Direct Hydroxylation Of Methane
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Author | : Kazunari Yoshizawa |
Publisher | : Springer Nature |
Total Pages | : 167 |
Release | : 2020-10-29 |
Genre | : Science |
ISBN | : 981156986X |
This book focuses on theoretical and computational studies by the editor’s group on the direct hydroxylation of methane, which is one of the most challenging subjects in catalyst chemistry. These studies of more than 20 years include gas-phase reactions by transition-metal oxide ions, enzymatic reactions by two types of methane monooxygenase (soluble and particulate MMO), catalytic reactions by metal-exchanged zeolites, and methane C–H activation by metal oxide surfaces. Catalyst chemistry has been mostly empirical and based on enormous experimental efforts. The subject of the title has been tackled using the orbital interaction and computations based on extended Hückel, DFT, and band structure calculations. The strength of the theoretical studies is in the synergy between theory and experiment. Therefore, the group has close contacts with experimentalists in physical chemistry, catalyst chemistry, bioinorganic chemistry, inorganic chemistry, and surface chemistry. This resulting book will be useful for the theoretical analysis and design of catalysts.
Author | : Michel Che |
Publisher | : John Wiley & Sons |
Total Pages | : 1313 |
Release | : 2012-05-14 |
Genre | : Technology & Engineering |
ISBN | : 3527326871 |
This two-volume book provides an overview of physical techniques used to characterize the structure of solid materials, on the one hand, and to investigate the reactivity of their surface, on the other. Therefore this book is a must-have for anyone working in fields related to surface reactivity. Among the latter, and because of its most important industrial impact, catalysis has been used as the directing thread of the book. After the preface and a general introduction to physical techniques by M. Che and J.C. Vedrine, two overviews on physical techniques are presented by G. Ertl and Sir J.M. Thomas for investigating model catalysts and porous catalysts, respectively. The book is organized into four parts: Molecular/Local Spectroscopies, Macroscopic Techniques, Characterization of the Fluid Phase (Gas and/ or Liquid), and Advanced Characterization. Each chapter focuses upon the following important themes: overview of the technique, most important parameters to interpret the experimental data, practical details, applications of the technique, particularly during chemical processes, with its advantages and disadvantages, conclusions.
Author | : William B. Tolman |
Publisher | : John Wiley & Sons |
Total Pages | : 382 |
Release | : 2006-12-13 |
Genre | : Science |
ISBN | : 3527609377 |
The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.
Author | : Robert H. Crabtree |
Publisher | : John Wiley & Sons |
Total Pages | : 425 |
Release | : 2013-02-19 |
Genre | : Technology & Engineering |
ISBN | : 1118632664 |
Energy production and storage are central problems for our time. In principle, abundant energy is available from the sun to run the earth in a sustainable way. Solar energy can be directly harnessed by agricultural and photovoltaic means, but the sheer scale of the energy demand poses severe challenges, for example any major competition between biomass production and food production would simply transfer scarcity from energy to food. Indirect use of solar energy in the form of wind looks also promising, especially for those regions not blessed with abundant sunlight. Other modes such as tidal and wave energy may well become important niche players. Inorganic chemistry plays a decisive role in the development of new energy technologies and this Volume covers some promising modes of alternative energy production and storage that minimize the atmospheric burden of fossil-derived carbon monoxide. No one production or storage mode is likely to dominate, at least at first, and numerous possibilities need to be explored to compare their technical feasibility and economics. This provides the context for a broad exploration of novel ideas that we are likely to see in future years as the field expands. This Volume covers a wide range of topics, such as: - Water splitting, only water is a sufficiently cheap and abundant electron source for global exploitation; - Energy conversion by photosynthesis; - Molecular catalysts for water splitting; - Thermochemical water splitting; - Photocatalytic hydrogen production; - Artificial photosynthesis, progress of the Swedish Consortium; - Hydrogen economy; - Reduction of carbon dioxide to useful fuels; - Conversion of methane to methanol; - Dye sensitized solar cells; - Photoinitiated electron transfer in fuel cells; - Proton exchange membranes for fuel cells; - Intermediate temperature solid oxide fuel cells; - Direct Ethanol fuel cells; - Molecular catalysis for fuel cells; - Enzymes and microbes in fuel cells; - Li-Ion batteries; - Magic Angle Spinning NMR studies of battery materials; Supercapacitors and electrode materials. About EIC Books The Encyclopedia of Inorganic Chemistry (EIC) has proved to be one of the defining standards in inorganic chemistry, and most chemistry libraries around the world have access either to the first or second print edition, or to the online version. Many readers, however, prefer to have more concise thematic volumes, targeted to their specific area of interest. This feedback from EIC readers has encouraged the Editors to plan a series of EIC Books, focusing on topics of current interest. They will appear on a regular basis, and will feature leading scholars in their fields. Like the Encyclopedia, EIC Books aim to provide both the starting research student and the confirmed research worker with a critical distillation of the leading concepts in inorganic and bioinorganic chemistry, and provide a structured entry into the fields covered. This volume is also available as part of Encyclopedia of Inorganic Chemistry, 5 Volume Set. This set combines all volumes published as EIC Books from 2007 to 2010, representing areas of key developments in the field of inorganic chemistry published in the Encyclopedia of Inorganic Chemistry. Find out more.
