Spin State
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| Author | : Chris Moriarty |
| Publisher | : Spectra |
| Total Pages | : 642 |
| Release | : 2004-11-23 |
| Genre | : Fiction |
| ISBN | : 0553586246 |
From a stunning new voice in hard science fiction comes the thrilling story of one woman’s quest to wrest truth from chaos, love from violence, and reality from illusion in a post-human universe of emergent AIs, genetic constructs, and illegal wetware. . . . UN Peacekeeper Major Catherine Li has made thirty-seven faster-than-light jumps in her lifetime—and has probably forgotten more than most people remember. But that’s what backup hard drives are for. And Li should know; she’s been hacking her memory for fifteen years in order to pass as human. But no memory upgrade can prepare Li for what she finds on Compson’s World: a mining colony she once called home and to which she is sent after a botched raid puts her on the bad side of the powers that be. A dead physicist who just happens to be her cloned twin. A missing dataset that could change the interstellar balance of power and turn a cold war hot. And a mining “accident” that is starting to look more and more like murder. . . . Suddenly Li is chasing a killer in an alien world miles underground where everyone has a secret. And one wrong turn in streamspace, one misstep in the dark alleys of blackmarket tech and interstellar espionage, one risky hookup with an AI could literally blow her mind.
| Author | : Marcel Swart |
| Publisher | : John Wiley & Sons |
| Total Pages | : 500 |
| Release | : 2015-09-22 |
| Genre | : Science |
| ISBN | : 1118898281 |
It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.
| Author | : Marcel Swart |
| Publisher | : John Wiley & Sons |
| Total Pages | : 500 |
| Release | : 2015-12-14 |
| Genre | : Science |
| ISBN | : 1118898311 |
It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.
| Author | : Chris Moriarty |
| Publisher | : Spectra |
| Total Pages | : 610 |
| Release | : 2007-06-26 |
| Genre | : Fiction |
| ISBN | : 0553586254 |
In this stunning follow-up to the critically acclaimed novel Spin State, Chris Moriarty depicts a grim future in which the final frontier may well be extinction. For as far-flung planets are terraformed and Earth’s age-old conflicts are contracted out to AIs, humanity is losing the only war that counts: the war for survival. Call Arkady a clone with a conscience. Or call him a traitor. A member of the space-faring Syndicates, Arkady has defected to Israel with a hot commodity: a genetic weapon powerful enough to wipe out humanity. But Israel’s not buying it. They’re selling it—and Arkady—to the highest bidder. As the auction heats up, the Artificial Life Emancipation Front sends in Major Catherine Li. Already drummed out of the Peacekeepers for “war crimes,” Li has now literally hooked up with an AI who has lived many lifetimes and shunted through many bodies. And while they each have their own definition of victory, together they have only one chance at survival. . . .
| Author | : Jonathan Bain |
| Publisher | : Oxford University Press |
| Total Pages | : 208 |
| Release | : 2016-04-08 |
| Genre | : Science |
| ISBN | : 0191044555 |
This book seeks to answer the question "What explains CPT invariance and the spin-statistics connection?" These properties play foundational roles in relativistic quantum field theories (RQFTs), are supported by high-precision experiments, and figure into explanations of a wide range of phenomena, from antimatter, to the periodic table of the elements, to superconductors and superfluids. They can be derived in RQFTs by means of the famous CPT and Spin-Statistics theorems; but, the author argues, these theorems cannot be said to explain these properties, at least under standard philosophical accounts of scientific explanation. This is because there are multiple, in some cases incompatible, ways of deriving these theorems, and, secondly, because the theorems fail for the types of theories that underwrite the empirical evidence: non-relativistic quantum theories, and realistic interacting RQFTs. The goal of this book is to work towards an understanding of CPT invariance and the spin-statistics connection by first providing an analysis of the necessary and sufficient conditions for these properties, and second by advocating a particular account of explanation appropriate for this context.
| Author | : Christian Groß |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 123 |
| Release | : 2012-01-13 |
| Genre | : Science |
| ISBN | : 3642256368 |
Interferometry, the most precise measurement technique known today, exploits the wave-like nature of the atoms or photons in the interferometer. As expected from the laws of quantum mechanics, the granular, particle-like features of the individually independent atoms or photons are responsible for the precision limit, the shot noise limit. However this “classical” bound is not fundamental and it is the aim of quantum metrology to overcome it by employing entanglement among the particles. This work reports on the realization of spin-squeezed states suitable for atom interferometry. Spin squeezing was generated on the basis of motional and spin degrees of freedom, whereby the latter allowed the implementation of a full interferometer with quantum-enhanced precision.
