Adsorptive Iron Removal from Groundwater

Adsorptive Iron Removal from Groundwater
Author: Sharoz Kumar Sharma
Publisher: CRC Press
Total Pages: 220
Release: 2021-05-31
Genre: Technology & Engineering
ISBN: 1000448304

A pilot study conducted at the Gilze water treatment plant of Water Supply North West Brabant demonstrated that adsorptive filtration has several potential advantages over floc filtration, namely: longer filter runs due to slower head loss development; better filtrate quality; shorter ripening time; and less backwash water use. In existing groundwater treatment plants, the high iron (II) adsorption capacity of the iron oxide coated filter media makes it potentially possible to switch the governing mode of operation from floc filtration to adsorptive filtration. To achieve this two options can be considered: iron (II) adsorption under anoxic conditions followed by oxidation with oxygen-rich water; and adsorption of iron (II) in the presence of oxygen and simultaneous oxidation. The first option might be attractive specifically when two filtration steps are available.

Application of Nanotechnology in Water Research

Application of Nanotechnology in Water Research
Author: Ajay Kumar Mishra
Publisher: John Wiley & Sons
Total Pages: 562
Release: 2014-06-09
Genre: Science
ISBN: 111893928X

Details the water research applications of nanotechnology in various areas including environmental science, remediation, membranes, nanomaterials, and water treatment At the nano size, materials often take on unique and sometimes unexpected properties that result in them being ‘tuned’ to build faster, lighter, stronger, and more efficient devices and systems, as well as creating new classes of materials. In water research, nanotechnology is applied to develop more cost-effective and high-performance water treatment systems, as well as to provide instant and continuous ways to monitor water quality. This volume presents an array of cutting-edge nanotechnology research in water applications including treatment, remediation, sensing, and pollution prevention. Nanotechnology applications for waste water research have significant impact in maintaining the long-term quality, availability, and viability of water. Regardless of the origin, such as municipal or industrial waste water, its remediation utilizing nanotechnology can not only be recycled and desalinized, but it can simultaneously detect biological and chemical contamination. Application of Nanotechnology in Water Research describes a broad area of nanotechnology and water research where membrane processes (nanofiltration, ultrafiltration, reverse osmosis, and nanoreactive membranes) are considered key components of advanced water purification and desalination technologies that remove, reduce, or neutralize water contaminants that threaten human health and/or ecosystem productivity and integrity. Various nanoparticles and nanomaterials that could be used in water remediation (zeolites, carbon nanotubes, self-assembled monolayer on mesoporous supports, biopolymers, single-enzyme nanoparticles, zero-valent iron nanoparticles, bimetallic iron nanoparticles, and nanoscale semiconductor photocatalysts) are discussed. The book also covers water-borne infectious diseases as well as water-borne pathogens, microbes, and toxicity approach.

Groundwater Geochemistry

Groundwater Geochemistry
Author: Sughosh Madhav
Publisher: John Wiley & Sons
Total Pages: 448
Release: 2021-06-14
Genre: Technology & Engineering
ISBN: 1119709709

This book contains both practical and theoretical aspects of groundwater resources relating to geochemistry. Focusing on recent research in groundwater resources, this book helps readers to understand the hydrogeochemistry of groundwater resources. Dealing primarily with the sources of ions in groundwater, the book describes geogenic and anthropogenic input of ions into water. Different organic, inorganic and emerging contamination and salinity problems are described, along with pollution-related issues affecting groundwater. New trends in groundwater contamination remediation measures are included, which will be particularly useful to researchers working in the field of water conservation. The book also contains diverse groundwater modelling examples, enabling a better understanding of water-related issues and their management. Groundwater Geochemistry: Pollution and Remediation offers the reader: An understanding of the quantitative and qualitative challenges of groundwater resources An introduction to the environmental geochemistry of groundwater resources A survey of groundwater pollution-related issues Recent trends in groundwater conservation and remediation Mathematical and statistical modeling related to groundwater resources Students, lecturers and researchers working in the fields of hydrogeochemistry, water pollution and groundwater will find Groundwater Geochemistry an essential companion.

