Organoboranes For Syntheses
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Author | : Donald S. Matteson |
Publisher | : Springer Science & Business Media |
Total Pages | : 417 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 3642797091 |
This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.
Author | : P. Veeraraghavan Ramachandran |
Publisher | : |
Total Pages | : 272 |
Release | : 2001 |
Genre | : Medical |
ISBN | : |
This book examines the recent advances in the art of organic synthesis via organoboranes. The volume includes a wide range of topics in asymmetric synthesis, such as reduction, aldol reaction, allyboration, homologation, and cyclopropanation. Additional subjects include Suzuki coupling, amino acid synthesis, fluoro-organic synthesis, boron catalysts for stereoselective transformations, heterocyclic synthesis and novel borohydride reagents.
Author | : Thomas Onak |
Publisher | : Elsevier |
Total Pages | : 373 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0323153615 |
Organoborane Chemistry deals with the chemistry of organoboranes, with emphasis on compounds containing a carbon-boron bond. The structure and physical properties of organoboranes are discussed, along with the reactions of three-coordinate and four-coordinate organoboranes, organodiboranes, and other organopolyboranes such as organotetraboranes and organopentaborane compounds. Comprised of seven chapters, this book begins with an overview of multistep synthetic or degradative reactions involving organoboron compounds, along with the nomenclature for such compounds. The next chapter examines the structure and physical properties of organoboranes, with emphasis on boron-carbon bond lengths, electronic transitions, and molecular orbital calculations. Subsequent chapters focus on three-coordinate and four-coordinate organoboranes, together with their synthesis, reactions, and properties; hydroboration and dehydroboration of organodiboranes; and the synthesis, reactions, and physical properties of other organopolyboranes such as organotetraboranes, organopentaborane compounds, and organodecaborane compounds. The final chapter is devoted to cyclic boron-carbon systems and the applications of organoboron compounds. This monograph should be of interest to organic chemists.
Author | : Herbert Charles Brown |
Publisher | : Wiley-Interscience |
Total Pages | : 312 |
Release | : 1975 |
Genre | : Science |
ISBN | : |
Author | : Gordon M. L. Cragg |
Publisher | : |
Total Pages | : 448 |
Release | : 1973 |
Genre | : Science |
ISBN | : |
Author | : E. Fernández |
Publisher | : Thieme |
Total Pages | : 582 |
Release | : 2020-05-22 |
Genre | : Science |
ISBN | : 3132429732 |
The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.
Author | : Elena Fernández |
Publisher | : Springer |
Total Pages | : 334 |
Release | : 2015-03-04 |
Genre | : Science |
ISBN | : 3319130544 |
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Author | : Akira Suzuki |
Publisher | : |
Total Pages | : 24 |
Release | : 1973 |
Genre | : |
ISBN | : |
Author | : Herbert C. Brown |
Publisher | : |
Total Pages | : 25 |
Release | : 1991 |
Genre | : Boranes |
ISBN | : |
The discovery of hydroboration has led to versatile methods of organic syntheses using organoboranes. The regiospecificity and stereospecificity of organoborane reagents have been exploited for asymmetric synthesis after it was discovered that substitution reactions of organoboranes proceed with the complete retention of configuration. Many chiral organoboranes, especially mono- and di-isocampheylboranes, can be obtained in 100% optical purity. Hydroboration using organoboranes provides a general method for synthesis of pure enantiomers.
Author | : Dennis G. Hall |
Publisher | : John Wiley & Sons |
Total Pages | : 6 |
Release | : 2012-05-29 |
Genre | : Science |
ISBN | : 1118344456 |
Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates. The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.