Collision-induced Absorption in Diatomic Molecule/rare-gas Mixtures

Collision-induced Absorption in Diatomic Molecule/rare-gas Mixtures
Author: H. T. Yura
Publisher:
Total Pages: 42
Release: 1967
Genre: Collisions (Nuclear physics)
ISBN:

A quantum mechanical calculation is given for collision-induced absorption in the infrared and far-infrared spectral regions for mixtures consisting of symmetrical diatomic molecules and rare-gas atoms. The induced moment consists of a short-range overlap term and a long-range quadrupole term. Near molecular transition lines, the quadrupole term gives the main contribution to the absorption, while in the far wings, the overlap term is dominant. The H2-He, H2-Ar, N2-Ar systems are considered, and an estimate is given of the absorption coefficient near 10 millimicrons for N2-N2 systems. (Author).

Collision-induced Absorption in Gases

Collision-induced Absorption in Gases
Author: Lothar Frommhold
Publisher:
Total Pages: 410
Release: 1993
Genre: Science
ISBN: 9780521393454

This book reviews the theory and experiment of collision-induced absorption of infrared radiation in dense gases.

Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the Atmosphere

Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the Atmosphere
Author: Claude Camy-Peyret
Publisher: Springer Science & Business Media
Total Pages: 295
Release: 2012-12-06
Genre: Science
ISBN: 9401000255

The Advanced Research Workshop entitled “Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the At- sphere” was held in Abbaye de Fontevraud, France, from April 29 to May 3, 2002. The meeting involved 40 researchers from 14 countries. The goal of this meeting was to address a problem that the scienti?c community is aware of for many years. Up now, however, the so- tion for this problem is far from satisfactory. Pair e?ects are called unconventional in the title of this meeting. In speci?c spectral domains and/or geophysical conditions they are recognized to play a dominant role in the absorption/emission properties of the atmosphere. Water vapor continuum absorption is among the most prominent examples. Permanently improving accuracy of both laboratory studies and ?eld observations requires better knowledge of the spectroscopic features - tributable to molecular pairs which may form at equilibrium. The Workshop was targeted both to clarify the pending questions and, as far as feasible, to trace the path to possible answers since the underlying phenomena are yet incompletely understood and since a reliable theory is often not available. On the other hand, the lack of precise laboratory data on bimolecular absorption is often precluding the construction of reliable theoretical models. Ideally, the knowledge accumulated in the course of laboratory studies should correlate with the practical demands from those who are carrying out atmospheric ?eld measurements and space observations.

Phenomena Induced by Intermolecular Interactions

Phenomena Induced by Intermolecular Interactions
Author: G. Birnbaum
Publisher: Springer Science & Business Media
Total Pages: 784
Release: 2013-03-09
Genre: Computers
ISBN: 1461325110

This book is concerned with recent experimental and theoretical work dealing with phenomena created by the transient dipoles and polarizabilities produced by intermolecular interactions. The for mer produce absorption from the microwave to the optical regions of the spectrum and the latter produce Rayleigh and Raman scattering; such absorption and scattering would be absent without collisions. Static properties, such as dielectric constant, refractive index, and Kerr effect, also exhibit the effects of induced dipoles and polarizabilities. The first observation of an infrared absorption spectrum pro duced by the collisions of molecules which ordinarily do not have an allowed dipole transition was reported in 1949 (Crawford, Welsh, and Locke). The first observation of depolarized Rayleigh spectra due to collisions in atomic gases appeared in 1968 (McTague and Birnbaum). However, it was not until 1977 that the first conference dealing with collision-induced phenomena was organized by J. D. Poll at the University of Guelph. This conference was mainly concerned with studies of collision-induced absorption in gases. Light scat tering received more attention at the second meeting of the colli sion-induced community in 1978, at the E. Fermi Summer School on "Intermolecular Spectroscopy and Dynamical Properties of Dense Sys tems," organized by J. Van Kranendonk. However, the emphasis was still on collision-induced absorption in compressed gases, although some work on liquids, solid H , and related subjects such as ro 2 tational relaxation was included. The third induced phenomena con ference, organized by F.