Supramolecular Science

Supramolecular Science
Author: Rocco Ungaro
Publisher: Springer Science & Business Media
Total Pages: 331
Release: 2012-12-06
Genre: Science
ISBN: 9401145547

A summary of all the most important aspects of supramolecular science, from molecular recognition in chemical and biological systems to supramolecular devices, materials and catalysis. The 17 chapters cover calixarenes, catenanes, cavitands, cholophanes, dendrimers, membranes and self-assembly systems, molecular modelling, molecular level devices, organic materials, peptides and protein surfaces, recognition of carbohydrates, rotaxanes, supramolecular catalysis. A forward-looking chapter written by J.-M. Lehn indicated the future prospects for the entire field. Audience: Ph.D. students and young researchers in chemistry, physics and biology.

Crystal Engineering: The Design and Application of Functional Solids

Crystal Engineering: The Design and Application of Functional Solids
Author: Kenneth Richard Seddon
Publisher: Springer Science & Business Media
Total Pages: 524
Release: 1999-09-30
Genre: Science
ISBN: 9780792359050

Crystal engineers need an understanding of bonding theory, computational chemistry, applied spectroscopy, structural methods, synthesis strategies, and applications of custom-designed solids. This book contains chapters on all these topics, written by internationally recognized experts, plus contributions from leading researchers in the field.

NMR in Supramolecular Chemistry

NMR in Supramolecular Chemistry
Author: M. Pons
Publisher: Springer Science & Business Media
Total Pages: 352
Release: 2012-12-06
Genre: Science
ISBN: 9401146152

NMR is better suited than any other experimental technique for the characterization of supramolecular systems in solution. The presentations included here can be broadly divided into three classes. The first class illustrates the state of the art in the design of supramolecular systems and includes examples of different classes of supramolecular complexes: catenanes, rotaxanes, hydrogen-bonded rosettes, tubes, capsules, dendrimers, and metal-containing hosts. The second class comprises contributions to NMR methods that can be applied to address the main structural problems that arise in supramolecular chemistry. The third class includes biological supramolecular systems studied by state-of-the-art NMR techniques.

Calixarenes 2001

Calixarenes 2001
Author: M.-Z. