The Interfacial Interactions in Polymeric Composites

The Interfacial Interactions in Polymeric Composites
Author: Güneri Akovali
Publisher: Springer
Total Pages: 455
Release: 2012-10-29
Genre: Technology & Engineering
ISBN: 9789401047173

Polymer composites represent materials of great and of continuously growing importance. Their potential for application appears to be limitless. They have been the subject of numerous studies both at academic and industrial levels. Much progress has been made in the incisive formulation of composites; sophisticated methods of property evaluation have been developed in the past decade and many, largely empirical solutions have been proposed to resolve the problem of their long-term performance under typical conditions of use (i. e. the use of silane or titane coupling agents to enhance adhesion within composite materials). Assuredly one of the most essential factors in the performance of these systems is the condition of the interface and interphase among the constituents of a given system. It has become clear that it is the interface/interphase, and the interactions which take place in this part of a system, which determine to a significant degree the initial properties of the material. In order to achieve leadership in the formulation and application of polymer composites, it is evident that in depth understanding of interfacial and interphase phenomena becomes a prerequisite.

The Interfacial Interactions in Polymeric Composites

The Interfacial Interactions in Polymeric Composites
Author: Güneri Akovali
Publisher: Springer Science & Business Media
Total Pages: 460
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401116423

Polymer composites represent materials of great and of continuously growing importance. Their potential for application appears to be limitless. They have been the subject of numerous studies both at academic and industrial levels. Much progress has been made in the incisive formulation of composites; sophisticated methods of property evaluation have been developed in the past decade and many, largely empirical solutions have been proposed to resolve the problem of their long-term performance under typical conditions of use (i. e. the use of silane or titane coupling agents to enhance adhesion within composite materials). Assuredly one of the most essential factors in the performance of these systems is the condition of the interface and interphase among the constituents of a given system. It has become clear that it is the interface/interphase, and the interactions which take place in this part of a system, which determine to a significant degree the initial properties of the material. In order to achieve leadership in the formulation and application of polymer composites, it is evident that in depth understanding of interfacial and interphase phenomena becomes a prerequisite.

Interface / Interphase in Polymer Nanocomposites

Interface / Interphase in Polymer Nanocomposites
Author: Anil N. Netravali
Publisher: John Wiley & Sons
Total Pages: 448
Release: 2016-11-29
Genre: Technology & Engineering
ISBN: 1119185181

Significant research has been done in polymeric nanocomposites and progress has been made in understanding nanofiller-polymer interface and interphase and their relation to nanocomposite properties. However, the information is scattered in many different publication media. This is the first book that consolidates the current knowledge on understanding, characterization and tailoring interfacial interactions between nanofillers and polymers by bringing together leading researchers and experts in this field to present their cutting edge research. Eleven chapters authored by senior subject specialists cover topics including: Thermodynamic mechanisms governing nanofiller dispersion, engineering of interphase with nanofillers Role of interphase in governing the mechanical, electrical, thermal and other functional properties of nanocomposites, characterization and modelling of the interphase Effects of crystallization on the interface, chemical and physical techniques for surface modification of nanocellulose reinforcements Electro-micromechanical and nanoindentation techniques for interface evaluation, molecular dynamics (MD) simulations to quantify filler-matrix adhesion and nanocomposite mechanical properties.

Polymer Composite Materials — Interface Phenomena & Processes

Polymer Composite Materials — Interface Phenomena & Processes
Author: Y. Ivanov
Publisher: Springer Science & Business Media
Total Pages: 176
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401096643

New technologies demand new materials. Polymer composites, with their wide range of possible fillers and polymers, open the way to an enormous range of materials with differing chemical, physical, and mechanical properties. The ultimate goal of polymer composite research is to formulate procedures that will lead to the design of composites with preset, i.e. specified, properties. Based on many years' experience in the field, the authors prepare the way towards just such a design procedure. The key element is the analysis and classification of the state of the filler-polymer interfaces from the point of view of their acid-base adsorption interactions. These interfacial phenomena play a pivotal role in determining overall properties of the composite: its rheological behaviour, its structural properties, catalytic effects in polymerization and polycondensation, and other technological characteristics. The book discusses and evaluates the extensive previous research scattered throughout the literature in Eastern Europe and the West, presents numerous experimental studies, and sets new benchmarks for the analysis of polymer composites. The book is required for researchers wanting to keep abreast of the progress in the burgeoning fields of polymer analysis and design.

Carbon Nanotube-polymer Composites

Carbon Nanotube-polymer Composites
Author: Dimitrios Tasis
Publisher: Royal Society of Chemistry
Total Pages: 293
Release: 2013
Genre: Science
ISBN: 1849735689

The purpose of this book is to summarize the basic chemical aspects for obtaining multifunctional carbon nanotube-based polymer composites, but also to highlight some of the most remarkable advances that occurred in the field during the last recent years.

Molecular Characterization of Composite Interfaces

Molecular Characterization of Composite Interfaces
Author: Hatsuo Ishida
Publisher: Springer Science & Business Media
Total Pages: 451
Release: 2013-11-11
Genre: Science
ISBN: 1489922512

This book is an extended version of the proceedings of the Symposium on Polymer Composites, Interfaces, which was held under the auspices of the Division of Polymer Chemistry, American Chemical Society (ACS) during the annual ACS meeting in Seattle, March, 1983. The importance of the interface in composite materials has been recognized since the inception of modern composite technology. Specifically, silane coupling agents were developed for glass fiber reinforced compOSites at a very early date. Ever since then the diversity of composite materials and the development of various surface treatment methods have led to the establishment of an "interface art." A trial-and-error approach has dominated the interfacial aspects of composite technology until very recently. With the advent of modern analytical techniques for surface characterization, it became possible to study detailed surface and interface structures. It was hoped that this symposium would catalyze such a fundamental and scientific approach in composite studies. For this reason, the symposium was structured to verify the influence of interfacial structures on the mechanical and physical performance of composites and to improve our knowledge of the microstructure of composite interfaces. As the word ·composite" indicates, interdisciplinary interaction is indispensable for proper understanding of multiphase systems.