| Author | : Malcolm H. Levitt |
| Publisher | : John Wiley & Sons |
| Total Pages | : 824 |
| Release | : 2013-05-20 |
| Genre | : Science |
| ISBN | : 1118681843 |
Spin Dynamics: Basics of Nuclear Magnetic Resonance, Second Edition is a comprehensive and modern introduction which focuses on those essential principles and concepts needed for a thorough understanding of the subject, rather than the practical aspects. The quantum theory of nuclear magnets is presented within a strong physical framework, supported by figures. The book assumes only a basic knowledge of complex numbers and matrices, and provides the reader with numerous worked examples and exercises to encourage understanding. With the explicit aim of carefully developing the subject from the beginning, the text starts with coverage of quarks and nucleons and progresses through to a detailed explanation of several important NMR experiments, including NMR imaging, COSY, NOESY and TROSY. Completely revised and updated, the Second Edition features new material on the properties and distributions of isotopes, chemical shift anisotropy and quadrupolar interactions, Pake patterns, spin echoes, slice selection in NMR imaging, and a complete new chapter on the NMR spectroscopy of quadrupolar nuclei. New appendices have been included on Euler angles, and coherence selection by field gradients. As in the first edition, all material is heavily supported by graphics, much of which is new to this edition. Written for undergraduates and postgraduate students taking a first course in NMR spectroscopy and for those needing an up-to-date account of the subject, this multi-disciplinary book will appeal to chemical, physical, material, life, medical, earth and environmental scientists. The detailed physical insights will also make the book of interest for experienced spectroscopists and NMR researchers. • An accessible and carefully written introduction, designed to help students to fully understand this complex and dynamic subject • Takes a multi-disciplinary approach, focusing on basic principles and concepts rather than the more practical aspects • Presents a strong pedagogical approach throughout, with emphasis placed on individual spins to aid understanding • Includes numerous worked examples, problems, further reading and additional notes Praise from the reviews of the First Edition: "This is an excellent book... that many teachers of NMR spectroscopy will cherish... It deserves to be a ‘classic’ among NMR spectroscopy texts." NMR IN BIOMEDICINE "I strongly recommend this book to everyone...it is probably the best modern comprehensive description of the subject." ANGEWANDTE CHEMIE, INTERNATIONAL EDITION
| Author | : Malcolm A. Halcrow |
| Publisher | : John Wiley & Sons |
| Total Pages | : 729 |
| Release | : 2013-01-07 |
| Genre | : Science |
| ISBN | : 1118519310 |
The phenomenon of spin-crossover has a large impact on the physical properties of a solid material, including its colour, magnetic moment, and electrical resistance. Some materials also show a structural phase change during the transition. Several practical applications of spin-crossover materials have been demonstrated including display and memory devices, electrical and electroluminescent devices, and MRI contrast agents. Switchable liquid crystals, nanoparticles, and thin films of spin-crossover materials have also been achieved. Spin-Crossover Materials: Properties and Applications presents a comprehensivesurvey of recent developments in spin-crossover research, highlighting the multidisciplinary nature of this rapidly expanding field. Following an introductory chapter which describes the spin-crossover phenomenon and historical development of the field, the book goes on to cover a wide range of topics including Spin-crossover in mononuclear, polynuclear and polymeric complexes Structure: function relationships in molecular spin-crossover materials Charge-transfer-induced spin-transitions Reversible spin-pairing in crystalline organic radicals Spin-state switching in solution Spin-crossover compounds in multifunctional switchable materials and nanotechnology Physical and theoretical methods for studying spin-crossover materials Spin-Crossover Materials: Properties and Applications is a valuable resource for academic researchers working in the field of spin-crossover materials and topics related to crystal engineering, solid state chemistry and physics, and molecular materials. Postgraduate students will also find this book useful as a comprehensive introduction to the field.
| Author | : OpenStax |
| Publisher | : |
| Total Pages | : 622 |
| Release | : 2016-11-04 |
| Genre | : Science |
| ISBN | : 9781680920451 |
University Physics is a three-volume collection that meets the scope and sequence requirements for two- and three-semester calculus-based physics courses. Volume 1 covers mechanics, sound, oscillations, and waves. Volume 2 covers thermodynamics, electricity and magnetism, and Volume 3 covers optics and modern physics. This textbook emphasizes connections between between theory and application, making physics concepts interesting and accessible to students while maintaining the mathematical rigor inherent in the subject. Frequent, strong examples focus on how to approach a problem, how to work with the equations, and how to check and generalize the result. The text and images in this textbook are grayscale.
| Author | : Randy S Fishman |
| Publisher | : Morgan & Claypool Publishers |
| Total Pages | : 225 |
| Release | : 2018-11-05 |
| Genre | : Science |
| ISBN | : 1643271148 |
Two of the most powerful tools used to study magnetic materials are inelastic neutron scattering and THz spectroscopy. Because the measured spectra provide a dynamical fingerprint of a magnetic material, those tools enable scientists to unravel the structure of complex magnetic states and to determine the microcscopic interactions that produce them. This book discusses the experimental techniques of inleastic neutron scattering and THz spectroscopy and provides the theoretical tools required to analyze their measurements using spin-wave theory. For most materials, this analysis can resolve the microscopic magnetic interactions such as exchange, anisotropy, and Dzyaloshinskii-Moriya interactions. Assuming a background in elementary statistical mechanics and a familiarity with the quantized harmonic oscillator, this book presents a comprehensive review of spin-wave theory and its applications to both inelastic neutron scattering and THz spectroscopy. Spin-wave theory is used to study several model magnetic systems, including non-collinear magnets such as spirals and cycloids that are produced by geometric frustration, competing exchange interactions, or Dzyaloshinskii-Moriya interactions. Several case studies utilizing spin-wave theory to analyze inelastic neutron-scattering and THz spectroscopy measurements are presented. These include both single crystals and powders and both oxides and molecule-based magnets. In addition to sketching the numerical techniques used to fit dynamical spectra based on microscopic models, this book also contains over 70 exercises that can be performed by beginning graduate students.
