Nanoscale Electrochemistry of Molecular Contacts

Nanoscale Electrochemistry of Molecular Contacts
Author: Paulo Roberto Bueno
Publisher: Springer
Total Pages: 98
Release: 2018-12-29
Genre: Science
ISBN: 3319904876

This book discusses the merging of nanoscale electronics and electrochemistry and how this can potentially modernize the way electronic devices are currently engineered or constructed. It introduces the electrochemical capacitance as a fundamental missing concept that solves the puzzle between molecular electronics and electrochemistry at the nanoscale. The electrochemical capacitance, as a fundamental principle, is deduced from first principles quantum mechanics. The text also confirmed that faradaic and non-faradaic processes are only different physical approximations of the same sort of energetic phenomenon.The book comprises three chapters. Chapter one introduces the concepts of chemical capacitance, relaxation resistance, and the quantum resistive-capacitive circuit and demonstrates how these elements are translated to the electrochemistry context. In chapter two, the chemical capacitance, the fundamental concept and missing part of the puzzle that unity electronics and electrochemistry, is deduced from first principles of quantum mechanics. In chapter three, the concepts are practically used in different contexts that include molecular diagnostics, molecular conductance and super-capacitive phenomena is explained using the introduced basic principles.

Molecular Nanowires and Other Quantum Objects

Molecular Nanowires and Other Quantum Objects
Author: Alexandre S. Alexandrov
Publisher: Springer Science & Business Media
Total Pages: 434
Release: 2004-04-30
Genre: Technology & Engineering
ISBN: 1402020937

There is a growing understanding that the progress of the conventional silicon technology will reach its physical, engineering and economic limits in near future. This fact, however, does not mean that progress in computing will slow down. What will take us beyond the silicon era are new nano-technologies that are being pursued in university and corporate laboratories around the world. In particular, molecular switching devices and systems that will self-assemble through molecular recognition are being designed and studied. Many labora tories are now testing new types of these and other reversible switches, as well as fabricating nanowires needed to connect circuit elements together. But there are still significant opportunities and demand for invention and discovery be fore nanoelectronics will become a reality. The actual mechanisms of transport through molecular quantum dots and nanowires are of the highest current ex perimental and theoretical interest. In particular, there is growing evidence that both electron-vibron interactions and electron-electron correlations are impor tant. Further progress requires worldwide efforts of trans-disciplinary teams of physicists, quantum chemists, material and computer scientists, and engineers.

Charge and Exciton Transport through Molecular Wires

Charge and Exciton Transport through Molecular Wires
Author: Laurens D. A. Siebbeles
Publisher: John Wiley & Sons
Total Pages: 293
Release: 2011-07-18
Genre: Technology & Engineering
ISBN: 352763309X

As functional elements in opto-electronic devices approach the singlemolecule limit, conducting organic molecular wires are the appropriate interconnects that enable transport of charges and charge-like particles such as excitons within the device. Reproducible syntheses and a thorough understanding of the underlying principles are therefore indispensable for applications like even smaller transistors, molecular machines and light-harvesting materials. Bringing together experiment and theory to enable applications in real-life devices, this handbook and ready reference provides essential information on how to control and direct charge transport. Readers can therefore obtain a balanced view of charge and exciton transport, covering characterization techniques such as spectroscopy and current measurements together with quantitative models. Researchers are thus able to improve the performance of newly developed devices, while an additional overview of synthesis methods highlights ways of producing different organic wires. Written with the following market in mind: chemists, molecular physicists, materials scientists and electrical engineers.

Oxford Handbook of Nanoscience and Technology

Oxford Handbook of Nanoscience and Technology
Author: A. V. Narlikar
Publisher: OUP Oxford
Total Pages: 919
Release: 2010-02-11
Genre: Science
ISBN: 0191035513

This is an agenda-setting and high-profile book that presents an authoritative and cutting-edge analysis of nanoscience and technology. The Oxford Handbook of Nanoscience and Technology provides a comprehensive and accessible overview of the major achievements in different aspects of this field. The Handbook comprises 3 volumes, structured thematically, with 25 chapters each. Volume I presents fundamental issues of basic physics, chemistry, biochemistry, tribology etc. of nanomaterials. Volume II focuses on the progress made with host of nanomaterials including DNA and protein based nanostructures. Volume III highlights engineering and related developments, with a focus on frontal application areas. All chapters are written by noted international experts in the field. The book should be useful for final year undergraduates specializing in the field. It should prove indispensable to graduate students, and serious researchers from academic and industrial sectors working in the field of Nanoscience and Technology from different disciplines including Physics, Chemistry, Biochemistry, Biotechnology, Medicine, Materials Science, Metallurgy, Ceramics, Information Technology as well as Electrical, Electronic and Computational Engineering.

Energy Level Alignment and Electron Transport Through Metal/Organic Contacts

Energy Level Alignment and Electron Transport Through Metal/Organic Contacts
Author: Enrique Abad
Publisher: Springer Science & Business Media
Total Pages: 211
Release: 2012-09-16
Genre: Science
ISBN: 3642309062

In recent years, ever more electronic devices have started to exploit the advantages of organic semiconductors. The work reported in this thesis focuses on analyzing theoretically the energy level alignment of different metal/organic interfaces, necessary to tailor devices with good performance. Traditional methods based on density functional theory (DFT), are not appropriate for analyzing them because they underestimate the organic energy gap and fail to correctly describe the van der Waals forces. Since the size of these systems prohibits the use of more accurate methods, corrections to those DFT drawbacks are desirable. In this work a combination of a standard DFT calculation with the inclusion of the charging energy (U) of the molecule, calculated from first principles, is presented. Regarding the dispersion forces, incorrect long range interaction is substituted by a van der Waals potential. With these corrections, the C60, benzene, pentacene, TTF and TCNQ/Au(111) interfaces are analyzed, both for single molecules and for a monolayer. The results validate the induced density of interface states model.

