Nonaqueous Electrolytes Handbook

Nonaqueous Electrolytes Handbook
Author: G.J. Janz
Publisher: Elsevier
Total Pages: 1123
Release: 2012-12-02
Genre: Science
ISBN: 032314103X

Nonaqueous Electrolytes Handbook, Volume I, is an authoritative and updated information source for nonaqueous solvent systems. The information in this handbook covers the literature to 1972 and includes data for some 210 solvents. The book has been organized into eight well-defined areas: Physical Properties o f Solvents, Solvent Purification, Electrical Conductance, Diffusion, Density, Viscosity, Transference Numbers, and Additional References and Data Sources. The latter section covers additional data sources and reviews not adequately described in the preceding sections; recent data and references are also found in this section. The method of presentation of material is briefly described in the introduction to each section to facilitate the use of the tabulated information. Bibliographies are given at the end of each section. A Compound Index is included. Electrical conductance is the property most widely investigated. In view of the wealth of data, this section has been organized by solutes as follows: acids and alkali metal compounds, including ammonium compounds; quaternary ammonium salts and amines; solvent systems, electrolyte systems, and finally, all other solutes. For each, the data are reported not only for single component nonaqueous solvents but also for mixed solvents.

Non-Aqueous Electrolytes for Lithium Batteries

Non-Aqueous Electrolytes for Lithium Batteries
Author: T. R. Jow
Publisher: The Electrochemical Society
Total Pages: 240
Release: 2009-05
Genre: Science
ISBN: 156677716X

The electrolyte plays a vital role for the performance of rechargeable lithium batteries with a Li metal anode as well as Li-ion batteries. A better understanding of the elementary processes involved in the formation of the electrolyte/electrode interface and charge transfer kinetics in relation to solvent, salt, additive, and electrode material is crucial to the further optimization of Li and Li-ion batteries. This issue will focus on both the fundamental and applied aspects of the electrolyte for Li and Li-ion batteries. Topics include theoretical and experimental studies of structure/property relationships of electrolytes; development of new salts, solvents and additives; development of electrolytes for 5 V Li and Li-ion batteries; studies and approaches leading to the understanding of electrode/electrolyte interfacial phenomena and the charge transfer processes; electrolytes with enhanced non-flammability; electrolytes for wide temperature range operations; and cell performance improvement with respect to that of electrolyte materials.

New Cathode-anode Couples Using Nonaqueous Electrolytes

New Cathode-anode Couples Using Nonaqueous Electrolytes
Author: J. E. Chilton (Jr.)
Publisher:
Total Pages: 70
Release: 1962
Genre: Anodes
ISBN:

New anode-cathode couples using nonaqueous solvents were investigated for use as secondary batteries for power sources in orbiting satellites. Initial criteria of selection of the couples is based on the theoretical energy-to-weight ratio calculated from the free energy of reaction of anode and cathode, which will be greater than 200 wh/lb. Cells with active metal anodes as alkali metals and light-weight cathodes meet this criteria. Since the electrolyte solution must be compatible with alkali metals; water, alcohols, and acids are excluded from use and nonreactive nonaqueous liquids will be used for the solvent system. A survey of physical properties of liquids indicates that certain nonaqueous systems have a wide temperature range of liquid state, high dielectric constant, and moderate viscosity, but electrical conductivities of nonaqueous solutions are less than othes of aqueous systems. Reversibility of anode and cathode reactions in nonaqueous media was studied by measuring the current efficiency for metal deposition or dissolution as a function of current density. At densities of 20 ma/sq cm, Mg from a Mg ethyl bromide-ethyl ether solution, K from a POCl3-KI system, Al from an AlCl2-n hexylamine-ethyl ether system showed low reversibility. High current efficiences were found for Li electrodeposition from a propylene carbonate Li salt system and for an AlCl3-ethyl pyridinium bromide-toluene system at 20 ma/sq cm current density. After anodic oxidation of many metals, NiCl2 and AgCl were insoluble in the propylene carbonate system; NiCl2 was insoluble in the AlCl3-ethyl pyridinium bromide-toluene solution.

