Molecular Ions
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| Author | : A.A. Radzig |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 475 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 3642820484 |
This reference book contains information about the structure and properties of atomic and molecular particles, as well as some of the nuclear parameters. It includes data which can be of use when studying atomic and molecular processes in the physics of gases, chemistry of gases and gas optics, in plasma physics and plasma chemistry, in physical chemistry and radiation chemistry, in geophysics, astrophysics, solid-state physics and a variety of cross-discipli nary fields of science and technology. Our aim was to collect carefully selected and estimated numerical values for a wide circle of microscopic parameters in a relatively "not thick" book. These values are of constant use in the work of practical investigators. In essence, the book represents a substantially revised and extended edi tion of our reference book published in Russian in 1980. Two main reasons made it necessary to rework the material. On the one hand, a great deal of new high-quality data has appeared in the past few years and furthermore we have enlisted many sources of information previously inaccessible to us. On the other hand, we have tried to insert extensive information on new, rapidly progressing branches of physical research, such as multiply charged ions, Rydberg atoms, van der Waals and excimer molecules, complex ions, etc. All this brings us to the very edge of studies being carried out in the field.
| Author | : Joseph Berkowitz |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 597 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 1461336643 |
The present volume contains contributions presented at the NATO Advanced Study Institute on Molecular Ions held on the island of Kos, Greece, from September 30 to October 10, 1980. The meeting was attended by some 60 participants from 15 different countries. It was the first meeting devoted exclusively to the topic of molecular ions. Its vitality derived from bringing together experts and students from a wide variety of disciplines, whose studies bear upon the structure of molecular ions. The aim of the meeting was to assemble these scientists, representing many countries in Europe and North America, to discuss the advances and capabilities of the various experimental and theoretical approaches and to point out un solved problems and directions for future research. The format, in volving lecturers and students, served as a tutorial. Molecular ions play an important role in very diverse fields of nature such as reactions in the ionosphere, the processes of forma tion of molecules in dense interstellar clouds, and the magnetohydro dynamics of plasmas used for energy generation. Our understanding of the properties of molecular ions, their electronic and geometric structures, has been developing from a variety of sources, as far removed as tickling ions with radiofre quency radiation and smashing them apart at relativistic energies. Various laser techniques are described, and the queen of structural determination, spectroscopy, is well represented. On the instrumen tal side, older techniques have been perfected and new methods have evolved.
| Author | : Steven L. Guberman |
| Publisher | : Springer |
| Total Pages | : 0 |
| Release | : 2012-10-13 |
| Genre | : Science |
| ISBN | : 9781461349150 |
Dissociative Recombination of Molecular Ions with Electrons is a comprehensive collection of refereed papers describing the latest developments in dissociative recombination research. The papers are written by the leading researchers in the field. The topics covered include the use of microwave afterglows, merged beams and storage rings to measure rate coefficients and to identify the products and their yields. The molecules studied range in size from the smallest, H2+, to bovine insulin ions. The theoretical papers cover the important role of Rydberg states and the use of wave packets and quantum defect theory to deduce cross sections, rate constants and quantum yields. Several theoretical and experimental papers address the controversial topic of H3+ dissociative recombination and its importance in the interstellar medium. Dissociative recombination studies of other molecular ions in the interstellar medium and in cometary and planetary atmospheres are covered. Ionization is an important competitive process to dissociative recombination and its competition with predissociation and its role in the reverse process of the association of neutral species is presented. Dissociative attachment, in which an electron attaches to a neutral molecule, has many similarities to dissociative recombination. The topics covered include the accurate calculation of electron affinities, attachment to molecules, clusters, and to species absorbed on solid surfaces and electron scattering by a molecular anion.
