Current Status and Future Perspectives of Electron Interactions with Molecules, Clusters, Surfaces, and Interfaces [Workshop on Fundamental Challenges in Electron-driven Chemistry ; Workshop on Electron-driven Processes

Current Status and Future Perspectives of Electron Interactions with Molecules, Clusters, Surfaces, and Interfaces [Workshop on Fundamental Challenges in Electron-driven Chemistry ; Workshop on Electron-driven Processes
Author:
Publisher:
Total Pages: 57
Release: 2000
Genre:
ISBN:

This report is based largely on presentations and discussions at two workshops and contributions from workshop participants. The workshop on Fundamental Challenges in Electron-Driven Chemistry was held in Berkeley, October 9-10, 1998, and addressed questions regarding theory, computation, and simulation. The workshop on Electron-Driven Processes: Scientific Challenges and Technological Opportunities was held at Stevens Institute of Technology, March 16-17, 2000, and focused largely on experiments. Electron-molecule and electron-atom collisions initiate and drive almost all the relevant chemical processes associated with radiation chemistry, environmental chemistry, stability of waste repositories, plasma-enhanced chemical vapor deposition, plasma processing of materials for microelectronic devices and other applications, and novel light sources for research purposes (e.g. excimer lamps in the extreme ultraviolet) and in everyday lighting applications. The life sciences are a rapidly advancing field where the important role of electron-driven processes is only now beginning to be recognized. Many of the applications of electron-initiated chemical processes require results in the near term. A large-scale, multidisciplinary and collaborative effort should be mounted to solve these problems in a timely way so that their solution will have the needed impact on the urgent questions of understanding the physico-chemical processes initiated and driven by electron interactions.

Electron Collisions with Molecules, Clusters, and Surfaces

Electron Collisions with Molecules, Clusters, and Surfaces
Author: H. Ehrhardt
Publisher: Springer Science & Business Media
Total Pages: 265
Release: 2013-06-29
Genre: Science
ISBN: 1489914897

This volume contains the invited papers and selected contributed papers presented at the biennial International Symposium on ELECTRON COLLISIONS WITH MOLECULES, CLUSTERS AND SURF ACES held at Royal Holloway, University of London from 29th to 30th July, 1993. This Symposium was a Satellite Meeting of the XVIII International Conference on the Physics of Electronic and Atomic Collisions (ICPEAC) and follows a 16 year tradition of Satellite Conferences in related areas of collisions held in association with previous ICPEAC's. In the past each of these electron -molecule symposia covered the broad field of electron-molecule scattering at rather low energies, but also included hot topics. This time as well as covering the whole field, well defined electron collisions with clusters and with particles in the complex potential of a surface were emphasized. Not many details are known about such collisions, although they become more and more important in surface characterisation, plasma-wall interactions, electron induced desorption and reorganisation of adsorbed particles. Recently, much work, theoretical and experimental, has been devoted to electron collisions with rather large carbon, silicon and halogen containing molecules. These problems are of relevance in plasma assisted thin film formation and etching of surfaces and can now be approached with advanced theoretical methods and experimental equipment.

Visualizing Chemistry

Visualizing Chemistry
Author: National Research Council
Publisher: National Academies Press
Total Pages: 222
Release: 2006-06-01
Genre: Science
ISBN: 030916463X

Scientists and engineers have long relied on the power of imaging techniques to help see objects invisible to the naked eye, and thus, to advance scientific knowledge. These experts are constantly pushing the limits of technology in pursuit of chemical imagingâ€"the ability to visualize molecular structures and chemical composition in time and space as actual events unfoldâ€"from the smallest dimension of a biological system to the widest expanse of a distant galaxy. Chemical imaging has a variety of applications for almost every facet of our daily lives, ranging from medical diagnosis and treatment to the study and design of material properties in new products. In addition to highlighting advances in chemical imaging that could have the greatest impact on critical problems in science and technology, Visualizing Chemistry reviews the current state of chemical imaging technology, identifies promising future developments and their applications, and suggests a research and educational agenda to enable breakthrough improvements.

Workshop on Coupled-Cluster Theory at the Interface of Atomic Physics and Quantum Chemistry

Workshop on Coupled-Cluster Theory at the Interface of Atomic Physics and Quantum Chemistry
Author:
Publisher:
Total Pages: 17
Release: 1991
Genre:
ISBN:

The Workshop on Coupled-Cluster Theory linked researchers by the need for high accuracy correlated calculations for electronic structure in atoms and molecules. One group were experts in coupled-cluster (CC) and many-body perturbation methods (MBPT) approaches for electron correlation in molecules, and had developed very powerful tools for determining molecular structure and spectra using CC/MBPT methods. The second group was primarily concerned with important applications to weak interactions in atoms, while employing many-body techniques in their calculations. Many examples were shown that demonstrate numerically the inherent superiority of CC methods for electron correlation compared to most other approaches.

