Aziridines And Epoxides In Organic Synthesis
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| Author | : Andrei K. Yudin |
| Publisher | : John Wiley & Sons |
| Total Pages | : 516 |
| Release | : 2006-12-13 |
| Genre | : Science |
| ISBN | : 352760748X |
Aziridines and epoxides are among the most widely used intermediates in organic synthesis, acting as precursors to complex molecules due to the strains incorporated in their skeletons. Besides their importance as reactive intermediates, many biologically active compounds also contain these three-membered rings. Filling a gap in the literature, this clearly structured book presents the much needed information in a compact and concise way. The renowned editor has succeeded in gathering together excellent authors to cover synthesis, applications, and the biological aspects in equal depth. Divided roughly equally between aziridines and epoxides, the twelve chapters discuss: * Synthesis of aziridines * Nucleophilic ring-opening of aziridines and epoxides * Organic synthesis with aziridine building blocks * Vinyl aziridines in organic synthesis * Diastereoselective aziridination reagents * Synthetic aspects of aziridinomitocene chemistry * Biosynthesis of biologically important aziridines * Organic catalysis of epoxide and aziridine ring formation * Metal-mediated synthesis of epoxides * Asymmetric epoxide ring opening chemistry * Epoxides in complex molecule synthesis * Biological activity of epoxide-containing molecules A high-quality reference manual for academic and industrial chemists alike.
| Author | : Navjeet Kaur |
| Publisher | : Elsevier |
| Total Pages | : 354 |
| Release | : 2024-01-13 |
| Genre | : Science |
| ISBN | : 0443220603 |
The smallest possible saturated azaheterocycle, aziridine, is well-known to organic chemists for its tremendous potential in pharmaceutical chemistry and organic synthesis. The general biological importance of aziridines is proven by the fact that they found several uses as subunits in pharmacologically active compounds such as antitumor agents, enzyme inhibitors, and antibiotics. Although aziridines are highly reactive, this framework occurs in many synthetic compounds and the natural products of biological interest also contain aziridine skeleton in their structures. The synthetic community is captivated with prospects of selective synthesis and conversions of aziridines. Several important advances in this area have been witnessed in recent years and discovering efficient novel methods for the synthesis of aziridines has been very active field of research. Its powerful synthetic utility has been described by an overpowering amount of documentation on the approaches for the formation of aziridine. Synthesis of Aziridines and Oxaziridines from Imines describes the new and old methods for the synthesis of aziridines from imines and covers an important and rapidly growing branch of heterocyclic chemistry. Readers will have access to different methods and information allowing them to evaluate which method is most suitable for particular cases. - Focuses on the biological importance of different heterocycles - Describes traditional and innovative methods for the synthesis of aziridines from imines - Includes comparison amongst different methods, reagents, reaction conditions in tabulated forms, advantages, disadvantages, and critical analysis of different methodologies with respect to their comparison with green technique
| Author | : Rick Reeves |
| Publisher | : |
| Total Pages | : 0 |
| Release | : 2018 |
| Genre | : Epoxy compounds |
| ISBN | : 9781536129601 |
This book opens with a discussion on the syntheses of acyclic polyketides by using epoxide opening reactions. The stereoselective epoxidations of allylic alcohols, including catalytic asymmetric epoxidation reactions and stereospecific reactions due to substrate-control, are described shortly. Afterwards, different epoxide opening reactions and applications in natural product synthesis are reviewed. The authors highlight the recent advances in catalytic one-pot synthesis of epoxides. The versatility of organometallic catalysts in epoxidation of alkenes are considered an important point of research in the context of these transformations. Later, occurrence of carotenoid 5,6-epoxides, their chemical synthesis, the separation of stereoisomers, some transformations of 5,6-epoxy-carotenoids, and their biological processes are described. Following this, the methodologies for the deoxygenation of epoxides using oxo-molybdenum and oxo-rhenium complexes as efficient catalysts are described, allowing a large community of readers, in particularly the community that works in catalysis, organic and organometallic chemistry, ready access to the novel methodologies developed.
