The Synthesis Electrochemistry And Optical Spectroscopy Of Some Transition Metal Acetylide Complexes And Polymers
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Optical Spectra and Chemical Bonding in Transition Metal Complexes
Author | : Thomas Schönherr |
Publisher | : Springer |
Total Pages | : 310 |
Release | : 2004-09-30 |
Genre | : Science |
ISBN | : 9783540008545 |
Axel Christian Klixbüll Jørgensen was a “Polyhistor”,one of the very few in the highly specialized science of our time.His interests and contributions in ch- istry covered the whole Periodic Table.This statement demonstrates the breadth of his interests,however,it also sheds light on the constraints of chemistry which deals with a large, yet limited number of elements. It is not surprising that Jørgensen went beyond these limits,exploring the probable or plausible ch- istry of yet unknown elements and elementary particles such as quarks. Even chemistry itself did not place rigid limits on his mind,he was able to transfer his chemical concepts to scientific problems far beyond the normal such as in astrophysics. “Structure and Bonding” is intimately associated with the name C.K. J- gensen both as initiator and author over several decades.The appearance of a special edition in memory of this great scientist is a self-evident prolongation of his many contributions to the success of this series.
Conjugated Polymer Synthesis
Author | : Yoshiki Chujo |
Publisher | : John Wiley & Sons |
Total Pages | : 333 |
Release | : 2011-08-02 |
Genre | : Technology & Engineering |
ISBN | : 3527632689 |
Edited and authored by top international experts, this first book on conjugated polymers with a focus on synthesis provides a detailed overview of all modern synthetic methods for these highly interesting compounds. As such, it describes every important compound class, including polysilanes, organoboron compounds, and ferrocene-containing conjugated polymers. An indispensable source for every synthetic polymer chemist.
Spectroscopy and Electronic Structure of Transition Metal Complexes
Author | : Dimitrios A. Pantazis |
Publisher | : |
Total Pages | : 500 |
Release | : 2019-11-19 |
Genre | : Science |
ISBN | : 9781788014243 |
The combination of spectroscopy and theory has developed considerably in the past two decades. Computational techniques and theoretical analysis to extract electronic structure information from spectroscopy has become a crucial aspect of modern research in chemistry and materials science. This book provides a comprehensive and up-to-date resource on spectroscopic methods used in transition metal chemistry and explains the relationships between experimental techniques and electronic structure. Chapters cover topics including computational chemistry; ligand field theory; magnetochemistry; and optical, vibrational, NMR and EPR spectroscopy. Edited and written by world experts in the field, this unique volume is valuable to students of all levels and serves as a reference for researchers in physical inorganic chemistry, (bio)inorganic chemistry and spectroscopy.
Metallo-Supramolecular Polymers
Author | : Masayoshi Higuchi |
Publisher | : Springer Nature |
Total Pages | : 89 |
Release | : 2019-11-12 |
Genre | : Technology & Engineering |
ISBN | : 4431568913 |
This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.