Flow-induced Structure in Polymers

Flow-induced Structure in Polymers
Author: Alan I. Nakatani
Publisher:
Total Pages: 386
Release: 1995
Genre: Science
ISBN:

Examines recent advances in understanding the structures of polymer melts, polymer solutions, block copolymers, liquid crystalline polymers, colloid suspensions, and multiphase systems subjected to flow. Reports on advances in instrumental techniques, characterization, theories, and applications. An overview chapter provides a guide and reference source to related reviews and identifies similarities in flow behavior between various materials science disciplines.

Rheo-Physics of Multiphase Polymer Systems

Rheo-Physics of Multiphase Polymer Systems
Author: Kai Sondergaard
Publisher: CRC Press
Total Pages: 604
Release: 1995-06-02
Genre: Technology & Engineering
ISBN: 9781566761567

FROM THE PREFACE Almost all polymeric systems are subjected to a flow field at least once along the route between preparation and application. . . . There is also an increased interest in predictive models on phase behavior and suitable techniques for characterizing the structure of these systems when subjected to flow. Multiphase polymeric systems are particularly susceptible to flow, which may cause orientation of species, morphological changes, and phase transitions. All these events may, in turn, affect the end product properties, such as permeability, electrical conductivity, [and] mechanical properties. In processing, escalating needs have evolved for optimization and development of novel and more uniform product properties and increased productivity. In order to arrive at an understanding of processing polymeric systems under elastic flow conditions, it is convenient to analyze the basic physical mechanisms under conditions that enable development of predictive models in conjunction with controlled experimentation. . . . In recent years, the science of rheo-physics has evolved and now involves both advanced theories and experimental techniques. Rheo-physics means the rheological, morphological, and thermodynamic behavior of structured polymer systems during flow. . . . In this monograph, the rheo-optical techniques are . . . emphasized. The book gives an introduction to rheo-physics, including fundamentals of theories, and a representative selection of applications of rheo-optical techniques for analyzing multiphase systems. The chapters contain both practical advice for the new experimenter . . . as well as review material for the experienced scientist.

Flow-Induced Crystallization of Polymers

Flow-Induced Crystallization of Polymers
Author: Gaetano Guerra
Publisher: Wiley-VCH
Total Pages: 360
Release: 2002-12-20
Genre: Science
ISBN:

In polymer processing, the molecular orientation induced by flow has a significant effect on the crystallization kinetics and final morphology of the polymer produced. The impact on processing operations and object properties is extremely important and recently scientific and technological researchers have begun to quanitify these effects. The international conference 'Flow-Induced Crystallization of Polymers', held in October 2001 in Salerno, Italy, was timely and well attended. An interdisciplinary approach was taken and presentations were made on topics ranging from real-time measurement, through modelling, to final morphology and properties of polymers. Invited and other selected contributions from the conference are collected here, in this volume of Macromolecular Symposia

Flow-Induced Alignment in Composite Materials

Flow-Induced Alignment in Composite Materials
Author: T.D. Papathanasiou
Publisher: Woodhead Publishing
Total Pages: 399
Release: 2021-10-19
Genre: Technology & Engineering
ISBN: 0128185759

The purpose of aligning short fibers in a fiber-reinforced material is to improve the mechanical properties of the resulting composite. Aligning the fibers, generally in a preferred direction, allows them to contribute as much as possible to reinforcing the material. The first edition of this book detailed, in a single volume, the science, processing, applications, characterization and properties of composite materials reinforced with short fibers that have been orientated in a preferred direction by flows arising during processing. The technology of fiber-reinforced composites is continually evolving and this new edition provides timely and much needed information about this important class of engineering materials. Each of the original chapters have been brought fully up-to-date and new developments such as: the advent of nano-composites and the issues relating to their alignment; the wider use of long-fiber composites and the appearance of models able to capture their orientation during flow; the wider use of flows in micro-channels in the context of composites fabrication; and the increase in computing power, which has made relevant simulations (especially coupling flow kinematics to fiber content and orientation) much easier to perform are all covered in detail. The book will be an essential up-to-date reference resource for materials scientists, students, and engineers who are working in the relevant areas of particulate composites, short fiber-reinforced composites or nanocomposites. - Presents recent progress on flow-induced alignment, modelling and design of fiber and particulate filled polymer composites - Discusses important advances such as alignment of CNTs in polymer nanocomposites and molecular alignment of polymers induced by the injection molding process in the presence of fillers such as short fibers - Presents fiber interaction/diffusion modelling and also the fiber flexure/breakage models

