S Sulfur Nitrogen Compounds
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| Author | : Hans-Jürgen Fachmann |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 293 |
| Release | : 2013-11-11 |
| Genre | : Science |
| ISBN | : 3662063573 |
The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a !arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters.
| Author | : |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 344 |
| Release | : 2013-06-29 |
| Genre | : Science |
| ISBN | : 3662063603 |
The present volume describes cyclic sulfur-nitrogen compounds whose ring system con tains one or two other types of atoms in addition to sulfur and nitrogen. At least one sulfur atom can be regarded as having oxidation number IV in one resonance structure. That means the sulfur in fact has an oxidation number higher than 11 and lower than VI. The volume continues "Sulfur-Nitrogen Compounds" Part 2, in which the binary sulfur(lV)-nitrogen ring systems are described. Compounds with the same "hetero atom" in the sulfur-nitrogen ring are arranged in groups. Within a group the compounds are arranged according to ring size, and for a given number of ring atoms, in order of decreasing S: N ratio. Neutral compounds are described before ions, and saturated compounds before unsaturated, aromatic ones. A very heterogeneous material is brought together in this volume. SN Se2 rings, which 2 strongly resemble the binary S3N2 ring, are covered. S-N-Si rings with five, six, and eight atoms, and also N-S-N-bridged eight-membered rings, are described. The S-N-P rings form a puzzling and complex part of this volume; they readily interconvert by dimerization, cleavage, and by addition and loss of NSN and NPN groups. Especially interesting is the aromatic character of 8-N-P rings.
| Author | : Roy M. Harrison |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 642 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 9400940831 |
The contributing authors have been chosen because of their depth of knowledge and experience in air pollution work, and we are confident that this is reflected in a Handbook which will find very wide application wherever air pollution analysis is practised. Roy M. Harrison Roger Perry February 1985 Readers are recommended to follow all the usual laboratory safety pre cautions. While care has been taken to ensure that the information in this book is correct, neither the authors nor the publisher can accept responsibility for any outcome of the application of methods and procedures outlined in this book. Contributors A. Apling BSc, PhD Air Pollution Division Warren Spring Laboratory Gunnels Wood Road Stevenage Hertfordshire SG 1 2BX UK H.W. de Koning DSc Environmental Pollution Division of Environmental Health World Health Organization Geneva Switzerland R.M. Harrison PhD Department of Chemistry University of Essex Wivenhoe Park Colchester C04 3SQ UK P.W.W. Kirk BSc, MSc, PhD, DIC, C Chern, MRSC Department of Civil Engineering Imperial College London SW7 2BU UK J.R. Kramer Professor in Geochemistry Department of Geology McMaster University Hamilton Ontario L8S 4Ml Canada J.N. Lester B. Tech, MSc, DIC, PhD, MIPHE, Department of Civil Engineering Imperial College London SW7 2BU UK xxi xxii Contributors A.E. Mcintyre BSc, PhD, DIC, MIWES Consultants in Environmental Sciences Ltd Yeoman House 63 Croydon Road London SW20 7TW UK D.J.
| Author | : Alfons Kubny |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 347 |
| Release | : 2013-06-29 |
| Genre | : Science |
| ISBN | : 3662063514 |
This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by Ä2 + 4Ü cycloaddition with 1,3-butadiene. Among dithionitryl (1+) salts, only ÄS=N=SÜ+AsF6- has been studied extensively. Cycloaddition with alkenes and triple bond compounds produce 1,3,2-dithiazolium salts. Thiohydroxylamine, HSNH2, has been detected in the gas phase. Numerous examples of N, N-diorganyl-amino-halogeno-sulfanes (XSNR2, X = F, Cl, Br, I; R = organyl) and salts of the cation (XS)2N+ (X = Cl, Br) are known. N, N-Diorganyl-amino-chloro-sulfanes are important synthetic reagents.
| Author | : Xing-Hong Zhang |
| Publisher | : John Wiley & Sons |
| Total Pages | : 482 |
| Release | : 2021-03-23 |
| Genre | : Technology & Engineering |
| ISBN | : 3527823808 |
A must-have resource to the booming field of sulfur-containing polymers Sulfur-Containing Polymers is a state-of-the-art text that offers a synthesis of the various sulfur-containing polymers from low-cost sulfur resources such as elemental sulfur, carbon disulfide (CS2), carbonyl sulfide (COS) and mercaptan. With contributions from noted experts on the topic, the book presents an in-depth understanding of the mechanisms related to the synthesis of sulfur-containing polymers. The book also includes a review of the various types of sulfur-containing polymers, such as: poly(thioester)s, poly(thioether)s and poly(thiocarbonate)s and poly(thiourethane)s with linear or hyperbranched (dendrimer) architectures. The expert authors provide the fundamentals on the structure-property relationship and applications of sulfur-containing polymers. Designed to be beneficial for both research and application-oriented chemists and engineers, the book contains the most recent research and developments of sulfur-containing polymers. This important book: Offers the first comprehensive handbook on the topic Contains state-of-the-art research on synthesis of sulfur containing polymers from low-cost sulfur-containing compounds Examines the synthesis, mechanism, structure properties, and applications of various types of sulful-containing polymers Includes contributions from well-known experts Written for polymer chemists, materials scientists, chemists in industry, biochemists, and chemical engineers, Sulfur-Containing Polymers offers a groundbreaking text to the field with inforamtion on the most recent research.