Computational Methods for Electron—Molecule Collisions

Computational Methods for Electron—Molecule Collisions
Author: Franco A. Gianturco
Publisher: Springer
Total Pages: 364
Release: 2013-07-28
Genre: Science
ISBN: 9781475797985

The collision of electrons with molecules and molecular ions is a fundamental pro cess in atomic and molecular physics and in chemistry. At high incident electron en ergies, electron-molecule collisions are used to deduce molecular geometries, oscillator strengths for optically allowed transitions, and in the case of electron-impact ionization, to probe the momentum distribution of the molecule itself. When the incident electron energy is comparable to or below those of the molecular valence electrons, the physics involved is particularly rich. Correlation and exchange effects necessary to describe such collision processes bear a close resemblance to similar efft:cts in the theory of electronic structure in molecules. Compound state formations, in the form of resonances and vir tual states, manifest themselves in experimental observables which provide details of the electron-molecule interactions. Ro-vibrational excitations by low-energy electron collisions exemplify energy transfer between the electronic and nuclear motion. The role of nonadiabatic interaction is raised here. When the final vibrational state is in the continuum, molecular dissociation occurs. Dissociative recombination and dissociative attachment are examples of such fragmentation processes. In addition to its fundamental nature, the study of electron-molecule collisions is also motivated by its relation to other fields of study and by its technological appli cations. The study of planetary atmospheres and the interstellar medium necessarily involve collision processes of electrons with molecules and molecular ions.

Computational Methods for Electron—Molecule Collisions

Computational Methods for Electron—Molecule Collisions
Author: Franco A. Gianturco
Publisher: Springer
Total Pages: 364
Release: 1995-03-31
Genre: Science
ISBN: 9780306449116

The collision of electrons with molecules and molecular ions is a fundamental pro cess in atomic and molecular physics and in chemistry. At high incident electron en ergies, electron-molecule collisions are used to deduce molecular geometries, oscillator strengths for optically allowed transitions, and in the case of electron-impact ionization, to probe the momentum distribution of the molecule itself. When the incident electron energy is comparable to or below those of the molecular valence electrons, the physics involved is particularly rich. Correlation and exchange effects necessary to describe such collision processes bear a close resemblance to similar efft:cts in the theory of electronic structure in molecules. Compound state formations, in the form of resonances and vir tual states, manifest themselves in experimental observables which provide details of the electron-molecule interactions. Ro-vibrational excitations by low-energy electron collisions exemplify energy transfer between the electronic and nuclear motion. The role of nonadiabatic interaction is raised here. When the final vibrational state is in the continuum, molecular dissociation occurs. Dissociative recombination and dissociative attachment are examples of such fragmentation processes. In addition to its fundamental nature, the study of electron-molecule collisions is also motivated by its relation to other fields of study and by its technological appli cations. The study of planetary atmospheres and the interstellar medium necessarily involve collision processes of electrons with molecules and molecular ions.

The Chemistry of Metal CVD

The Chemistry of Metal CVD
Author: Toivo T. Kodas
Publisher: John Wiley & Sons
Total Pages: 562
Release: 2008-09-26
Genre: Technology & Engineering
ISBN: 3527615849

High purity, thin metal coatings have a variety of important commercial applications, for example, in the microelectronics industry, as catalysts, as protective and decorative coatings as well as in gas-diffusion barriers. This book offers detailed, up- to-date coverage of the chemistry behind the vapor deposition of different metals from organometallic precursors. In nine chapters, the CVD of metals including aluminum, tungsten, gold, silver, platinum, palladium, nickel, as well as copper from copper(I) and copper(II) compounds is covered. The synthesis and properties of the precursors, the growth process, morphology, quality and adhesion of the resulting films as well as laser- assisted, ion- assisted and plasma-assisted methods are discussed. Present applications and prospects for future developments are summarized. With ca. 1000 references and a glossary, this book is a unique source of in-depth information. It is indispensable for chemists, physicists, engineers and materials scientists working with metal- coating processes and technologies. From Reviews: 'I highly recommend this book to anyone interested in learning more about the chemistry of metal CVD.' J. Am Chem. Soc.

Coupled Cluster and Electron Correlation Workshop (1997) "Fifty Years of the Correlation Problem" Held in Cedar Key, Florida on June 15-19, 1997

Coupled Cluster and Electron Correlation Workshop (1997)
Author: Rodney Bartlett
Publisher:
Total Pages: 2
Release: 1997
Genre:
ISBN:

The Coupled Cluster Theory Electron Correlation Workshop 'Fifty Years of the Correlation Problem' was held at Cedar Key, Florida, from June 15-19, 1997, to recognize the essential developments for one of the dominant topics in the quantum theory of atoms, molecules, and solids. The instantaneous Coloumbic interactions among electrons that correlate their motion (the electron correlation problem) has been the focal point of ab initio quantum chemistry and physics for many years. Only with the proper inclusion of electron correlation in approximate solutions of the Schroedinger (or Dirac-Fock) equation is it possible to provide predictive accuracy for most properties of atoms and molecules. Such quantities include energetics (involving multiplets, dissociation pathways, and activation barriers), excited states and first- and second-order properties (like moments, field, gradients, polarizabilitles, and magnetic susceptibilities), and vibrational, electronic, EPR and NMR spectra, among others.

Enzymatic Bioelectrocatalysis

Enzymatic Bioelectrocatalysis
Author: Kenji Kano
Publisher: Springer Nature
Total Pages: 135
Release: 2020-11-13
Genre: Science
ISBN: 9811589607

This book covers the fundamental aspects of the electrochemistry and redox enzymes that underlie enzymatic bioelectrocatalysis, in which a redox enzyme reaction is coupled with an electrode reaction. Described here are the basic concept and theoretical aspects of bioelectrocatalysis and the various experimental techniques and materials used to study and characterize related problems. Also included are the various applications of bioelectrocatalysis to bioelectrochemical devices including biosensors, biofuel cells, and bioreactors. This book is a unique source of information in the area of enzymatic bioelectrocatalysis, approaching the subject from a cross-disciplinary point of view.