| Author | : Eugen Illenberger |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 357 |
| Release | : 2013-03-09 |
| Genre | : Science |
| ISBN | : 3662073838 |
Most of the matter in our solar system, and, probably, within the whole universe, exists in the form of ionized particles. On the other hand, in our natural environ ment, gaseous matter generally consists of neutral atoms and molecules. Only under certain conditions, such as within the path oflightning or in several technical devices (e. g. gas discharges, rocket engines, etc. ) will some of the atoms and molecules be ionized. It is also believed that the chemistry of the earth's troposphere predomi nantly proceeds via reactions between neutral particles. (The complex system of atmospheric chemistry will be treated in one of the forthcoming volumes to this series. ) Why, then, are ions considered so important that hundreds oflaboratories all over the world (including some of the most prestigious) are involved in research pro grams on ions, covering many different facets, from biochemistry to physics? One may obtain as many different answers as there are research groups busy in this field. There is, however, one simple, common feature which makes it attractive to work with ions: since they carry one or more net elementary charges, they can easily be gui ded, focused or separated by appropriate electric and magnetic fields, and, last but not least, they can easily be detected. Apart from these advantages, which are welcome and appreciated by the researcher, the study of molecular ions can provide insight into very fundamental aspects of the general behavior of molecules.
| Author | : Leon Panetta |
| Publisher | : DIANE Publishing |
| Total Pages | : 8 |
| Release | : 2012-05 |
| Genre | : Education |
| ISBN | : 9781422318843 |
| Author | : Steven L. Guberman |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 467 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 1461500834 |
Dissociative Recombination of Molecular Ions with Electrons is a comprehensive collection of refereed papers describing the latest developments in dissociative recombination research. The papers are written by the leading researchers in the field. The topics covered include the use of microwave afterglows, merged beams and storage rings to measure rate coefficients and to identify the products and their yields. The molecules studied range in size from the smallest, H2+, to bovine insulin ions. The theoretical papers cover the important role of Rydberg states and the use of wave packets and quantum defect theory to deduce cross sections, rate constants and quantum yields. Several theoretical and experimental papers address the controversial topic of H3+ dissociative recombination and its importance in the interstellar medium. Dissociative recombination studies of other molecular ions in the interstellar medium and in cometary and planetary atmospheres are covered. Ionization is an important competitive process to dissociative recombination and its competition with predissociation and its role in the reverse process of the association of neutral species is presented. Dissociative attachment, in which an electron attaches to a neutral molecule, has many similarities to dissociative recombination. The topics covered include the accurate calculation of electron affinities, attachment to molecules, clusters, and to species absorbed on solid surfaces and electron scattering by a molecular anion.
| Author | : Jesús Pérez Ríos |
| Publisher | : Springer Nature |
| Total Pages | : 278 |
| Release | : 2020-11-05 |
| Genre | : Science |
| ISBN | : 303055936X |
This book provides advanced undergraduate and graduate students with an overview of the fundamentals of cold and ultracold chemistry. Beginning with definitions of what cold and ultracold temperatures mean in chemistry, the book then takes the student through the essentials of scattering theory (classical and quantum mechanical), light-matter interaction, reaction dynamics and Rydberg physics. The author aims to show the reader the richness of the topic while motivating students to understand the fundamentals of these intriguing reactions and underlying connecting relationships. Including material which was previously only found in specialized review articles, this book provides students working in the fields of ultracold gases, chemical physics and physical chemistry with the tools they need to immerse themselves in the realm of cold and ultracold chemistry. This book opens up the exciting chemical laws which govern chemistry at low temperatures to the next generation of researchers.
| Author | : Ch Ottinger |
| Publisher | : |
| Total Pages | : 52 |
| Release | : 1968 |
| Genre | : Dissociation |
| ISBN | : |
The time interval between the ionization of a molecule by electron impact and its dissociation was determined from the kinetic energy of the fragment ions. This technique allows a direct differential sampling of the dissociation rate at various times, in contrast to previous, integral methods. The use of disc-shaped molecular beam of 28 micrometers half-width and a draw-out field of 10,000 V/cm in the ionization region resulted in a minimum measured time interval of 7.4 nonoseconds. The longest times measured were between 5 and 6 microseconds. The time dependence of the decomposition rate was measured for two decompositions in butane, five in heptane, three in benzene, one in CD4 and one in CO2(++), with rather similar results. It was established that the decay is not exponential. All decay curves, plotted semi-logarithmically, were found to have an increasing slope towards shorter times, indicating contributions from a variety of rate constants in agreement with the predictions of the statistical theory of ion decompositions.
| Author | : |
| Publisher | : |
| Total Pages | : 18 |
| Release | : 1964 |
| Genre | : |
| ISBN | : |
| Author | : |
| Publisher | : |
| Total Pages | : 0 |
| Release | : 2002 |
| Genre | : Cells |
| ISBN | : 9780815332183 |
