Electrochemistry in Nonaqueous Solutions

Electrochemistry in Nonaqueous Solutions
Author: Kosuke Izutsu
Publisher: John Wiley & Sons
Total Pages: 432
Release: 2009-09-22
Genre: Science
ISBN: 9783527629169

An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.

Coordination Chemistry in Non-Aqueous Solutions

Coordination Chemistry in Non-Aqueous Solutions
Author: Victor Gutmann
Publisher: Springer Science & Business Media
Total Pages: 181
Release: 2012-12-06
Genre: Science
ISBN: 3709181941

Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.

Ph Measurements

Ph Measurements
Author: C Westcott
Publisher: Elsevier
Total Pages: 185
Release: 2012-12-02
Genre: Science
ISBN: 0323160603

pH Measurements is a seven-chapter simplified text on obtaining a high degree of accuracy in practical pH measurement. The introductory chapter of this book relates the principles of pH measurements to the actual measurement. This chapter specifically tackles the factors involved in the measurement and what magnitude of effect does each factor have on the measurement. These topics are followed by discussions on the components of pH equipment and technique, including the electrodes and buffers. A chapter considers the general approach of pH measurements and illustrates with examples of some common difficult samples. The concluding chapter shows the isolation and correction a pH equipment malfunction. pH equipment operators and users will find this book rewarding.

Diffusion and Electrophoretic NMR

Diffusion and Electrophoretic NMR
Author: Peter Stilbs
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 482
Release: 2019-08-19
Genre: Technology & Engineering
ISBN: 3110551659

Diffusion and Eletrophoretic NMR experiments resolve chemical compounds based on their molecular motion. This publication introduces the basics of these methods and explains how they can be used to measure the size of molecules and aggregates, to determine degree of polymerization and to solve other chemical problems. Supplied with many case studies, the book is a must-have for students and researchers who work with practical NMR measurements.

Buffers for pH and Metal Ion Control

Buffers for pH and Metal Ion Control
Author: D. Perrin
Publisher: Springer Science & Business Media
Total Pages: 138
Release: 2012-12-06
Genre: Science
ISBN: 9400958749

This book is intended as a practical manual for chemists, biologists and others whose work requires the use of pH or metal-ion buffers. Much information on buffers is scattered throughout the literature and it has been our endeavour to select data and instructions likely to be helpful in the choice of suitable buffer substances and for the preparation of appropriate solutions. For details of pH measurement and the preparation of standard acid and alkali solutions the reader is referred to a companion volume, A. Albert and E. P. Serjeant's The Determination of Ionization Constants (1971). Although the aims of the book are essentially practical, it also deals in some detail with those theoretical aspects considered most helpful to an understanding of buffer applications. We have cast our net widely to include pH buffers for particular purposes and for measurements in non-aqueous and mixed solvent systems. In recent years there has been a significant expansion in the range of available buffers, particularly for biological studies, largely in conse quence of the development of many zwiUerionic buffers by Good et al. (1966). These are described in Chapter 3.

Nonaqueous Electrochemistry

Nonaqueous Electrochemistry
Author: Doron Aurbach
Publisher: CRC Press
Total Pages: 980
Release: 1999-07-27
Genre: Science
ISBN: 9780824741389

An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.

Non-Aqueous Solutions – 5

Non-Aqueous Solutions – 5
Author: J. B. Gill
Publisher: Elsevier
Total Pages: 131
Release: 2013-10-22
Genre: Science
ISBN: 1483155714

Non-Aqueous Solutions — 5 is a collection of lectures presented at the Fifth International Conference on Non-Aqueous Solutions held in Leeds, England, on July 5-9, 1976. The papers explore reactions in non-aqueous solutions as well as the thermodynamic and kinetic properties of non-aqueous solutions. Examples of the use of spectroscopic techniques are presented, and solutions in molten salts are given. Metals in solution and liquid metal solutions are also considered. This book is comprised of 12 chapters and begins with a review of a general scheme which considers the species formed by cation-electron and electron-electron interactions at dilute to moderate concentrations, along with the influence of the solvent and the metal on these interactions. The discussion then shifts to the application of electron spin resonance spectroscopy to the study of solvation; the influence of solvent properties on ligand substitution mechanisms of labile complexes; and the effect of acidity on chemical reactions in molten salts. Subsequent chapters deal with the chemistry of solutions of salts in liquid alkali metals; preferential solvation in kinetics; and the use of non-aqueous solvents for preparation and reactions of nitrogen halogen compounds. Results of Raman spectroscopic studies of non-aqueous solutions and spectroscopic studies of coordination compounds formed in molten salts are also presented. This monograph will be of interest to chemists.

Vanadium

Vanadium
Author: Alan S. Tracey
Publisher: CRC Press
Total Pages: 266
Release: 2007-03-19
Genre: Medical
ISBN: 1420046144

The first comprehensive resource on the chemistry of vanadium, Vanadium: Chemistry, Biochemistry, Pharmacology, and Practical Applications has evolved from over a quarter century of research that concentrated on delineating the aqueous coordination reactions that characterize the vanadium(V) oxidation state. The authors distill information o