Spectroscopy and Photochemistry of Uranyl Compounds

Spectroscopy and Photochemistry of Uranyl Compounds
Author: Eugene Rabinowitch
Publisher: Elsevier
Total Pages: 383
Release: 2013-10-22
Genre: Science
ISBN: 1483156753

Spectroscopy and Photochemistry of Uranyl Compounds is a guide to the research and physics of the actinide elements, particularly the uranyl ion. The book is introduced with the subject of the spectroscopy of uranyl salts in the solid state. Studies dealing with the fluorescence and absorption spectra of solid uranyl salts through band measurements and empirical classification, term analysis, and fluorescence spectrum in relation to excitation by light of various wavelengths are then discussed. The book also mentions the analysis of the uranyl spectrum by Dieke and co-workers, because of the precise measurements of the fluorescence and absorption bands obtained under the Manhattan project. The table determined by Pant and Sakhwalkar in their study of the florescence spectrum of solid, hydrated uranyl fluoride at -185 degrees centigrade is presented. The text also discusses the theory of electronic structure and spectra of the uranyl ion. The spectroscopy of uranyl compounds in solution and the uranyl fluorescence intensity and decay are then presented. The book then explains the process of measuring the intensity of slowly decaying florescence of uranyl salts. The primary photochemical reactions in uranyl compounds are found to be slow, giving rise to many secondary thermal reactions that may be unwanted. Researchers in the fields of chemistry and physics working on actinide elements will find this collection of monographs invaluable.

Uranium

Uranium
Author: Peter C. Burns
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 696
Release: 2018-12-17
Genre: Science
ISBN: 1501509195

Volume 38 of Reviews in Mineralogy provides detailed reviews of various aspects of the mineralogy and geochemistry of uranium. We have attempted to produce a volume that incorporates most important aspects of uranium in natural systems, while providing some insight into important applications of uranium mineralogy and geochemistry to environmental problems. The result is a blend of perspectives and themes: historical (Chapter 1), crystal structures (Chapter 2), systematic mineralogy and paragenesis (Chapters 3 and 7), the genesis of uranium ore deposits (Chapters 4 and 6), the geochemical behavior of uranium and other actinides in natural fluids (Chapter 5), environmental aspects of uranium such as microbial effects, groundwater contamination and disposal of nuclear waste (Chapters 8, 9 and 10), and various analytical techniques applied to uranium-bearing phases (Chapters 11-14). This volume was written in preparation for a short course by the same title, sponsored by the Mineralogical Society of America, October 22 and 23, 1999 in Golden, Colorado, prior to MSA's joint annual meeting with the Geological Society of America.

Index to Reviews, Symposia Volumes and Monographs in Organic Chemistry

Index to Reviews, Symposia Volumes and Monographs in Organic Chemistry
Author: Norman Kharasch
Publisher: Elsevier
Total Pages: 339
Release: 2013-11-15
Genre: Science
ISBN: 1483154904

Index to Reviews, Symposia Volumes and Monographs in Organic Chemistry presents the development in organic chemistry for the period 1963—1964. This book covers works in English, German, and French languages, including also English translations of Russian studies. Organized into three parts encompassing 136 chapters, this book starts with a collection of review articles concerning the advances in analytical chemistry and instrumentation. This text then presents the annual collection of review articles on advances in chemical physics, chemotherapy, clinical chemistry, drug research, and fluorine chemistry. Other chapters deal with advances in food research, heterocyclic chemistry, spectroscopy, organic reactions, and tracer methodology. This book presents as well a collection of review articles on pharmaceutical sciences, polymer science, medicinal chemistry, pharmacy, and pharmacology. The final chapter presents a list of monographs concerning chemical engineering, applications of neutron diffraction in chemistry, and mechanochemistry of polymers. This book is a valuable resource for organic chemists, students, and scientists.

Preparative Organic Photochemistry

Preparative Organic Photochemistry
Author: Alexander Schönberg
Publisher: Springer Science & Business Media
Total Pages: 631
Release: 2012-12-06
Genre: Science
ISBN: 3642879187

(Abridged and translated) Organic photochemistry may be divided into three parts: theory which is the province of the physical chemist; instrumentation which requires the skill of both physicist and engineer; and preparation which falls within the sphere of the organic chemist. At one time the same person could cover all three fields without too much difficulty, but this has now become virtually impossible because the disciplines involved have expanded in both breadth and depth; it is there fore timely to have a separate treatment of preparative organic photo chemistry. There appears to be no review of the main photochemical reactions which includes the advances made in recent years available to the organic chemist working in the preparative field. An exception is the excellent "Photochemical Reactions" by C. R. MASSON, V. BOEKELHEIDE and W. A. NoYES JR., published in 1956, which gives a brief review of the reactions which are important in preparative organic photochemistry. The present monograph on the other hand seeks to provide a detailed survey for the chemist; the author does not set out to discuss every photo chemical reaction in the field of organic chemistry but he does include in addition to those of current interest in the preparative field some which are likely to be of interest in the future and which result in single end-products of known composition. The photochemical synthesis of highly polymerized products falls outside the scope of the work.

Optical Spectroscopy of Inorganic Solids

Optical Spectroscopy of Inorganic Solids
Author: B. Henderson
Publisher: Oxford University Press
Total Pages: 678
Release: 2006
Genre: Science
ISBN: 9780199298624

This text describes the technique of optical spectroscopy applied to problems in condensed matter physics. It relates theoretical understanding to experimental measurement, including discussion of the optical spectroscopy of inorganic insulators, with many illustrative examples. Symmetry arguments are developed from a formal group theoretical basis and are frequently used, and a special effort is made to treat the subject of lattice vibrations and to show how these can affect the spectroscopic properties of solids. The elements of laser theory are developed, and the authors also explore the use of optically detected magnetic resonance techniques for the investigation of semiconducting materials.