Conceptual Foundations of Materials

Conceptual Foundations of Materials
Author:
Publisher: Elsevier
Total Pages: 245
Release: 2006-09-20
Genre: Science
ISBN: 0080464572

The goal of this Volume "Conceptual Foundations of Materials: A standard model for ground- and excited-state properties" is to present the fundamentals of electronic structure theory that are central to the understanding and prediction of materials phenomena and properties. The emphasis is on foundations and concepts. The Sections are designed to offer a broad and comprehensive perspective of the field. They cover the basic aspects of modern electronic structure approaches and highlight their applications to the structural (ground state, vibrational, dynamic and thermodynamic, etc.) and electronic (spectroscopic, dielectric, magnetic, transport, etc.) properties of real materials including solids, clusters, liquids, and nanostructure materials. This framework also forms a basis for studies of emergent properties arising from low-energy electron correlations and interactions such as the quantum Hall effects, superconductivity, and other cooperative phenomena. Although some of the basics and models for solids were developed in the early part of the last century by figures such as Bloch, Pauli, Fermi, and Slater, the field of electronic structure theory went through a phenomenal growth during the past two decades, leading to new concepts, understandings, and predictive capabilities for determining the ground- and excited-state properties of real, complex materials from first principles. For example, theory can now be used to predict the existence and properties of materials not previously realized in nature or in the laboratory. Computer experiments can be performed to examine the behavior of individual atoms in a particular process, to analyze the importance of different mechanisms, or just to see what happen if one varies the interactions and parameters in the simulation. Also, with ab initio calculations, one can determine from first principles important interaction parameters which are needed in model studies of complex processes or highly correlated systems. Each time a new material or a novel form of a material is discovered, electronic structure theory inevitably plays a fundamental role in unraveling its properties. - Provides the foundations of the field of condensed matter physics - An excellent supplementary text for classes on condensed matter physics/solid state physics - Volume covers current work at the forefront - Presentations are accessible to nonspecialists, with focus on underlying fundamentals

Introducing Molecular Electronics

Introducing Molecular Electronics
Author: Gianaurelio Cuniberti
Publisher: Springer
Total Pages: 526
Release: 2006-05-21
Genre: Science
ISBN: 3540315144

Klaus von Klitzing Max-Planck-Institut fur ̈ Festk ̈ orperforschung, Heisenbergstraße 1, 70569 Stuttgart, Germany Already many Cassandras have prematurely announced the end of the silicon roadmap and yet, conventional semiconductor-based transistors have been continuously shrinking at a pace which has brought us to nowadays cheap and powerful microelectronics. However it is clear that the traditional scaling laws cannot be applied if unwanted tunnel phenomena or ballistic transport dominate the device properties. It is generally expected, that a combination of silicon CMOS devices with molecular structure will dominate the ?eld of nanoelectronics in 20 years. The visionary ideas of atomic- or molecular-scale electronics already date back thirty years but only recently advanced nanotechnology, including e.g. scanning tunneling methods and mechanically controllable break junctions, have enabled to make distinct progress in this direction. On the level of f- damentalresearch,stateofthearttechniquesallowtomanipulate,imageand probechargetransportthroughuni-molecularsystemsinanincreasinglyc- trolled way. Hence, molecular electronics is reaching a stage of trustable and reproducible experiments. This has lead to a variety of physical and chemical phenomena recently observed for charge currents owing through molecular junctions, posing new challenges to theory. As a result a still increasing n- ber of open questions determines the future agenda in this ?eld.

Spintronics with Individual Metal-organic Molecules

Spintronics with Individual Metal-organic Molecules
Author: Stefan Schmaus
Publisher: KIT Scientific Publishing
Total Pages: 120
Release: 2014-08-24
Genre: Science
ISBN: 3866446497

In this work two ideas of using individual metal organic molecules in applications for data storage are presented. On the one hand, metal-free phthalocyanine is used to form a GMR contact consisting of one single molecule leading to the world smallest magnetic sensor. On the other hand, chromium acetylacetonate was used to study the properties of magnetic molecules adsorbed on surfaces in order to build magnetic bits for date storage.

Molecular Electronics: An Introduction To Theory And Experiment

Molecular Electronics: An Introduction To Theory And Experiment
Author: Elke Scheer
Publisher: World Scientific
Total Pages: 724
Release: 2010-06-23
Genre: Science
ISBN: 9814466913

This book provides a comprehensive overview of the rapidly developing field of molecular electronics. It focuses on our present understanding of the electrical conduction in single-molecule circuits and provides a thorough introduction to the experimental techniques and theoretical concepts. It will also constitute as the first textbook-like introduction to both the experiment and theory of electronic transport through single atoms and molecules. In this sense, this publication will prove invaluable to both researchers and students interested in the field of nanoelectronics and nanoscience in general.Molecular Electronics is self-contained and unified in its presentation. It may be used as a textbook on nanoelectronics by graduate students and advanced undergraduates studying physics and chemistry. In addition, included are previously unpublished material that will help researchers gain a deeper understanding into the basic concepts involved in the field of molecular electronics.