| Author | : D.L.H. Williams |
| Publisher | : Elsevier |
| Total Pages | : 281 |
| Release | : 2004-12-16 |
| Genre | : Science |
| ISBN | : 0080473601 |
Since 1988, there has been much literature published on the chemistry of nitric oxide, particularly in the field of S-nitrosation and the chemistry of S-nitroso compounds. Written by a chemist for the chemistry community, this book provides an update of the chemistry of nitrosation reactions, dealing with both the synthetic and mechanistic aspects of these reactions. It also looks at the chemistry of nitric oxide in relation to the amazing biological properties of this simple diatomic molecule, which were unknown until around 1990.* Provides an update on previously published literature on nitric oxide chemistry* Contains chapters on reagents for nitrosation, nitrosation at nitrogen, aliphatic and aromatic carbon, oxygen, sulfur and metal centres* Looks at hot research topics such as synthesis, properties and reactions of s-nitrosothiols
| Author | : Samuel Butcher |
| Publisher | : Elsevier |
| Total Pages | : 256 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 032315879X |
An Introduction to Air Chemistry serves as a textbook on air chemistry and covers topics such as chemical principles, sampling and collection, treatment of data, and special methods of analysis. The atmospheric chemistry of sulfur compounds is also discussed, together with nitrogen compounds and ozone, aerosols, and carbon compounds. This book is comprised of nine chapters and begins with a review of the relevant chemical and meteorological principles. The general methods for obtaining and handling air chemical data are then described, followed by a discussion on three classes of chemical compounds that are important in any consideration of trace constituents of the atmosphere, namely, sulfur compounds, carbon compounds, and nitrogen compounds and ozone. Significant atmospheric reactions, the global budgets, and selected methods of analysis for these compounds are considered. The final chapter examines some of the physical characteristics of aerosols. This monograph will be a valuable resource for upper-level undergraduate and graduate-level students of analytical chemistry, meteorology, oceanography, and civil engineering, as well as for laboratory chemists, meteorologists, physical scientists, and technicians.
| Author | : Tristram Chivers |
| Publisher | : World Scientific |
| Total Pages | : 464 |
| Release | : 2021-10-12 |
| Genre | : Science |
| ISBN | : 981124135X |
Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Since the publication of A Guide to Chalcogen-Nitrogen Chemistry in 2005, the emphasis of investigations of chalcogen-nitrogen compounds has advanced from a focus on fundamental studies to the development of practical applications, as indicated by the title of this new edition. Pharmaceutical applications of organic sulfur-nitrogen compounds include drugs for the treatment of various diseases, as well as probes for locating tumour cells. From a materials perspective, carbon-containing chalcogen-nitrogen heterocycles have applications in everyday devices such as LEDs and solar cells. A new technology based on binary sulfur nitrides is being used for fingerprint detection in forensic science. As a result, this book includes seven new chapters and updates the others with extensive literature coverage of developments since 2005 while retaining earlier seminal results. This comprehensive text is essential for anyone working in the field, and the four introductory chapters emphasise general concepts that will be helpful to the non-specialist. The treatment is unique in providing a comparison of sulfur, selenium and tellurium compounds. Each chapter is designed to be self-contained, and there are extensive cross-references between chapters.
| Author | : Hans-Jürgen Fachmann |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 348 |
| Release | : 2013-11-11 |
| Genre | : Science |
| ISBN | : 3662063549 |
The volume continues the description of acyclic sulfur - nitrogen compounds with sulfur having the oxidation number II and covers amino-di- and aminopolysulfanes as well as diamino-di- and diamino-polysulfanes. Numerous examples of the class of diamino-disulfanes and their interesting chemical properties are described: N, N'-disulfanediyl-bis(N-heterocycles), for instance, undergo S-S bond scission in a thermal or photochemical radical - dimer equilibrium or react with acetylenes to give thiophenes, and N, N'disulfanediyl-bis(phthalimide) is a sulfur transfer reagent for organic synthesis. The volume completes the series on sulfur - nitrogen compounds which is a unique and comprehensive source of information for this field in chemistry.
| Author | : Xuefeng Jiang |
| Publisher | : Springer Nature |
| Total Pages | : 477 |
| Release | : 2019-08-28 |
| Genre | : Science |
| ISBN | : 3030255980 |
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
