Electrochemistry For Chemists
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Author | : Donald T. Sawyer |
Publisher | : Wiley-Interscience |
Total Pages | : 528 |
Release | : 1995-10-03 |
Genre | : Science |
ISBN | : 9780471594680 |
A complete and practical guide to the basic principles of electrochemistry for the nonspecialist Emphasizing practical applications and real-world experimentation, Electrochemistry for Chemists gives chemists, biologists, and material scientists a solid understanding of the basic principles and modern methodology of electrochemistry. Incorporating the many new applications of recent years, this thoroughly updated Second Edition gives the nonelectrochemist access to a powerful tool for the study and measurement of chemical systems. And, like the popular first edition, the Second Edition is also a useful text for senior undergraduate and graduate students, especially in organic, inorganic, and biological chemistry. * Offers a practical guide to the use of electrochemical methods in research and laboratory work * Provides examples of molecular characterization by electrochemical methods in all subdivisions of chemistry, including dioxygen species, base metals, and nonmetals * Includes numerous tables of electrochemical data, as well as physical parameters for solvents, electrolytes, cells, and electrodes * Incorporates the latest information on instrumentation, solvents, and reagents * Lists extensive references for further study of theoretical issues
Author | : Eliezer Gileadi |
Publisher | : Capstone |
Total Pages | : 620 |
Release | : 1993 |
Genre | : Science |
ISBN | : 9781560816263 |
Offering a thorough explanation of electrode kinetics, this textbook emphasizes physical phenomena - rather than mathematical formalism - and elucidates the underlying principles of the different experimental techniques. Assuming an elementary knowledge of thermodynamics and chemical kinetics and minimal mathematical skills, coverage explores the arguments of two primary schools of thought: electrode kinetics and interfacial electrochemistry viewed as a branch of physical chemistry and from the perspective of analytical chemistry.
Author | : J. Grimshaw |
Publisher | : Elsevier |
Total Pages | : 415 |
Release | : 2000-12-01 |
Genre | : Science |
ISBN | : 0080530729 |
Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook.As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.
Author | : Keith Oldham |
Publisher | : John Wiley & Sons |
Total Pages | : 420 |
Release | : 2011-12-12 |
Genre | : Science |
ISBN | : 0470710853 |
Electrochemistry is a discipline of wide scientific and technological interest. Scientifically, it explores the electrical properties of materials and especially the interfaces between different kinds of matter. Technologically, electrochemistry touches our lives in many ways that few fully appreciate; for example, materials as diverse as aluminum, nylon, and bleach are manufactured electrochemically, while the batteries that power all manner of appliances, vehicles, and devices are the products of electrochemical research. Other realms in which electrochemical science plays a crucial role include corrosion, the disinfection of water, neurophysiology, sensors, energy storage, semiconductors, the physics of thunderstorms, biomedical analysis, and so on. This book treats electrochemistry as a science in its own right, albeit resting firmly on foundations provided by chemistry, physics, and mathematics. Early chapters discuss the electrical and chemical properties of materials from which electrochemical cells are constructed. The behavior of such cells is addressed in later chapters, with emphasis on the electrodes and the reactions that occur on their surfaces. The role of transport to and from electrodes is a topic that commands attention, because it crucially determines cell efficiency. Final chapters deal with voltammetry, the methodology used to investigate electrode behavior. Interspersed among the more fundamental chapters are chapters devoted to applications of electrochemistry: electrosynthesis, power sources, “green electrochemistry”, and corrosion. Electrochemical Science and Technology is addressed to all who have a need to come to grips with the fundamentals of electrochemistry and to learn about some of its applications. It will constitute a text for a senior undergraduate or graduate course in electrochemistry. It also serves as a source of material of interest to scientists and technologists in various fields throughout academia, industry, and government – chemists, physicists, engineers, environmentalists, materials scientists, biologists, and those in related endeavors. This book: Provides a background to electrochemistry, as well as treating the topic itself. Is accessible to all with a foundation in physical science, not solely to chemists. Is addressed both to students and those later in their careers. Features web links (through www.wiley.com/go/EST) to extensive material that is of a more tangential, specialized, or mathematical nature. Includes questions as footnotes to support the reader’s evolving comprehension of the material, with fully worked answers provided on the web. Provides web access to Excel® spreadsheets which allow the reader to model electrochemical events. Has a copious Appendix of relevant data.
Author | : Piero Zanello |
Publisher | : Royal Society of Chemistry |
Total Pages | : 733 |
Release | : 2007-10-31 |
Genre | : Science |
ISBN | : 1847551149 |
Electrochemistry can be an elegant and essential support to synthetic inorganic chemistry. However, it is often perceived as a difficult technique. This book aims to introduce inorganic chemists to electrochemical investigations in as straightforward a way as possible. First, the reader is introduced to the theory of electron transfer processes, how they can be studied by various electrochemical techniques, and the practical procedures required. The book then goes on to look extensively, and with numerous illustrations, at the application of the techniques in the multiple fields of inorganic chemistry (including organometallics, coordination compounds, bioinorganics/biomimetics and materials science). Topics covered include: metallocenes; organometallic and coordination complexes; metal complexes of redox active ligands; metal-carbonyl clusters; superconductors; molecular wires; and proteins. Throughout, special attention is paid to the structural effects accompanying the electron transfer processes. This unique book bridges the gap between undergraduate and research-level electrochemistry books, and will be welcomed as an introduction to electrochemical applications within inorganic chemistry.
