Multiphase Polymer Systems
Author: Abderrahim Boudenne
Publisher: John Wiley & Sons
Total Pages: 1322
Release: 2011-06-09
Genre: Technology & Engineering
ISBN: 1119972884

Multiphase polymeric systems include a wide range of materials such as composites, blends, alloys, gels, and interpenetrating polymer networks (IPNs). A one-stop reference on multiphase polymer systems, this book fully covers the preparation, properties, and applications of advanced multiphase systems from macro to nano scales. Edited by well-respected academics in the field of multiphase polymer systems, the book includes contributions from leading international experts. An essential resource for plastic and rubber technologists, filler specialists and researchers in fields studying thermal and electrical properties.

Structural Studies of Polymers by Solution Nmr

Structural Studies of Polymers by Solution Nmr
Author: H.N. Cheng
Publisher: iSmithers Rapra Publishing
Total Pages: 168
Release: 2001
Genre: Science
ISBN: 9781859572481

Solution-state NMR spectroscopy is generally regarded as the premier technique to characterise polymer structure. This report provides a timely review of the developments in the NMR of polymers in solution in the past few years. An additional indexed section containing several hundred abstracts from the Polymer Library gives useful references for further reading.

Encyclopedia of Polymeric Nanomaterials

Encyclopedia of Polymeric Nanomaterials
Author: Shiro Kobayashi
Publisher: Springer
Total Pages: 0
Release: 2015-06-12
Genre: Technology & Engineering
ISBN: 9783642296475

Over the last few years, nanoscience and nanotechnology have been the focus of significant research attention, both from academia and industry. This sustained focus has in-turn driven the interdisciplinary field of material science research to the forefront of scientific inquiry through the creation and study of nanomaterials. Nanomaterials play an important role in the development of new materials as they can be used to influence and control physical properties and specific characteristics of other materials. Nanostructured materials that have been created include nanoparticles, nanocapsules, nanoporous materials, polymer multi-layers to name a few. These are increasingly used across applications as diverse as automotive, environment, energy, catalysis, biomedical, pharmaceutical, and polymer industries. The Encyclopedia of Polymeric Nanomaterials (EPN) intends to be a comprehensive reference work on this dynamic field studying nanomaterials within the context of the relationship between molecular structure and the properties of polymeric materials. Alphabetically organized as an encyclopedic Major Reference Work, EPN will cover the subject along multiple classification axes represented by name, source, properties, function, and structures or even processes, applications and usage. The underlying themes of the encyclopedia has been carefully identified to be based not just on material-based and function-based representation but also on structure- and process-based representation. The encyclopedia will have an exclusive focus on polymeric nanomaterials (for e.g., nanoceramics, nanocomposites, quantum dots, thin films) and will be a first of its kind work to have such an organization providing an overview to the concepts, practices and applications in the field. The encyclopedia intends to cover research and development work ranging from the fundamental mechanisms used for the fabrication of polymeric nanomaterials to their advanced application across multiple industries.

Science and Technology of Rubber

Science and Technology of Rubber
Author: Frederick R. Eirich
Publisher: Elsevier
Total Pages: 686
Release: 2012-12-02
Genre: Technology & Engineering
ISBN: 0323138799

Science and Technology of Rubber covers the most important aspects of rubber science and technology, from synthesis and structure to elasticity and flow, blending, filling, and cross-linking. Polymerization and copolymerization, the rheological behavior of unvulcanized rubber, vulcanization, reinforcement of elastomers by particulate fillers, and the chemical modification of polymers are also discussed. This book is comprised of 14 chapters; the first ten of which take the reader from an introduction through synthesis characterization, mechanical behavior, and flow to the major processing steps of filling, compounding, and vulcanization and to the theories and measurement of elastomeric performance, leaning strongly on the ""materials"" approach. The next three chapters deal with blended, modified, and thermoplastic elastomers, touching on topics such as polymer esterification, etherification, hydrolysis, and hydrogenation as well as the influence of blending on the properties of elastomer/plastic blends, especially impact strength and crack resistance. The book concludes with a chapter on tire manufacture and engineering, with emphasis on the geometric, structural, and chemical aspects of tire. This book will be of vital interest to students, practitioners, and research and development managers, as well as to anyone interested in the unusual chemistry and physics and the outstanding properties and usefulness of elastomers.

Block Copolymers

Block Copolymers
Author: Nikos Hadjichristidis
Publisher: John Wiley & Sons
Total Pages: 445
Release: 2003-04-28
Genre: Technology & Engineering
ISBN: 0471461342

Polymers may be classified as either homopolymers, consisting of one single repeating unit, or copolymers, consisting of two or more distinct repeating units. Block copolymers contain long contiguous blocks of two or more repeating units in the same polymer chain. Covering one of the hottest topics in polymer chemistry, Block Copolymers provides a coherent overview of the synthetic routes, physical properties, and applications of block copolymers. This pioneering text provides not only a guideline for developing synthetic strategies for creating block copolymers with defined characteristics, but also a key to the relationship between the physical properties of block copolymers and the structure and dynamics of materials. Covering features of the chemistry and physics of block copolymers that are not found in comparable texts, Block Copolymers illustrates the structure-activity relationship of block copolymers and offers suggestions for the design of specific applications. Divided into five sections-Block Copolymers includes chapters on: * Block Copolymers by Chemical Modification of Precursor Polymers * Nonlinear Block Copolymers * Adsorption of Block Copolymers at Solid-Liquid Interfaces * Theory of Block Copolymer Segregation * Phase Transformation Kinetics * Block Copolymer Morphology * Block Copolymer Dynamics Polymer chemists, physicists, chemical engineers, and materials scientists, as well as graduate students in polymer science, will find Block Copolymers to be an invaluable text.