Transformation Of Carbon Dioxide To Formic Acid And Methanol
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| Author | : Yuichiro Himeda |
| Publisher | : John Wiley & Sons |
| Total Pages | : 322 |
| Release | : 2021-06-28 |
| Genre | : Technology & Engineering |
| ISBN | : 3527346635 |
A guide to the effective catalysts and latest advances in CO2 conversion in chemicals and fuels Carbon dioxide hydrogenation is one of the most promising and economic techniques to utilize CO2 emissions to produce value-added chemicals. With contributions from an international team of experts on the topic, CO2 Hydrogenation Catalysis offers a comprehensive review of the most recent developments in the catalytic hydrogenation of carbon dioxide to formic acid/formate, methanol, methane, and C2+ products. The book explores the electroreduction of carbon dioxide and contains an overview on hydrogen production from formic acid and methanol. With a practical review of the advances and challenges in future CO2 hydrogenation research, the book provides an important guide for researchers in academia and industry working in the field of catalysis, organometallic chemistry, green and sustainable chemistry, as well as energy conversion and storage. This important book: Offers a unique review of effective catalysts and the latest advances in CO2 conversion Explores how to utilize CO2 emissions to produce value-added chemicals and fuels such as methanol, olefins, gasoline, aromatics Includes the latest research in homogeneous and heterogeneous catalysis as well as electrocatalysis Highlights advances and challenges for future investigation Written for chemists, catalytic chemists, electrochemists, chemists in industry, and chemical engineers, CO2 Hydrogenation Catalysis offers a comprehensive resource to understanding how CO2 emissions can create value-added chemicals.
| Author | : Wan-Hui Wang |
| Publisher | : Springer |
| Total Pages | : 128 |
| Release | : 2017-10-26 |
| Genre | : Science |
| ISBN | : 9811032505 |
This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.
| Author | : P.A. Chaloner |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 293 |
| Release | : 2013-11-11 |
| Genre | : Science |
| ISBN | : 9401717915 |
Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.
| Author | : National Academies of Sciences, Engineering, and Medicine |
| Publisher | : National Academies Press |
| Total Pages | : 257 |
| Release | : 2019-02-22 |
| Genre | : Science |
| ISBN | : 0309483360 |
In the quest to mitigate the buildup of greenhouse gases in Earth's atmosphere, researchers and policymakers have increasingly turned their attention to techniques for capturing greenhouse gases such as carbon dioxide and methane, either from the locations where they are emitted or directly from the atmosphere. Once captured, these gases can be stored or put to use. While both carbon storage and carbon utilization have costs, utilization offers the opportunity to recover some of the cost and even generate economic value. While current carbon utilization projects operate at a relatively small scale, some estimates suggest the market for waste carbon-derived products could grow to hundreds of billions of dollars within a few decades, utilizing several thousand teragrams of waste carbon gases per year. Gaseous Carbon Waste Streams Utilization: Status and Research Needs assesses research and development needs relevant to understanding and improving the commercial viability of waste carbon utilization technologies and defines a research agenda to address key challenges. The report is intended to help inform decision making surrounding the development and deployment of waste carbon utilization technologies under a variety of circumstances, whether motivated by a goal to improve processes for making carbon-based products, to generate revenue, or to achieve environmental goals.
| Author | : Alexandre C. Dimian |
| Publisher | : Elsevier |
| Total Pages | : 756 |
| Release | : 2019-08-08 |
| Genre | : Technology & Engineering |
| ISBN | : 0444638865 |
Applications in Design and Simulation of Sustainable Chemical Processes addresses the challenging applications in designing eco-friendly but efficient chemical processes, including recent advances in chemistry and catalysis that rely on renewable raw materials. Grounded in the fundamental knowledge of chemistry, thermodynamics, chemical reaction engineering and unit operations, this book is an indispensable resource for developing and designing innovating chemical processes by employing computer simulations as an efficient conceptual tool. Targeted to graduate and post graduate students in chemical engineering, as well as to professionals, the book aims to advance their skills in process innovation and conceptual design. The work completes the book Integrated Design and Simulation of Chemical Processes by Elsevier (2014) authored by the same team. - Includes comprehensive case studies of innovative processes based on renewable raw materials - Outlines Process Systems Engineering approach with emphasis on systematic design methods - Employs steady-state and dynamic process simulation as problem analysis and flowsheet creation tool - Applies modern concepts, as process integration and intensification, for enhancing the sustainability
| Author | : George A. Olah |
| Publisher | : John Wiley & Sons |
| Total Pages | : 351 |
| Release | : 2011-08-24 |
| Genre | : Science |
| ISBN | : 3527644636 |
The world is currently consuming about 85 million barrels of oil a day, and about two-thirds as much natural gas equivalent, both derived from non-renewable natural sources. In the foreseeable future, our energy needs will come from any available alternate source. Methanol is one such viable alternative, and also offers a convenient solution for efficient energy storage on a large scale. In this updated and enlarged edition, renowned chemists discuss in a clear and readily accessible manner the pros and cons of humankind's current main energy sources, while providing new ways to overcome obstacles. Following an introduction, the authors look at the interrelationship of fuels and energy, and at the extent of our non-renewable fossil fuels. They also discuss the hydrogen economy and its significant shortcomings. The main focus is on the conversion of CO2 from industrial as well as natural sources into liquid methanol and related DME, a diesel fuel substitute that can replace LNG and LPG. The book is rounded off with an optimistic look at future possibilities. A forward-looking and inspiring work that vividly illustrates potential solutions to our energy and environmental problems.