Surface and Interfacial Aspects of Biomedical Polymers

Surface and Interfacial Aspects of Biomedical Polymers
Author: J.D. Andrade
Publisher: Springer Science & Business Media
Total Pages: 480
Release: 2012-12-06
Genre: Science
ISBN: 1468486101

This book is intended to provide a fundamental basis for the study of the interaction of polymers with living systems, biochemicals, and with aqueous solutions. The surface chemistry and physics of polymeric materials is a subject not normally covered to any significant extent in classical surface chemistry textbooks. Many of the assumptions of classical surface chemistry are invalid when applied to polymer surfaces. Surface properties of polymers are important in the development of medical devices and diagnostic products. Surface properties are also of vital importance in fields such as adhesion, paints and coatings, polymer-filler interactions, heterogeneous catalysis, composites, and polymers for energy generation. The book begins with a chapter considering the current sources of information on polymer surface chemistry and physics. It moves on to consider the question of the dynamics of polymer surfaces and the implica tions of polymer surface dynamics on all subsequent characterization and interfacial studies. Two chapters are directed toward the question of model polymers for preparing model surfaces and interfaces. Complete treatments of X-ray photoelectron spectroscopy and attenuated total reflection infrared spectroscopy are given. There is a detailed treatment of the contact angle with particular emphasis on contact angle hysteresis in aqueous systems, followed by chapters on interfacial electrochemistry and interface acid-base charge-transfer properties. The very difficult problem of block and graft copolymer surfaces is also discussed. The problem of theoretical calculations of surface and interfacial tensions is presented. Raman spectroscopy is considered as an analytical technique for polymer surface characterization.

Broadband Dielectric Spectroscopy

Broadband Dielectric Spectroscopy
Author: Friedrich Kremer
Publisher: Springer Science & Business Media
Total Pages: 740
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 3642561209

Both an introductory course to broadband dielectric spectroscopy and a monograph describing recent dielectric contributions to current topics, this book is the first to cover the topic and has been hotly awaited by the scientific community.

Spectroscopic Techniques for Polymer Characterization

Spectroscopic Techniques for Polymer Characterization
Author: Yukihiro Ozaki
Publisher: John Wiley & Sons
Total Pages: 500
Release: 2021-10-29
Genre: Science
ISBN: 3527830324

An insightful exploration of cutting-edge spectroscopic techniques in polymer characterization In Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications, a team of distinguished chemists delivers a comprehensive exploration of the vast potential of spectroscopic characterization techniques in polymer research. The book offers a concise outline of the principles, advantages, instrumentation, experimental techniques, and noteworthy applications of cutting-edge spectroscopy. Covering a wide range of polymers, from nylon to complex polymeric nanocomposites, the author presents recent developments in polymer science to polymer, analytical, and material chemists, assisting them in keeping track of the progress in modern spectroscopy. Spectroscopic Techniques for Polymer Characterization contains contributions from pioneers in modern spectroscopic techniques from around the world. The included materials bridge the gap between spectroscopists, polymer scientists, and engineers in academia and industry. The book also offers: A thorough introduction to the progress in spectroscopic techniques, including polymer spectroscopy and near-infrared spectroscopy Comprehensive explorations of topical polymers studied by spectroscopy, including polymer thin films, fluoropolymers, polymer solutions, conductive polymers Practical discussions of infrared imaging, near-infrared imaging, two-dimensional correlation spectroscopy, and far-ultraviolet spectroscopy In-depth examinations of spectroscopic studies of weak hydrogen bonding in polymers Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications is a must-read reference for polymer, analytical, and physical chemists, as well as materials scientists and spectroscopists seeking a one-stop resource for polymer characterization using spectroscopic analyses.

Adhesion Science and Engineering

Adhesion Science and Engineering
Author:
Publisher: Elsevier
Total Pages: 2020
Release: 2002-11-14
Genre: Science
ISBN: 0080525989

The Mechanics of Adhesion shows that adhesion science and technology is inherently an interdisciplinary field, requiring fundamental understanding of mechanics, surfaces, and materials. This volume comprises 19 chapters. Starting with a background and introduction to stress transfer principles; fracture mechanics and singularities; and an energy approach to debonding, the volume continues with analysis of structural lap and butt joint configurations. It then continues with discussions of test methods for strength and constitutive properties; fracture; peel; coatings, the case of adhesion to a single substrate; elastomeric adhesives such as sealants. The role of mechanics in determining the locus of failure in bonded joints is discussed, followed by a chapter on rheology relevant to adhesives and sealants. Pressure sensitive adhesive performance; the principles of tack and tack measurements; and contact mechanics relevant to wetting and surface energy measurements are then covered. The volume concludes with sections on fibermatrix bonding and reinforcement; durability considerations for adhesive bonds; ultrasonic non-destructive evaluation of adhesive bonds; and design of adhesive bonds from a strength perspective. This book will be of interest to practitioners in the fields of engineering and to those with an interest in adhesion science.