Author | : V. Ya. Shtern |
Publisher | : Elsevier |
Total Pages | : 721 |
Release | : 2016-07-29 |
Genre | : Science |
ISBN | : 1483185079 |
The Gas-Phase Oxidation of Hydrocarbons reviews research on the mechanism of oxidation of paraffins, naphthenes, olefines, and aromatic hydrocarbons and explains in detail the phenomena and theories with significant kinetic equations and graphs. This book first presents a study of the development of research on the gaseous-phase oxidation of hydrocarbons. The non-chain schemes for the oxidation of hydrocarbons, such as hydroxylation, peroxidation, and aldehyde and dehydrogenation schemes, are then discussed. This book also presents experimental investigations and important topics such as oxidation of methane and olefinic hydrocarbons. This selection will be invaluable to students and experts in the field of chemistry and related disciplines.
Author | : Mohammad Reza Rahimpour |
Publisher | : Elsevier |
Total Pages | : 468 |
Release | : 2024-04-17 |
Genre | : Technology & Engineering |
ISBN | : 0443192286 |
Advances in Natural Gas: Formation, Processing, and Applications is a comprehensive eight-volume set of books that discusses in detail the theoretical basics and practical methods of various aspects of natural gas from exploration and extraction, to synthesizing, processing and purifying, producing valuable chemicals and energy. The volumes introduce transportation and storage challenges as well as hydrates formation, extraction, and prevention Volume 7 titled Natural Gas Products and Uses comprehensively discusses natural gas conversion and applications for producing high-value chemicals and energy which are accompanied with related environmental challenges and economic analysis. The book covers various methods for producing valuable materials such as synthesis and fuel gases, alkanes, aromatics, sulphurs, etc. and introduces power and electricity generation as well as heat production from natural gas and their applications on future energy systems. - Introduces various chemicals produced from natural gas - Describes power and energy generation methods from natural gas - Discusses cogeneration, trigeneration, and other techniques for effective integration of natural gas production with energy systems
Author | : Robert Bakhtchadjian |
Publisher | : Bentham Science Publishers |
Total Pages | : 137 |
Release | : 2023-01-11 |
Genre | : Science |
ISBN | : 9815050931 |
This book introduces readers to the fundamentals of oxygen atom transfer reactions. It also gives mechanistic insights into the redox processes occurring through the oxygen atom transfer reactions. It also includes information about catalytic activation of oxygen through enzymes and oxo-metallic complexes. All topics are explored in separate chapters. Key features: - reviews the basic mechanisms in redox processes involving oxo-atom transfer reactions. - presents progress in the biomimetic activation of dioxygen related to the catalytic oxidations by synthetic metal organic complexes. - covers an important class of metal-organic compounds - nickel-oxygen species - generated in catalytic oxidation processes as oxygen atom transfer agents. - explains the mechanistic aspects of the heterogeneous photochemical redox processes via oxo-atom transfer reactions - provides references for further reading It is a reference for both professional scientists in the fields of chemistry, biology and applied sciences, and for graduate and undergraduate students interested in understanding reaction mechanisms involving oxygen.
