High Resolution Gas Phase Infrared Absorption Spectra of Simple Gases

High Resolution Gas Phase Infrared Absorption Spectra of Simple Gases
Author: John Overend
Publisher:
Total Pages: 13
Release: 1973
Genre:
ISBN:

A study has been made of the infrared spectra of simple gases under conditions of very high resolution. Most of the measurements have been made in the spectral region between 2000-400/cm. The molecules which have been studied are CS2, ethylene, methylfluoride and formaldehyde-d2. The spectra have been assigned in considerable detail and the wavenumbers of the assigned lines have been analyzed to yield fundamental data on the structure of these molecules. It appears that the results of this study will have not only fundamental importance but also immediate practical value since the infrared spectra are useful for the determination of concentrations of atmospheric pollutants. (Author).

High Resolution Infrared Spectroscopy of Carbon Dioxide and Nitrous Oxide at Elevated Temperatures

High Resolution Infrared Spectroscopy of Carbon Dioxide and Nitrous Oxide at Elevated Temperatures
Author: Mark P. Esplin
Publisher:
Total Pages: 72
Release: 1988
Genre: Atmospheric carbon dioxide
ISBN:

Although both Carbon Dioxide and Nitrous Oxide are minor constituents of the terrestrial atmosphere, they play leading roles in several current atmospheric problems. Both CO2 and N2O are greenhouse gases, and while it is known that the atmospheric concentrations of both gases is increasing, the impact of these trends on global temperature is not yet adequately understood. In addition to being a greenhouse gas, N2O plays an indirect part in ozone chemistry. Heating a molecule makes possible the observations of molecular transitions originating from highly excited rotation-vibration states. Heating a molecule makes possible the observations of molecular transitions originating from highly excited rotation-vibration states. These observations can then be used to characterize the shape of the molecular potential function at increasing distances from the minimum of the potential function. The infrared spectra of linear molecules like CO2 and N2O are composed of vibration bands made up of a number of nearly equally spaced rotation lines. A Fourier Spectrometer is ideally suited to the study of high temperature gases since it meets both of these needs by providing high resolution over a wide spectral region.