Manganese Removal from Groundwater

Manganese Removal from Groundwater
Author: J.H. Bruins
Publisher: CRC Press
Total Pages: 162
Release: 2017-03-16
Genre: Technology & Engineering
ISBN: 1351652508

In The Netherlands, Belgium and other European countries, manganese is removed by conventional groundwater treatment with aeration and rapid (sand) filtration. Such a treatment process is easy to operate, cost effective and sustainable, because it does not make use of strong oxidants such as O3, Cl2, ClO2 and KMnO4 with the associated risk of by-product formation and over or under dosing. However, application of aeration-filtration is also facing drawbacks, especially the long ripening time of filter media. Due to the long ripening time, water companies have to waste large volumes of treated water, making this process less sustainable. Also, costs associated with filter media ripening (man power, electricity, operational and analysis costs) are high. Therefore decreasing the filter ripening time, regarding manganese removal is a big issue. Although already extended research has been carried out into manganese removal, the controlling mechanisms, especially of the start up face of filter media ripening, are not fully understood yet. The emphasis of this thesis is to provide a better understanding of the mechanisms involved in the ripening of virgin filter media, regarding manganese removal and how to shorten or completely eliminate the long ripening period of filters with virgin material. This thesis therefore highlights the role of the formation of a manganese oxide coating on virgin filter media. Characterization and identification revealed that the responsible manganese oxide for an effective manganese removal was Birnessite. It was found that Birnessite, formed at the beginning of the ripening process was of a biological origin. Based on the knowledge that manganese removal in conventional groundwater treatment is initiated biologically, long ripening times may be reduced by creating conditions favouring the growth of manganese oxidizing bacteria, e.g., by limiting the back wash frequency and / or intensity. Additionally, this thesis also shows that the use of freshly prepared manganese oxide, containing Birnessite, can completely eliminate filter media ripening time.

Fluoride Removal from Groundwater by Adsorption Technology

Fluoride Removal from Groundwater by Adsorption Technology
Author: Abdulai Salifu
Publisher: CRC Press
Total Pages: 276
Release: 2018-09-27
Genre:
ISBN: 9781138373204

In the Eastern corridor of Northern region of Ghana, presence of high fluoride concentration in the groundwater has made many drilled boreholes unusable for drinking. Little is, however, known about the factors contributing to the occurrence of high fluoride in this part of Ghana and it's spatial distribution. Treatment of the fluoride-contaminated groundwater by adsorption is also hampered by the lack of suitable adsorbents that are locally available. Based on principal component analysis, and saturation indices calculations, this thesis highlights that, the predominant mechanisms controlling the fluoride enrichment probably include calcite precipitation and Na/Ca exchange processes, both of which deplete Ca from the groundwater, and promote the dissolution of fluorite. The mechanisms also include F-/OH-anion exchange processes, as well as evapotranspiration processes which concentrate the fluoride ions, hence increasing its concentration in the groundwater. Spatial mapping showed that the high fluoride groundwaters occur predominantly in the Saboba, Cheriponi and Yendi districts. The thesis further highlights that, modifying the surface of indigenous materials by an aluminium coating process, is a very promising approach to develop a suitable fluoride adsorbent. Aluminum oxide coated media reduced fluoride in water from 5. 0 ± 0.2 mg/L to ≤ 1.5 mg/L (which is the WHO health based guideline for fluoride), in both batch and continuous flow column experiments in the laboratory. Kinetic and isotherm studies, thermodynamic calculations, as well as analytical results from Fourier Transform Infrared Spectroscopy and Raman spectroscopy, suggest the mechanism of fluoride adsorption onto aluminium oxide coated media involved both physisorption and chemisorption processes. Field testing in a fluoritic community in Northern Ghana showed that the adsorbent is also capable of treating fluoride-contaminated groundwater in field conditions, suggesting it is a promising defluoridation adsorbent. The adsorbent also showed good regenerability potential that would allow re-use, which could make it practically and economically viable. Additional research is, however, required to further increase the fluoride adsorption capacity of developed adsorbent.

