Progress in Reaction Kinetics

Progress in Reaction Kinetics
Author: G. Porter
Publisher: Elsevier
Total Pages: 400
Release: 2016-06-03
Genre: Science
ISBN: 1483195007

Progress in Reaction Kinetics discusses the main themes of chemical kinetics. It covers such topics as the reactions of halogen atoms and methylenes, mercury photosensitized reactions, anionic polymerization, cis trans-isomerisation, and protolytic reactions. The book provides a good illustration of the quantitative rate studies in biochemical systems. The experiments to determine the relative rate constants are shown and analyzed. The process of photosensitization involves absorption of light energy by a strongly absorbing substance. The methods to identify the reactions of carbonyl compounds, organic acids and esters are presented as well as the reactions of alcohols, ethers, and epoxides. The degree of reaction of some haem compounds is explained. A chapter of the book focuses on the kinetic treatment of processes that takes place in a series of steps. Such procedures are called consecutive processes. A sample of these is the rate-determining step approximation. The book will provide useful information to chemists, chemical engineers, students, and researchers.

Chemical Reaction Kinetics

Chemical Reaction Kinetics
Author: Jorge Ancheyta
Publisher: John Wiley & Sons
Total Pages: 309
Release: 2017-08-07
Genre: Science
ISBN: 1119226643

A practical approach to chemical reaction kinetics—from basic concepts to laboratory methods—featuring numerous real-world examples and case studies This book focuses on fundamental aspects of reaction kinetics with an emphasis on mathematical methods for analyzing experimental data and interpreting results. It describes basic concepts of reaction kinetics, parameters for measuring the progress of chemical reactions, variables that affect reaction rates, and ideal reactor performance. Mathematical methods for determining reaction kinetic parameters are described in detail with the help of real-world examples and fully-worked step-by-step solutions. Both analytical and numerical solutions are exemplified. The book begins with an introduction to the basic concepts of stoichiometry, thermodynamics, and chemical kinetics. This is followed by chapters featuring in-depth discussions of reaction kinetics; methods for studying irreversible reactions with one, two and three components; reversible reactions; and complex reactions. In the concluding chapters the author addresses reaction mechanisms, enzymatic reactions, data reconciliation, parameters, and examples of industrial reaction kinetics. Throughout the book industrial case studies are presented with step-by-step solutions, and further problems are provided at the end of each chapter. Takes a practical approach to chemical reaction kinetics basic concepts and methods Features numerous illustrative case studies based on the author’s extensive experience in the industry Provides essential information for chemical and process engineers, catalysis researchers, and professionals involved in developing kinetic models Functions as a student textbook on the basic principles of chemical kinetics for homogeneous catalysis Describes mathematical methods to determine reaction kinetic parameters with the help of industrial case studies, examples, and step-by-step solutions Chemical Reaction Kinetics is a valuable working resource for academic researchers, scientists, engineers, and catalyst manufacturers interested in kinetic modeling, parameter estimation, catalyst evaluation, process development, reactor modeling, and process simulation. It is also an ideal textbook for undergraduate and graduate-level courses in chemical kinetics, homogeneous catalysis, chemical reaction engineering, and petrochemical engineering, biotechnology.

Progress in Reaction Kinetics

Progress in Reaction Kinetics
Author: J. R. Jones
Publisher:
Total Pages: 90
Release: 1973
Genre: Science
ISBN: 9780080170374

Ion Association in Proton Transfer Reactions: Use of ESR for the Quantitative Determination of Gas Phase Atom and Radical Concentrations summarizes the basic information essential for the measurement of both gas phase atoms and free radicals concentration by electron spin resonance (ESR) spectroscopy. Organized into two chapters, this book first explains the ion association in proton transfer reactions, and then characterizes the ion pairs. The second chapter focuses on the specific use of the ESR spectroscopy. This book also details the gas phase species detected by ESR spectroscopy, includin ...

Chemical Kinetics and Reaction Dynamics

Chemical Kinetics and Reaction Dynamics
Author: Santosh K. Upadhyay
Publisher: Springer Science & Business Media
Total Pages: 256
Release: 2007-04-29
Genre: Science
ISBN: 1402045476

Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.

An Introduction to Chemical Kinetics

An Introduction to Chemical Kinetics
Author: Michel Soustelle
Publisher: John Wiley & Sons
Total Pages: 484
Release: 2013-02-07
Genre: Science
ISBN: 1118604229

This book is a progressive presentation of kinetics of the chemical reactions. It provides complete coverage of the domain of chemical kinetics, which is necessary for the various future users in the fields of Chemistry, Physical Chemistry, Materials Science, Chemical Engineering, Macromolecular Chemistry and Combustion. It will help them to understand the most sophisticated knowledge of their future job area. Over 15 chapters, this book present the fundamentals of chemical kinetics, its relations with reaction mechanisms and kinetic properties. Two chapters are then devoted to experimental results and how to calculate the kinetic laws in both homogeneous and heterogeneous systems. The following two chapters describe the main approximation modes to calculate these laws. Three chapters are devoted to elementary steps with the various classes, the principles used to write them and their modeling using the theory of the activated complex in gas and condensed phases. Three chapters are devoted to the particular areas of chemical reactions, chain reactions, catalysis and the stoichiometric heterogeneous reactions. Finally the non-steady-state processes of combustion and explosion are treated in the final chapter.

Kinetics of Catalytic Reactions

Kinetics of Catalytic Reactions
Author: M. Albert Vannice
Publisher: Springer Science & Business Media
Total Pages: 257
Release: 2006-04-09
Genre: Science
ISBN: 0387259724

Describes how to conduct kinetic experiments with heterogeneous catalysts, analyze and model the results, and characterize the catalysts Detailed analysis of mass transfer in liquid phase reactions involving porous catalysts. Important to the fine chemicals and pharmaceutical industries so it has appeal to many researchers in both industry and academia (chemical engineering and chemistry departments