Helical Wormlike Chains in Polymer Solutions

Helical Wormlike Chains in Polymer Solutions
Author: Hiromi Yamakawa
Publisher: Springer
Total Pages: 517
Release: 2016-02-22
Genre: Technology & Engineering
ISBN: 3662487160

This book presents the "helical wormlike chain" model – a general model for both flexible and semiflexible polymer chains. It explains how statistical-mechanical, hydrodynamic, and dynamic theories of their solution properties can be developed on the basis of this model. This new second edition has been carefully updated and thoroughly revised. It includes a new chapter covering "Simulation and More on Excluded-Volume Effects", as well as the discussion of new experimental data and the application of the theory to ring polymers. The authors provide analysis of important recent experimental data by the use of their theories for flexible polymers over a wide range of molecular weights, including the oligomer region, and for semiflexible polymers, including biological macromolecules such as DNA. This is all clearly illustrated using a reasonable number of theoretical equations, tables, figures, and computer-aided forms, which support the understanding of the basic theory and help to facilitate its application to experimental data for the polymer molecular characterization.

Single-Chain Polymer Nanoparticles

Single-Chain Polymer Nanoparticles
Author: José A. Pomposo
Publisher: John Wiley & Sons
Total Pages: 504
Release: 2017-08-18
Genre: Technology & Engineering
ISBN: 3527806393

This first book on this important and emerging topic presents an overview of the very latest results obtained in single-chain polymer nanoparticles obtained by folding synthetic single polymer chains, painting a complete picture from synthesis via characterization to everyday applications. The initial chapters describe the synthetics methods as well as the molecular simulation of these nanoparticles, while subsequent chapters discuss the analytical techniques that are applied to characterize them, including size and structural characterization as well as scattering techniques. The final chapters are then devoted to the practical applications in nanomedicine, sensing, catalysis and several other uses, concluding with a look at the future for such nanoparticles. Essential reading for polymer and materials scientists, materials engineers, biochemists as well as environmental chemists.

Polymers

Polymers
Author: J.M.G. Cowie
Publisher: CRC Press
Total Pages: 452
Release: 1991-06-01
Genre: Technology & Engineering
ISBN: 9780748740734

This text follows a broad sequence of preparation, characterization, physical and mechanical properties and structure-property relations. Polymers: Chemistry and Physics of Modern Materials, Second Edition covers several methods of polymerization, properties, and advanced applications such as liquid crystals and polymers used in the electronics industry. Topics also include Step-Growth, Free Radical Addition, and Ionic Polymerization; Copolymerization; Polymer Stereochemistry and Characterization; Structure-Property Relationship; Polymer Liquid Crystals; and Polymers for the Electronics Industry.

Physical Chemistry of Polymers

Physical Chemistry of Polymers
Author: Sebastian Seiffert
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 366
Release: 2023-01-30
Genre: Science
ISBN: 3110713268

This book introduces the concepts of physical chemistry of polymers in a format targeted for a blended-learning approach. It provides a basis to bridge polymer chemistry, which targets microscopic chain structures, and polymer engineering, which targets macroscopic material properties and functions. Topics covered are single chain statistics, multi-chain interactions, and chain dynamics, both from a viewpoint of structure, properties (mostly mechanical ones), and their interrelation. In all that, the author encourages the reader to think conceptually. Explains complex facts through simplifying models, diagrams, and illustrations Accessible to chemists, chemical engineers, materials scientists, and physicists Tailored content for an interactive blended-learning format

Polymer Chains

Polymer Chains
Author: Régine Penzkofer
Publisher:
Total Pages: 0
Release: 2012
Genre: Science
ISBN: 9781621004226

The physical properties of a polymer are strongly dependent on the size or length of the polymer chain. As chain length is increased, melting and boiling temperatures increase quickly. Impact resistance also tends to increase with chain length, as does the viscosity, or resistance to flow, of the polymer in its melted state. In this book, the authors present topical research in the study of the structure, physical properties and industrial uses of polymer chains. Topics discussed include the flexibility of polyheteroarylenes and the effect on several physical properties of these polymers; aliphatic polyester-based nanocomposites; bioplastic-based blends; interactions in small permeants in polymeric matrices; the role of polymer chain ends in plasma surface modification and pre-ceramic polymer chains.

Polymers in Confined Environments

Polymers in Confined Environments
Author: Steve Granick
Publisher: Springer
Total Pages: 293
Release: 2003-07-01
Genre: Technology & Engineering
ISBN: 354069711X

The rapidly-developing field of confined polymers is reviewed in this volume. Special emphasis is given to polymer aspects of this interdisciplinary problem. Taken together, the contributions offer ample evidence of how the field of polymer science continues to evolve with the passage of time. The topics revolve around the tendency of surfaces to impede chain relaxation and to stimulate new sorts of chain organization. These have been implicated in a variety of spectacular phenomena. Here is a listing of authors and affiliations: K. Binder (Johannes Gutenberg-Universität Mainz, Germany); P.-G. de Gennes (College de France, France); E.P. Giannelis, R. Krishnamoorti, and E. Manias (Cornell University and University of Houston, USA); G.S. Grest (Exxon Research and Engineering Co., USA); L. Leger, E. Raphael, and H. Hervet (College de France, France); S.-Q. Wang (Case Western Reserve University, USA).

Polymer Physics

Polymer Physics
Author: Wenbing Hu
Publisher: Springer Science & Business Media
Total Pages: 248
Release: 2012-11-05
Genre: Technology & Engineering
ISBN: 3709106702

A molecular view on the fundamental issues in polymer physics is provided with an aim at students in chemistry, chemical engineering, condensed matter physics and material science courses. An updated translation by the author, a renowned Chinese chemist, it has been proven to be an effective source of learning for many years. Up-to-date developments are reflected throughout the work in this concise presentation of the topic. The author aims at presenting the subject in an efficient manner, which makes this particularly suitable for teaching polymer physics in settings where time is limited, without having to sacrifice the extensive scope that this topic demands.

Polymer Conformation and Configuration

Polymer Conformation and Configuration
Author: Frank A. Bovey
Publisher: Elsevier
Total Pages: 189
Release: 2013-10-22
Genre: Science
ISBN: 1483276899

Polymer Conformation and Configuration focuses on the stereochemistry and conformation of vinyl polymers and the application of nuclear magnetic resonance (NMR) spectroscopy to their study and polypeptide conformation by NMR and optical methods. The book first offers information on the configuration of vinyl polymer chains and configurational sequences and the mechanism of vinyl propagation. Discussions focus on the effect of polymerization temperature, polyisopropyl acrylate, polypropylene, Coleman-Fox Propagation Mechanism, and sequence statistics. The text then elaborates on the observation of polymer chain conformation by NMR, including model compound conformations, averaging of vicinal couplings, conformer populations, and polymer chain conformation. The publication also takes a look at the conformations of N-disubstituted polypeptide chains. The manuscript is a valuable reference for readers interested in polymer conformation and configuration.