Physical and Chemical Separation in Water and Wastewater Treatment

Physical and Chemical Separation in Water and Wastewater Treatment
Author: Norihito Tambo
Publisher: IWA Publishing
Total Pages: 0
Release: 2020-11-15
Genre: Science
ISBN: 9781789061291

Based upon half a century of research by the authors, Physical and Chemical Separation in Water and Wastewater Treatment addresses the whole water cycle spectrum, from global hydrological cycle, urban-regional metabolic cycle to individual living and production cycle, with respect to quality control technology based on fundamental science and theories. For every treatment process, basic scientific and environmental physical and chemical natures are explained with respect to those of water and its impurities. Health danger and risks for human beings are also covered. The authors define water qualities on a “Water Quality Matrix” composed of 35 elements. The vertical axis (row), has individual 7digit impurity size from 10-10m (water molecule 3?) to 10-3m (0.1mm sand grains) and in the horizontal axis(column) there are 5 categories of surrogate chemical and biochemical quality indices. The same 35 element matrix is used to correspond with several typical water quality treatments, unit-operation/unit-process, with a suitable characteristic grouping of the elements. The authors then present “the Water Quality Conversion Matrix” or “Water Quality Treatment Matrix”. With respect to typical treatment processes, the basic concept and scientific background are explained and the background of the technologies is clarified. Mechanisms of the process are explained and a kinetic process is formulated. The kinetics are experimentally verified quantitatively with important equilibrium and rate constants. Based on the authors’ research, various new treatment technologies are proposed with high efficiency, high capacity and less energy, and with steady operation ability. This comprehensive reference book is intended for undergraduate and graduate students, and also serves as a guide book for practical engineers and industry and university researchers.

Iron Nanomaterials for Water and Soil Treatment

Iron Nanomaterials for Water and Soil Treatment
Author: Marta I. Litter
Publisher: CRC Press
Total Pages: 393
Release: 2018-09-03
Genre: Science
ISBN: 1351334786

Nanotechnology has a great potential for providing efficient, cost-effective, and environmentally acceptable solutions to face the increasing requirements on quality and quantity of fresh water for industrial, agricultural, or human use. Iron nanomaterials, either zerovalent iron (nZVI) or iron oxides (nFeOx), present key physicochemical properties that make them particularly attractive as contaminant removal agents for water and soil cleaning. The large surface area of these nanoparticles imparts high sorption capacity to them, along with the ability to be functionalized for the enhancement of their affinity and selectivity. However, one of the most important properties is the outstanding capacity to act as redox-active materials, transforming the pollutants to less noxious chemical species by either oxidation or reduction, such as reduction of Cr(VI) to Cr(III) and dehalogenation of hydrocarbons. This book focuses on the methods of preparation of iron nanomaterials that can carry out contaminant removal processes and the use of these nanoparticles for cleaning waters and soils. It carefully explains the different aspects of the synthesis and characterization of iron nanoparticles and methods to evaluate their ability to remove contaminants, along with practical deployment. It overviews the advantages and disadvantages of using iron-based nanomaterials and presents a vision for the future of this nanotechnology. While this is an easy-to-understand book for beginners, it provides the latest updates to experts of this field. It also opens a multidisciplinary scope for engineers, scientists, and undergraduate and postgraduate students. Although there are a number of books published on the subject of nanomaterials, not too many of them are especially devoted to iron materials, which are rather of low cost, are nontoxic, and can be prepared easily and envisaged to be used in a large variety of applications. The literature has scarce reviews on preparation of iron nanoparticles from natural sources and lacks emphasis on the different processes, such as adsorption, redox pathways, and ionic exchange, taking place in the removal of different pollutants. Reports and mechanisms on soil treatment are not commonly found in the literature. This book opens a multidisciplinary scope for engineers and scientists and also for undergraduate or postgraduate students.