| Author | : José J. G. Moura |
| Publisher | : Springer |
| Total Pages | : 506 |
| Release | : 2021-12-03 |
| Genre | : Science |
| ISBN | : 9783030583170 |
This book presents specific key natural and artificial systems that are promising biocatalysts in the areas of health, agriculture, environment and energy. It provides a comprehensive account of the state of the art of these systems and outlines the significant progress made in the last decade using these systems to develop innovative, sustainable and environmentally friendly solutions. Chapters from expert contributors explore how natural enzymes and artificial systems tackle specific targets such as: climate change, carbon footprint and economy and carbon dioxide utilisation; nitrogen footprint and fixation and nitrous oxide mitigation; hydrogen production, fuel cells and energy from bacteria; biomass transformation and production of added-value compounds, as well as biosensors development. This book provides an important and inspiring account for the designing of new natural and artificial systems with enhanced properties, and it appeals not only to students and researchers working in the fields of energy, health, food and environment, but also to a wider audience of educated readers that are interested in these up-to-date and exciting subjects. Chapter “Carbon Dioxide Utilisation—The Formate Route” is available open access under a Creative Commons Attribution 4.0 International License via link.springer.com.
| Author | : Annemie Bogaerts |
| Publisher | : MDPI |
| Total Pages | : 248 |
| Release | : 2019-04-02 |
| Genre | : Technology & Engineering |
| ISBN | : 3038977500 |
Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO2 conversion into value-added chemicals and fuels, N2 fixation for the synthesis of NH3 or NOx, methane conversion into higher hydrocarbons or oxygenates. It is also widely used for air pollution control (e.g., VOC remediation). Plasma catalysis allows thermodynamically difficult reactions to proceed at ambient pressure and temperature, due to activation of the gas molecules by energetic electrons created in the plasma. However, plasma is very reactive but not selective, and thus a catalyst is needed to improve the selectivity. In spite of the growing interest in plasma catalysis, the underlying mechanisms of the (possible) synergy between plasma and catalyst are not yet fully understood. Indeed, plasma catalysis is quite complicated, as the plasma will affect the catalyst and vice versa. Moreover, due to the reactive plasma environment, the most suitable catalysts will probably be different from thermal catalysts. More research is needed to better understand the plasma–catalyst interactions, in order to further improve the applications.
| Author | : Kingshuk Dutta |
| Publisher | : Elsevier |
| Total Pages | : 565 |
| Release | : 2020-02-25 |
| Genre | : Technology & Engineering |
| ISBN | : 0128191597 |
Direct Methanol Fuel Cell Technology presents the overall progress witnessed in the field of DMFC over the past decade, highlighting the components, materials, functions, properties and features, designs and configurations, operations, modelling, applications, pros and cons, social, political and market penetration, economics and future directions. The book discusses every single aspect of DMFC device technology, the associated advantages and drawbacks of state-of-the-art materials and design, market opportunities and commercialization aspects, and possible future directions of research and development. This book, containing critical analyses and opinions from experts around the world, will garner considerable interest among actual users/scientists/experts. - Analyzes developments of membrane electrolytes, electrodes, catalysts, catalyst supports, bipolar plates, gas diffusion layers and flow channels as critical components of direct methanol fuel cells - Includes modeling of direct methanol fuel cells to understand their scaling up potentials - Discusses commercial aspects of direct methanol fuel cells in terms of market penetration, end application, cost, viability, reliability, social and commercial perception, drawbacks and prospects
| Author | : Tomas Ramirez Reina |
| Publisher | : John Wiley & Sons |
| Total Pages | : 498 |
| Release | : 2021-02-25 |
| Genre | : Technology & Engineering |
| ISBN | : 3527346511 |
A comprehensive guide that offers a review of the current technologies that tackle CO2 emissions The race to reduce CO2 emissions continues to be an urgent global challenge. Engineering Solutions for CO2 Conversion offers a thorough guide to the most current technologies designed to mitigate CO2 emissions ranging from CO2 capture to CO2 utilization approaches. With contributions from an international panel representing a wide range of expertise, this book contains a multidisciplinary toolkit that covers the myriad aspects of CO2 conversion strategies. Comprehensive in scope, it explores the chemical, physical, engineering and economical facets of CO2 conversion. Engineering Solutions for CO2 Conversion explores a broad range of topics including linking CFD and process simulations, membranes technologies for efficient CO2 capture-conversion, biogas sweetening technologies, plasma-assisted conversion of CO2, and much more. This important resource: Addresses a pressing concern of global environmental damage, caused by the greenhouse gases emissions from fossil fuels Contains a review of the most current developments on the various aspects of CO2 capture and utilization strategies Incldues information on chemical, physical, engineering and economical facets of CO2 capture and utilization Offers in-depth insight into materials design, processing characterization, and computer modeling with respect to CO2 capture and conversion Written for catalytic chemists, electrochemists, process engineers, chemical engineers, chemists in industry, photochemists, environmental chemists, theoretical chemists, environmental officers, Engineering Solutions for CO2 Conversion provides the most current and expert information on the many aspects and challenges of CO2 conversion.
