Hybrid Metal-Organic Framework and Covalent Organic Framework Polymers

Hybrid Metal-Organic Framework and Covalent Organic Framework Polymers
Author: Bo Wang
Publisher: Royal Society of Chemistry
Total Pages: 313
Release: 2021-11-12
Genre: Technology & Engineering
ISBN: 1839163461

Metal–organic frameworks (MOFs) are crystalline porous materials constructed from metal ions/clusters and organic linkers, combining the merits of both organic and inorganic components. Due to high porosity, rich functionalities, well-defined open channels and diverse structures, MOFs show great potentials in field such as gas storage and separation, catalysis, and sensing. Combining them with polymers tunes their chemical, mechanical, electrical and optical properties, and endows MOFs with processability. Covalent organic frameworks (COFs) are crystalline porous materials built from organic molecular units with diverse structures and applications. Hybrid materials with intriguing properties can be achieved by appropriate preparation methods and careful selection of MOFs/COFs and polymers, broadening their potential applications. This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites. It also introduces various applications and potential applicable scenarios of hybrid MOF/COF polymers. Hybrid Metal–Organic Framework and Covalent Organic Framework Polymers offers an overview to readers who are new to this field, and will appeal to graduate students and researchers working on porous materials, polymers, hybrid materials, and supramolecular chemistry.

Semiconducting and Metallic Polymers

Semiconducting and Metallic Polymers
Author: Alan J. Heeger
Publisher: OUP Oxford
Total Pages: 288
Release: 2010-07-29
Genre: Science
ISBN: 0198528647

The unique properties of conducting and semiconducting (conjugated) polymers make them one of the most attractive areas of interdisciplinary materials science and technology. Written by a pioneer in the field, this book is the first aimed at teaching graduate students, postdoctoral scientists, and specialists in industry about this exciting field.

Metal-Polymer Systems

Metal-Polymer Systems
Author: Jörg Florian Friedrich
Publisher: John Wiley & Sons
Total Pages: 447
Release: 2017-09-13
Genre: Technology & Engineering
ISBN: 3527679928

The result of decades of research by a pioneer in the field, this is the first book to deal exclusively with achieving high-performance metal-polymer composites by chemical bonding. Covering both the academic and practical aspects, the author focuses on the chemistry of interfaces between metals and polymers with a particular emphasis on the chemical bonding between the different materials. He elucidates the various approaches to obtaining a stable interface, including, but not limited to, thermodynamically driven redox reactions, bond protection to prevent hydrolysis, the introduction of barrier layers, and stabilization by spacer molecules. Throughout, chemical bonding is promoted as a simple and economically viable alternative to adhesion based on reversible weak physical interaction. Consequently, the text equips readers with the practical tools necessary for designing high-strength metal-polymer composites with such desired properties as resilience, flexibility, rigidity or degradation resistance.

Polymers for Biomedical Applications

Polymers for Biomedical Applications
Author: Anil Mahapatro
Publisher: American Chemical Society
Total Pages: 442
Release: 2008-04-17
Genre: Medical
ISBN:

Research on applications of polymers for biomedical applications has increased dramatically to find improved medical plastics for this rapidly evolving field. This book brings together various aspects of recent research and developments within academia and industry related to polymers for biomedical applications.

Going to Extremes

Going to Extremes
Author: National Research Council
Publisher: National Academies Press
Total Pages: 80
Release: 2005-10-22
Genre: Technology & Engineering
ISBN: 0309097150

Advanced polymer matrix composites (PMC) have many advantages such as light weight and high specific strength that make them useful for many aerospace applications. Enormous uncertainty exists, however, in predicting long-term changes in properties of PMCs under extreme environmental conditions, which has limited their use. To help address this issue, the Department of Defense requested a study from the NRC to identify the barriers and limitations to the use of PMCs in extreme environments. The study was to focus on issues surrounding methodologies for predicting long-term performance. This report provides a review of the challenges facing application of PMCs in extreme environments, the current understanding of PMC properties and behavior, an analysis of the importance of data in developing effective models, and recommendations for improving long-term predictive methodologies.

Synthesis and Polymerization of Metal-Containing Monomers

Synthesis and Polymerization of Metal-Containing Monomers
Author: Anatoly D. Pomogailo
Publisher: CRC Press
Total Pages: 176
Release: 2018-01-31
Genre: Science
ISBN: 1351085506

This book overviews methods for the synthesis of metal-containing monomers with various types of metal bonds to the organic moiety of the molecule, such as ionic, covalent, donor-acceptor, and others. Published data on homopolymerization, copolymerization, and graft polymerization of these monomers are generalized. Synthesis and Polymerization of Metal-Containing Monomers discusses features typical of the molecular and structural organization of the resulting metal-containing polymers, their properties and the associated major applications, such as catalytical and biological activity, electrophysical characteristics, and thermal resistance.

Polymer Derived Ceramics

Polymer Derived Ceramics
Author: Paolo Colombo
Publisher: DEStech Publications, Inc
Total Pages: 490
Release: 2010
Genre: Technology & Engineering
ISBN: 1605950009

This book presents the foundations of the science of polymer derived ceramics, enriched with many descriptions of applications. Written by a team of selected researchers, the text is a systematic, comprehensive introduction to all phases of polymer derived ceramics from synthesis strategies through properties measurement, and applications. New material is given on the nanolevel structure of PDCs, and it is shown how nano-sized modifications can alter and improve the properties of polymer derived ceramics, including high chemical durability, oxidation resistance, luminescence, and piezo-resistivity. Groundbreaking work is also described on novel precursors such as stoichiometric SiC, BN, and SiBCN ceramics. In terms of technology, this volume explains how PDCs are fabricated and how these novel materials are used in membranes, filters, MEMS, fibers, and micro-components. This book covers: synthesis, structure, properties and applications; strategies for characterizing and synthesizing PDCs; and, original research on pre-ceramic PDC precursors.

Metallo-Supramolecular Polymers

Metallo-Supramolecular Polymers
Author: Masayoshi Higuchi
Publisher: Springer Nature
Total Pages: 92
Release: 2019-11-12
Genre: Technology & Engineering
ISBN: 4431568913

This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.

Organometallic Polymers

Organometallic Polymers
Author: Charles E. Jr. Carraher
Publisher: Elsevier
Total Pages: 368
Release: 2012-12-02
Genre: Science
ISBN: 0323153909

Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.

Materials Science and Engineering

Materials Science and Engineering
Author: William D. Callister, Jr.
Publisher: Wiley Global Education
Total Pages: 980
Release: 2018-02-23
Genre: Technology & Engineering
ISBN: 1119405432

Materials Science and Engineering: An Introduction promotes student understanding of the three primary types of materials (metals, ceramics, and polymers) and composites, as well as the relationships that exist between the structural elements of materials and their properties. The Enhanced E-Text is also available bundled with an abridged print companion and can be ordered by contacting customer service here: ISBN: 9781119463153 Price: $97.95 Canadian Price: $111.50