Transition-Metal-Promoted Reactions of Boron Hydrides. 6.1 Platinum(II) Bromide Catalyzed Borane and Carborane Dehydrodimerization Reactions. A New Synthetic Route to Boron-Boron Linked Multicage Boranes and Carboranes

Transition-Metal-Promoted Reactions of Boron Hydrides. 6.1 Platinum(II) Bromide Catalyzed Borane and Carborane Dehydrodimerization Reactions. A New Synthetic Route to Boron-Boron Linked Multicage Boranes and Carboranes
Author: E. W Corcoran (Jr)
Publisher:
Total Pages: 9
Release: 1984
Genre:
ISBN:

Platinum dibromide has been found to be a general dehydrodimerization catalyst for boron-boron linked polyhedral cage compounds. The reactions of a variety of small cage systems were explored, and all coupling reactions were found to proceed at moderate temperatures, were highly selective, and gave excellent yields of linked-cage products. These techniques have been used to prepare a number of new coupled cage boron hydrides and carboranes, including 1:1'-B4H92, 1:2'-B4H9B5H8, 1:2'-B4H91'-CH3B5H7, 1:2'-2-CH3B5H73'-CH3B5H7, and 2:2'-1,6-C2B4H52, as well as to provide synthetic routes to the previously known compounds, 1:2'-B5H82 and 2:2'-1,5-C2B3H42.

Organometallic Compounds

Organometallic Compounds
Author: Dakeshwar Kumar Verma
Publisher: John Wiley & Sons
Total Pages: 453
Release: 2023-03-08
Genre: Science
ISBN: 3527351787

Organometallic Compounds An up-to-date overview of the fundamentals, synthesis, and applications of organometallic compounds Organometallic Compounds: Synthesis, Reactions, and Applications delivers an accessible and robust introduction to the fundamentals of organometallic compounds, including their reactions, catalytic mechanisms, and modern applications, including carbon-dioxide fixation, reduction, gas adsorption and purification, drug delivery, renewable energy, and wastewater treatment. The book also covers toxicological and computational studies. The authors address the current challenges confronting researchers seeking to sustainably synthesize and process organometallic compounds and offer complete coverage on the most recent advancements in applications relating to the fields of environmental science, electronics, fossil fuels, and more. Readers will also find: Introduces to fundamentals, nomenclature, properties, and classification of organometallic compounds Discusses methods of synthesis of organometallic compounds Practical discussions of organometallic complexes of the lanthanoids and actinoids, as well as bio-organometallic chemistry Includes characterization techniques of organometallic compounds Perfect for organic, environmental, inorganic, water, and catalytic chemists, Organometallic Compounds: Synthesis, Reactions, and Applications will also benefit chemical engineers and industrial chemists.