Author | : Wei Zhang |
Publisher | : John Wiley & Sons |
Total Pages | : 769 |
Release | : 2012-05-10 |
Genre | : Science |
ISBN | : 1118308654 |
An updated overview of the rapidly developing field of green engineering techniques for organic synthesis and medicinal chemistry Green chemistry remains a high priority in modern organic synthesis and pharmaceutical R&D, with important environmental and economic implications. This book presents comprehensive coverage of green chemistry techniques for organic and medicinal chemistry applications, summarizing the available new technologies, analyzing each technique’s features and green chemistry characteristics, and providing examples to demonstrate applications for green organic synthesis and medicinal chemistry. The extensively revised edition of Green Techniques for Organic Synthesis and Medicinal Chemistry includes 7 entirely new chapters on topics including green chemistry and innovation, green chemistry metrics, green chemistry and biological drugs, and the business case for green chemistry in the generic pharmaceutical industry. It is divided into 4 parts. The first part introduces readers to the concepts of green chemistry and green engineering, global environmental regulations, green analytical chemistry, green solvents, and green chemistry metrics. The other three sections cover green catalysis, green synthetic techniques, and green techniques and strategies in the pharmaceutical industry. Includes more than 30% new and updated material—plus seven brand new chapters Edited by highly regarded experts in the field (Berkeley Cue is one of the fathers of Green Chemistry in Pharma) with backgrounds in academia and industry Brings together a team of international authors from academia, industry, government agencies, and consultancies (including John Warner, one of the founders of the field of Green Chemistry) Green Techniques for Organic Synthesis and Medicinal Chemistry, Second Edition is an essential resource on green chemistry technologies for academic researchers, R&D professionals, and students working in organic chemistry and medicinal chemistry.
Author | : Tomislav Rovis |
Publisher | : John Wiley & Sons |
Total Pages | : 725 |
Release | : 2016-10-17 |
Genre | : Science |
ISBN | : 1119061008 |
Spurred by the desire to make chemistry a sustainable and "greener" technology, the field of organocatalysis has grown to become one of the most important areas in synthetic organic chemistry. Organic catalysts can often replace potentially toxic metal catalysts and allow reactions to proceed under mild reaction conditions, thereby saving energy costs and rendering chemical processes inherently safer. More importantly perhaps, organocatalysis offers a complementary reactivity in many instances leading to increased versatility. This Handbook describes 126 key reagents for organocatalytic reactions and will be especially useful for professionals in the area of sustainable chemistry, medicinal research, as well as synthetic organic chemists working in academia and the pharmaceutical industry. All the information compiled in this volume is also available in electronic format on Wiley Online Library. The 126 reagents represented here are but a small fraction of the ca. 5,000 reagents available in the electronic Encyclopedia of Reagents for Organic Synthesis (e-EROS). e-EROS offers various search interfaces to locate reagents of interest, including chemical structure, substructure and reactions search modes. e-EROS is updated regularly with new and updated entries.
Author | : Jianli Hu |
Publisher | : CRC Press |
Total Pages | : 467 |
Release | : 2020-09-24 |
Genre | : Science |
ISBN | : 0429665962 |
Direct Natural Gas Conversion to Value-Added Chemicals comprehensively discusses all major aspects of natural gas conversion and introduces a broad spectrum of recent technological developments. Specifically, the book describes heterogeneous and homogeneous catalysis, microwave-assisted conversion, non-thermal plasma conversion, electrochemical conversion, and novel chemical looping conversion approaches. Provides an excellent benchmark resource for the industry and academics Appeals to experienced researchers as well as newcomers to the field, despite the variety of contributing authors and the complexity of the material covered Includes all aspects of direct natural gas conversion: fundamental chemistry, different routes of conversion, catalysts, catalyst deactivation, reaction engineering, novel conversion concepts, thermodynamics, heat and mass transfer issues, system design, and recent research and development Discusses new developments in natural gas conversion and future challenges and opportunities This book is as an excellent resource for advanced students, technology developers, and researchers in chemical engineering, industrial chemistry, and others interested in the conversion of natural gas.