Structure and Properties of Multiphase Polymeric Materials

Structure and Properties of Multiphase Polymeric Materials
Author: Takeo Araki
Publisher: CRC Press
Total Pages: 480
Release: 1998-03-03
Genre: Science
ISBN: 9780824701420

Offers an overview of recent advances in multiphase polymeric materials, ranging from theoretical aspects of polymer miscibility and phase separation kinetics to bulk, surface and interface properties in polymeric materials. This work considers the possibility of a nondestructive methodology to investigative multiphase polymers based mainly on a scattering technique that is sensitive to changes in the phase behaviour of multicomponent polymer systems.

Progress in Understanding of Polymer Crystallization

Progress in Understanding of Polymer Crystallization
Author: Günter Reiter
Publisher: Springer Science & Business Media
Total Pages: 521
Release: 2007-02-05
Genre: Technology & Engineering
ISBN: 354047305X

In the context of polymer crystallization there are several still open and often controversially debated questions. The present volume addresses issues such as novel general views and concepts. It presents new ideas in a connected and accessible way. The intention is thus not only to provide a summary of the present state-of-the-art to all active works but to provide an entry point to newcomer and graduate students entering the field.

Handbook of Polymer Crystallization

Handbook of Polymer Crystallization
Author: Ewa Piorkowska
Publisher: John Wiley & Sons
Total Pages: 514
Release: 2013-05-30
Genre: Technology & Engineering
ISBN: 1118541804

Polymeric crystals are more complex in nature than other materials' crystal structures due to significant structural disorder present. The only comprehensive reference on polymer crystallization, Handbook of Polymer Crystallization provides readers with a broad, in-depth guide on the subject, covering the numerous problems encountered during crystallization as well as solutions to resolve those problems to achieve the desired result. Edited by leading authorities in the field, topics explored include neat polymers, heterogeneous systems, polymer blends, polymer composites orientation induced crystallization, crystallization in nanocomposites, and crystallization in complex thermal processing conditions.

Characterization and Analysis of Polymers

Characterization and Analysis of Polymers
Author: Wiley
Publisher: John Wiley & Sons
Total Pages: 987
Release: 2008-02-08
Genre: Technology & Engineering
ISBN: 0470233001

Based on Wiley's renowned Encyclopedia of Polymer Science and Technology, this book provides coverage of key methods of characterization of the physical and chemical properties of polymers, including atomic force microscopy, chromatographic methods, laser light scattering, nuclear magnetic resonance, and thermal analysis, among others. Written by prominent scholars from around the world, this reference presents over twenty-five self -contained articles on the most used analytical techniques currently practiced in polymer science.

Polymer Crystallization

Polymer Crystallization
Author: Günter Reiter
Publisher: Springer
Total Pages: 402
Release: 2008-01-11
Genre: Science
ISBN: 3540458514

The classical view on polymer crystallization basically focused on the expla- tion of a few macroscopically observable parameters like the thickness of the resulting lamellar structure and the corresponding growth rates. However, the emerging paradigm for the description of chain crystals is too simple and cannot account for the complex non-equilibrium processes responsible for structure f- mation on various levels, ranging from the nanometer up to the millimeter scale. This complexity detected by several novel experimental results led to a renewed interest in this ”old” topic of polymer crystallization. These new ?ndings c- cern the early stages of the crystallization process, crystal formation in con?ned geometries like ultra-thin ?lms and the competition between (micro)phase s- aration and crystallization in copolymers and blends. In particular, high spatial resolution techniques such as atomic force microscopy provided deeper insight into the molecular organization of crystallizable polymers. Computer simu- tions based on microscopic processes were used to improve our understanding of how polymer crystals are nucleated and how they grow. New ideas emerged about possible multistage pathways which are followed during the formation of polymer lamellae. The importance and the consequences of the non-equilibrium character of polymer crystals got signi?cantly more attention. Links and ana- gies to growth phenomena and pattern formation in general are being developed. However, these ideas are still subject of intensive and controversial discussions.