Electrolytes for Lithium and Lithium-Ion Batteries

Electrolytes for Lithium and Lithium-Ion Batteries
Author: T. Richard Jow
Publisher: Springer
Total Pages: 488
Release: 2014-05-06
Genre: Technology & Engineering
ISBN: 1493903020

Electrolytes for Lithium and Lithium-ion Batteries provides a comprehensive overview of the scientific understanding and technological development of electrolyte materials in the last several years. This book covers key electrolytes such as LiPF6 salt in mixed-carbonate solvents with additives for the state-of-the-art Li-ion batteries as well as new electrolyte materials developed recently that lay the foundation for future advances. This book also reviews the characterization of electrolyte materials for their transport properties, structures, phase relationships, stabilities, and impurities. The book discusses in-depth the electrode-electrolyte interactions and interphasial chemistries that are key for the successful use of the electrolyte in practical devices. The Quantum Mechanical and Molecular Dynamical calculations that has proved to be so powerful in understanding and predicating behavior and properties of materials is also reviewed in this book. Electrolytes for Lithium and Lithium-ion Batteries is ideal for electrochemists, engineers, researchers interested in energy science and technology, material scientists, and physicists working on energy.

Electrochemistry in Nonaqueous Solutions

Electrochemistry in Nonaqueous Solutions
Author: Kosuke Izutsu
Publisher: John Wiley & Sons
Total Pages: 432
Release: 2009-09-22
Genre: Science
ISBN: 9783527629169

An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.

Polymer Electrolytes

Polymer Electrolytes
Author: Tan Winie
Publisher: John Wiley & Sons
Total Pages: 416
Release: 2020-02-18
Genre: Science
ISBN: 3527342001

A comprehensive overview of the main characterization techniques of polymer electrolytes and their applications in electrochemical devices Polymer Electrolytes is a comprehensive and up-to-date guide to the characterization and applications of polymer electrolytes. The authors ? noted experts on the topic ? discuss the various characterization methods, including impedance spectroscopy and thermal characterization. The authors also provide information on the myriad applications of polymer electrolytes in electrochemical devices, lithium ion batteries, supercapacitors, solar cells and electrochromic windows. Over the past three decades, researchers have been developing new polymer electrolytes and assessed their application potential in electrochemical and electrical power generation, storage, and conversion systems. As a result, many new polymer electrolytes have been found, characterized, and applied in electrochemical and electrical devices. This important book: -Reviews polymer electrolytes, a key component in electrochemical power sources, and thus benefits scientists in both academia and industry -Provides an interdisciplinary resource spanning electrochemistry, physical chemistry, and energy applications -Contains detailed and comprehensive information on characterization and applications of polymer electrolytes Written for materials scientists, physical chemists, solid state chemists, electrochemists, and chemists in industry professions, Polymer Electrolytes is an essential resource that explores the key characterization techniques of polymer electrolytes and reveals how they are applied in electrochemical devices.

Electrolytes, Interfaces and Interphases

Electrolytes, Interfaces and Interphases
Author: Kang Xu
Publisher: Royal Society of Chemistry
Total Pages: 841
Release: 2023-04-12
Genre: Science
ISBN: 1839163100

The authoritative textbook for those who want to enter the field of electrochemical energy storage research.

The Lithium Air Battery

The Lithium Air Battery
Author: Nobuyuki Imanishi
Publisher: Springer Science & Business Media
Total Pages: 327
Release: 2014-04-10
Genre: Technology & Engineering
ISBN: 1489980628

Lithium air rechargeable batteries are the best candidate for a power source for electric vehicles, because of their high specific energy density. In this book, the history, scientific background, status and prospects of the lithium air system are introduced by specialists in the field. This book will contain the basics, current statuses, and prospects for new technologies. This book is ideal for those interested in electrochemistry, energy storage, and materials science.