Reactivity In Confined Spaces
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| Author | : Gareth Lloyd |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 491 |
| Release | : 2021-08-16 |
| Genre | : Science |
| ISBN | : 1788019717 |
The chemistry that occurs within confined spaces is the product of a collection of forces, often beyond the molecule, and is not easily ascribed to singular factors. There is a breadth of material types that can define a confined space (e.g. macrocycles, interlocked molecules, porous and non-porous crystals, organic and inorganic/coordination cages) which are rarely discussed together. Studies of supramolecular entities in the solution and solid states are also not often compared in the same discussion, even though the concepts are often similar or can be easily transferred between the two. Chapters in this book combine classical host-guest chemistry with catalysis, reactivity, and modern supramolecular chemistry. They cover the many different technologies used to describe and understand reactivity in confined spaces in one accessible title. With contributions from leading experts, Reactivity in Confined Spaces will be relevant for graduate students and researchers working in supramolecular chemistry, both organic- and inorganic-based, homogeneous and heterogeneous catalysis, polymer chemistry, and materials science in general.
| Author | : Pratim Kumar Chattaraj |
| Publisher | : John Wiley & Sons |
| Total Pages | : 451 |
| Release | : 2021-08-23 |
| Genre | : Science |
| ISBN | : 1119684021 |
An insightful analysis of confined chemical systems for theoretical and experimental scientists Chemical Reactivity in Confined Systems: Theory and Applications presents a theoretical basis for the molecular phenomena observed in confined spaces. The book highlights state-of-the-art theoretical and computational approaches, with a focus on obtaining physically relevant clarification of the subject to enable the reader to build an appreciation of underlying chemical principles. The book includes real-world examples of confined systems that highlight how the reactivity of atoms and molecules change upon encapsulation. Chapters include discussions on recent developments related to several host-guest systems, including cucurbit[n]uril, ExBox+4, clathrate hydrates, octa acid cavitand, metal organic frameworks (MOFs), covalent organic frameworks (COFs), zeolites, fullerenes, and carbon nanotubes. Readers will learn how to carry out new calculations to understand the physicochemical behavior of confined quantum systems. Topics covered include: A thorough introduction to global reactivity descriptors, including electronegativity, hardness, and electrophilicity An exploration of the Fukui function, as well as dual descriptors, higher order derivatives, and reactivity through information theory A practical discussion of spin dependent reactivity and temperature dependent reactivity Concise treatments of population analysis, reaction force, electron localization functions, and the solvent effect on reactivity Perfect for academic researchers and graduate students in theoretical and computational chemistry and confined chemical systems, Chemical Reactivity in Confined Systems: Theory and Applications will also earn a place in the libraries of professionals working in the areas of catalysis, supramolecular chemistry, and porous materials.
| Author | : C.Richard A. Catlow |
| Publisher | : Elsevier |
| Total Pages | : 372 |
| Release | : 2017-09-20 |
| Genre | : Technology & Engineering |
| ISBN | : 0128050586 |
Modelling and Simulation in the Science of Micro- and Meso-Porous Materials addresses significant developments in the field of micro- and meso-porous science. The book includes sections on Structure Modeling and Prediction, Synthesis, Nucleation and Growth, Sorption and Separation processes, Reactivity and Catalysis, and Fundamental Developments in Methodology to give a complete overview of the techniques currently utilized in this rapidly advancing field. It thoroughly addresses the major challenges in the field of microporous materials, including the crystallization mechanism of porous materials and rational synthesis of porous materials with controllable porous structures and compositions. New applications in emerging areas are also covered, including biomass conversion, C1 chemistry, and CO2 capture. - Authored and edited by experts in the field of micro- and meso-porous materials - Includes introductory material and background both on the science of microporous materials and on the techniques employed in contemporary modeling studies - Rigorous enough for scientists conducting related research, but also accessible to graduate students in chemistry, chemical engineering, and materials science
| Author | : Robert Schlögl |
| Publisher | : Walter de Gruyter GmbH & Co KG |
| Total Pages | : 685 |
| Release | : 2022-01-19 |
| Genre | : Technology & Engineering |
| ISBN | : 3110608596 |
Energy – in the headlines, discussed controversially, vital. The use of regenerative energy in many primary forms leads to the necessity to store grid dimensions for maintaining continuous supply and enabling the replacement of fossil fuel systems. Chemical energy storage is one of the possibilities besides mechano-thermal and biological systems. This work starts with the more general aspects of chemical energy storage in the context of the geosphere and evolves to dealing with aspects of electrochemistry, catalysis, synthesis of catalysts, functional analysis of catalytic processes and with the interface between electrochemistry and heterogeneous catalysis. Top-notch experts provide a sound, practical, hands-on insight into the present status of energy conversion aimed primarily at the young emerging research front.