| Author | : Jean-Baptiste Sortais |
| Publisher | : John Wiley & Sons |
| Total Pages | : 372 |
| Release | : 2021-12-20 |
| Genre | : Technology & Engineering |
| ISBN | : 3527347305 |
Manganese Catalysis in Organic Synthesis A must-read reference for anyone interested in catalyst design and sustainable organic synthesis In Manganese Catalysis in Organic Synthesis, distinguished researcher Jean-Baptiste Sortais delivers an insightful and robust overview of the use of manganese in homogenous catalysis. The editor includes papers from authoritative academics describing the organometallic precursors used to develop manganese catalysts and covers critical applications in organic synthesis, including reduction to oxidation reactions, C-C, C-N, C-X bond formation reactions, cross-coupling reactions, C-H bond activation to dihydroxylation and epoxidation reactions. Manganese Catalysis in Organic Synthesis is a practical resource for every organic chemist in academia and industry with an interest in non-noble metal catalysis, organic synthesis, and sustainable chemistry. It is intuitively and clearly organized, covering the most important synthetic procedures using homogenous manganese catalysts. It is also the ideal companion to works like Cobalt Catalysis in Organic Synthesis, Nickel Catalysis in Organic Synthesis, and Iron Complexes in Catalysis. Readers will also enjoy: Thorough introductions to organometallic manganese compounds in organic synthesis and manganese-catalyzed hydrogenation and hydrogen transfer reactions A comprehensive exploration of manganese-catalyzed hydrogen borrowing reactions and dehydrogenative coupling reactions Practical discussions of manganese-catalyzed hydrosilylation and hydroboration reactions and manganese-catalyzed electro- and photocatalysis transformations In-depth examinations of manganese-catalyzed C-H oxygenation reactions and manganese-catalyzed organometallic C-H activation Insightful treatments of manganese-catalyzed cross-coupling processes and manganese(III) acetate mediated cyclizations Perfect for catalytic, organic, and pharmaceutical chemists, Manganese Catalysis in Organic Synthesis deserves a place in the libraries of researchers and professionals interested in catalyst design and sustainable organic synthesis.
| Author | : Hélène Pellissier |
| Publisher | : John Wiley & Sons |
| Total Pages | : 606 |
| Release | : 2017-06-19 |
| Genre | : Science |
| ISBN | : 3527341145 |
The first handbook to focus on the asymmetric synthesis of different types of three-membered rings. The outstanding and experienced authors have an excellent international reputation and cover cyclopropanes, epoxides and aziridines as well as chiral oxaziridines in equal measure. To this end, they describe in detail different synthetic approaches starting with chiral substrates as well as the application of chiral metal- or organocatalysts. Furthermore, methods for the kinetic resolution of initially racemic products are treated alongside recent advances and novel developments in established techniques for the synthesis of three-membered rings. With its structured composition this is of high interest to scientists in methodological and natural product synthesis as well as those in industrial and pharmaceutical chemistry.
| Author | : Matthias D’hooghe |
| Publisher | : Springer |
| Total Pages | : 376 |
| Release | : 2015-12-14 |
| Genre | : Science |
| ISBN | : 3319249606 |
The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal.
| Author | : Atta-ur-Rahman |
| Publisher | : Bentham Science Publishers |
| Total Pages | : 268 |
| Release | : 2018-08-01 |
| Genre | : Science |
| ISBN | : 1681086956 |
Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. The series presents comprehensive reviews written by eminent authorities on different synthetic approaches to selected target molecules and new methods developed to achieve specific synthetic transformations or optimal product yields. Advances in Organic Synthesis is essential for all organic chemists in academia and the industry who wish to keep abreast of rapid and important developments in the field. This volume presents the following reviews: • Asymmetric hydrogenation of tetrasubstituted olefins • Recent advances in catalytic organic synthesis applications of covalently supported ionic liquids • Recent developments in intramolecular cyclization reactions via carbon-heteroatom (c-x) bond formation • Efficient synthetic protocol and mechanistic study of quinazoline analogues and their biological importance • Synthesis of N,O,S-heterocycles by one-pot reactions of epoxides, aziridines and oxaziridines
| Author | : Noritaka Mizuno |
| Publisher | : John Wiley & Sons |
| Total Pages | : 356 |
| Release | : 2009-11-18 |
| Genre | : Science |
| ISBN | : 3527627553 |
Filling a gap in the current literature, this comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know -- from structure design to characterization, and from immobilization to industrial processes. A true must-have for anyone working in this key technology.
| Author | : |
| Publisher | : Newnes |
| Total Pages | : 9815 |
| Release | : 2014-02-14 |
| Genre | : Science |
| ISBN | : 008097743X |
The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively
| Author | : Alan R. Katritzky |
| Publisher | : Academic Press |
| Total Pages | : 314 |
| Release | : 2011-01-07 |
| Genre | : Science |
| ISBN | : 0123854644 |
Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area-one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties. Provides up-to-date material on a fast-growing and highly topical subject area Contains the latest research covering a wide variety of heterocyclic topics Written by leading authorities and designed as a handbook for students and industry and academic researchers
