Synthesis of Heterometallic Zinc-Gold and Lanthanide-Transition Metal Carbonyl Complexes and Reactivity Study of Pentaphosphaferrocene Towards Low-Valent Main Group Species

Synthesis of Heterometallic Zinc-Gold and Lanthanide-Transition Metal Carbonyl Complexes and Reactivity Study of Pentaphosphaferrocene Towards Low-Valent Main Group Species
Author: Ravi Yadav
Publisher:
Total Pages: 170
Release: 2019-11-27
Genre:
ISBN: 9783736971233

The work reported in this thesis is divided into three parts. In the first part, the synthesis of Zn-Au heterometallic complexes is described by using bifunctional carboxy-phosphine ligands. The second part of this thesis focuses on redox reactions between divalent lanthanides (LnII) and transition metal (TM) carbonyl complexes for the synthesis of high nuclearity heterometallic complexes. The third and final part of this thesis focuses on reactivity studies of [Cp*Fe(Л5-P5)] with lowvalent main group compounds.

Zinc Catalysis

Zinc Catalysis
Author: Stephan Enthaler
Publisher: John Wiley & Sons
Total Pages: 328
Release: 2015-02-17
Genre: Technology & Engineering
ISBN: 3527675973

Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.

Inorganometallic Chemistry

Inorganometallic Chemistry
Author: Thomas P. Fehlner
Publisher: Springer Science & Business Media
Total Pages: 409
Release: 2013-11-22
Genre: Science
ISBN: 1489924590

There is a certain fascination associated with words. The manipulation of strings of symbols according to mutually accepted rules allows a language to express history as well as to formulate challenges for the future. But language changes as old words are used in a new context and new words are created to describe changing situations. How many words has the computer revolution alone added to languages? "Inorganometallic" is a word you probably have never encountered before. It is one created from old words to express a new presence. A strange sounding word, it is also a term fraught with internal contradiction caused by the accepted meanings of its constituent parts. "In organic" is the name of a discipline of chemistry while "metallic" refers to a set of elements constituting a subsection of that discipline. Why then this Carrollian approach to entitling a set of serious academic papers? Organic, the acknowledged doyenne of chemistry, is distinguished from her brother, inorganic, by the prefix "in," i. e. , he gets everything not organic. Organometallic refers to compounds with carbon-metal bonds. It is simple! Inorganometallic is everything else, i. e. , compounds with noncarbon-metal element bonds. But why a new term? Is not inorganic sufficient? By virtue of training, limited time, resources, co-workers, and so on, chemists tend to work on a specific element class, on a particular compound type, or in a particular phase. Thus, one finds element-oriented chemists (e. g.

Topics in Inorganic and Organometallic Stereochemistry

Topics in Inorganic and Organometallic Stereochemistry
Author: Gregory L. Geoffroy
Publisher: John Wiley & Sons
Total Pages: 366
Release: 2009-09-17
Genre: Science
ISBN: 0470147431

This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research—the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.

Experiments in Green and Sustainable Chemistry

Experiments in Green and Sustainable Chemistry
Author: Herbert W. Roesky
Publisher: Wiley-VCH
Total Pages: 0
Release: 2009-06-08
Genre: Science
ISBN: 9783527325467

Encouraging a new attitude and approach to chemistry, this is the first such collection designed for lab courses and experimental teaching. Experts from around the globe present over 40 real-life teaching experiments, all clearly structured and divided into the five main principles of sustainable and green chemistry: catalysis, solvents, high yield and one-pot synthesis, limiting waste and exposure, as well as special topics. With a foreword by Nobel prize winner Jean Marie Lehn.

The Chemistry of the Cyclopropyl Group (NY Handling Set Only)

The Chemistry of the Cyclopropyl Group (NY Handling Set Only)
Author: Zvi Rappoport
Publisher:
Total Pages: 832
Release: 1987
Genre: Science
ISBN:

The latest in a series of advanced treatises under the general editorship of Professor Saul Patai providing a comprehensive review of the chemistry of the cyclopropyl group including physical properties, analysis, reaction mechanisms and synthetic uses.

Rare Earth Chemistry

Rare Earth Chemistry
Author: Rainer Pöttgen
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 669
Release: 2020-10-26
Genre: Science
ISBN: 311065492X

This work introduces into the chemistry, materials science and technology of Rare Earth Elements. The chapters by experienced lecturers describe comprehensively the recent studies of their characteristics, properties and applications in functional materials. Due to the broad range of covered topics as hydrogen storage materials, LEDs or permanent magnets this work gives an up-to-date presentation of this fascinating research.