Author | : Peter G. Bruce |
Publisher | : Cambridge University Press |
Total Pages | : 364 |
Release | : 1997-06-12 |
Genre | : Science |
ISBN | : 9780521599498 |
This book describes, for the first time in a modern text, the fundamental principles on which solid state electrochemistry is based. In this sense it is in contrast to other books in the field which concentrate on a description of materials. Topics include solid (ceramic) electrolytes, glasses, polymer electrolytes, intercalation electrodes, interfaces and applications. The different nature of ionic conductivity in ceramic, glassy and polymer electrolytes is described as are the thermodynamics and kinetics of intercalation reactions. The interface between solid electrolytes and electrodes is discussed and contrasted with the more conventional liquid state electrochemistry. The text provides an essential foundation of understanding for postgraduates or others entering the field for the first time and will also be of value in advanced undergraduate courses.
Author | : Donald T. Sawyer |
Publisher | : Wiley-Interscience |
Total Pages | : 456 |
Release | : 1974 |
Genre | : Science |
ISBN | : |
Indicator electrodes; Electrochemical cells; Solvents and electrolytes; Instrumentation; Potentiometric measurements; Controlled potential methods; Controlled current methods; Electrochemical titrations.
Author | : P.H. Rieger |
Publisher | : Springer Science & Business Media |
Total Pages | : 493 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 9401106916 |
It has been fashionable to describe electrochemistry as a discipline at the interface between the branches of chemistry and many other sciences. A perusal of the table of contents will affirm that view. Electrochemistry finds applications in all branches of chemistry as well as in biology, biochemistry, and engineering; electrochemistry gives us batteries and fuel cells, electroplating and electrosynthesis, and a host of industrial and technological applications which are barely touched on in this book. However, I will maintain that electrochemistry is really a branch of physical chemistry. Electrochemistry grew out of the same tradition which gave physics the study of electricity and magnetism. The reputed founders of physical chemistry-Arrhenius, Ostwald, and van't Hoff-made many of their contributions in areas which would now be regarded as electrochemistry. With the post-World War II capture of physical chemistry by chemical physicists, electrochemists have tended to retreat into analytical chemistry, thus defining themselves out of a great tradition. G. N. Lewis defined physical chemistry as "the study of that which is interesting." I hope that the readers of this book will find that electrochemistry qualifies.
Author | : Ilana Fried |
Publisher | : Elsevier |
Total Pages | : 236 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0323159524 |
The Chemistry of Electrode Processes discusses "electrodics" or the science dealing with the transfer of an electric charge between a solid and liquid phase. This book reviews the applications of electrodics, the history of electrochemistry, and the basic definitions and concepts of the galvanic cell. This text also deals with the rate expressions associated with the different types of electrode reaction mechanism including the passing of Faradaic current, the current-voltage curve, mass transport overpotential, and the influence of surface structure on electrode processes. This book describes the electrode-solution interphase at equilibrium, the properties of such interphase, and the ways it can influence electrode kinetics. Any electrode reaction involves several steps and can be influenced by diffusion, adsorption and other parameters. The techniques to study electrode reactions and the electrode-solution interphase consists of equilibrium measurements, steady state measurement, and transient measurement. This text also describes the significant and potential uses of electrodics in technology which need less expensive equipment compared to using spectrophotometric techniques. This book is suitable chemists, for advanced students in analytical chemistry, physics, thermodynamics, and related subjects.
Author | : Krystyna Jackowska |
Publisher | : Walter de Gruyter GmbH & Co KG |
Total Pages | : 312 |
Release | : 2020-06-22 |
Genre | : Science |
ISBN | : 3110598973 |
"This book introduces the main aspects of modern applied electrochemistry. Starting with the basics of thermodynamic background, structure of interfaces and selected techniques used in analytical and material chemistry, the authors address the principles of electrochemistry in material sience: corrosion, electrocatalysis, electrodeposition, energy storage and conversion. The application of nanostructured materials in these processes, as well as interfacing of electrochemistry with biology and medicine is discussed. The final part of the book is devoted to photoelectrochemistry and solar energy conversion in photoelectrochemical cells of various types. The goal of this book is to show that electrochemistry has many applications, not only for understanding of various phenomena in nowadays life but also in practical devices and can stimulate new science-enabled technologies, nourishing leaps from bench-top to large-scale industries, providing also means for protecting our environment"--Page 4 of cover.