| Author | : Bert Sels |
| Publisher | : Elsevier |
| Total Pages | : 475 |
| Release | : 2016-07-29 |
| Genre | : Technology & Engineering |
| ISBN | : 0444635149 |
Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. - Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 - Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials - Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) - Contains chapters prepared by known specialists who are members of the International Zeolite Association
| Author | : D. Alan Veasey |
| Publisher | : John Wiley & Sons |
| Total Pages | : 512 |
| Release | : 2005-12-02 |
| Genre | : Technology & Engineering |
| ISBN | : 0471787655 |
EVERY SECOND COUNTS WHEN YOU'RE RESPONDING TO AN EMERGENCYINVOLVINGCONFINED SPACE-HERE'S THE DEFINITIVE GUIDE TO PERFORMINGFLAWLESS RESCUES! Confined Space Entry and Emergency Response utilizes a realistic,scenario-based approach to teach you-and your staff-the right wayto respond to an incident involving a confined space. The authorsprovide intensive, step-by-step guidance through the challengingmaze of training regulations, equipment needs, and procedures tokeep your response team finely tuned and ready to go under anyconditions. You'll find expert, detailed coverage of complex-and oftenconfusing-topics such as: * The basic components of rescue * OSHA's regulations for confined space entry and rescue * Confined space entry permitting * Assessing confined space hazards * Hazardous atmospheres and how to protect entrants from them * Air monitoring in confined spaces * Selection and use of personal protective equipment * The use of ropes and rigging The CD-ROM includes the Instructor's Guide along with lesson plansand useful practice tools such as worksheets, exercise handouts,performance checklists, diagrams and equipment lists for fieldexercises, instructions for building field training simulators, andguidelines for identifying rescue trainers and evaluating theircompetency as well as that of outside rescue teams. Everything you need to effectively train those working in aconfined space can truly be found within these pages and on theCD-ROM.
| Author | : Neil McManus |
| Publisher | : Routledge |
| Total Pages | : 916 |
| Release | : 2018-12-18 |
| Genre | : Technology & Engineering |
| ISBN | : 1351417800 |
Safety and Health in Confined Spaces goes beyond all other resources currently available. International in scope, the 15 chapters and 10 appendices cover every facet of this important subject. A significant addition to the literature, this book provides a confined space focus to other health and safety concepts. Confined spaces differ from other workspaces because their boundary surfaces amplify the consequences of hazardous conditions. The relationship between the individual, the boundary surface, and the hazardous condition is the critical factor in the onset, outcome, and severity of accidents in these workspaces. The author uses information about causative and other factors from analysis of fatal accidents to develop a hazard assessment and hazard management system. He provides a detailed, disciplined protocol, covering 36 hazardous conditions, that addresses all segments of work--the undisturbed space, entry preparation, work activity, and emergency preparedness and response--and illustrates how to use it. Safety and Health in Confined Spaces gives you the tools you need for preventing and responding to accidents.
| Author | : U.S. Department of Transportation |
| Publisher | : Simon and Schuster |
| Total Pages | : 352 |
| Release | : 2013-06-03 |
| Genre | : House & Home |
| ISBN | : 1626363765 |
Does the identification number 60 indicate a toxic substance or a flammable solid, in the molten state at an elevated temperature? Does the identification number 1035 indicate ethane or butane? What is the difference between natural gas transmission pipelines and natural gas distribution pipelines? If you came upon an overturned truck on the highway that was leaking, would you be able to identify if it was hazardous and know what steps to take? Questions like these and more are answered in the Emergency Response Guidebook. Learn how to identify symbols for and vehicles carrying toxic, flammable, explosive, radioactive, or otherwise harmful substances and how to respond once an incident involving those substances has been identified. Always be prepared in situations that are unfamiliar and dangerous and know how to rectify them. Keeping this guide around at all times will ensure that, if you were to come upon a transportation situation involving hazardous substances or dangerous goods, you will be able to help keep others and yourself out of danger. With color-coded pages for quick and easy reference, this is the official manual used by first responders in the United States and Canada for transportation incidents involving dangerous goods or hazardous materials.
| Author | : |
| Publisher | : |
| Total Pages | : 344 |
| Release | : 1965 |
| Genre | : Air |
| ISBN | : |
"The report is a complete compilation of the papers presented and the proceedings of the Conference on Atmospheric Contamination in Confined Spaces, sponsored by the Aerospace Medical Research Laboratories and held in Dayton, Ohio on 30, 31 March and 1 April 1965. Major technical areas discussed by the invited speakers, panel members and conference attendees included continuous inhalation exposure techniques, statistical methods for evaluation and interpretation of exposure data, minimum criteria for continuous exposure studies and toxicological qualification of space cabin materials. The conference participants were provided the opportunity to tour the Toxic Hazards Research Unit at Wright-Patterson Air Force Base and to ask questions regarding its operation. A discussion of the Clean Air Act of 1963 was presented by a representative of the Federal Department of Health, Education and Welfare."--Abstract
| Author | : CCPS (Center for Chemical Process Safety) |
| Publisher | : John Wiley & Sons |
| Total Pages | : 364 |
| Release | : 2010-09-09 |
| Genre | : Technology & Engineering |
| ISBN | : 0470938005 |
With new and growing interest in dealing with the hazards of reactive chemicals, this book offers guidelines that can significantly reduce the risk or mitigate the severity of accidents associated with storing and handling reactive materials. Necessary elements of a reliable system to prevent equipment or human failures that might lead to a reactive chemical incident are sound and responsible management policies, together with a combination of superior siting, design, fabrication, erection, inspection, monitoring, maintenance, operations and maintenance of facilities. These Guidelines deal with all of these elements with emphasis on design considerations.
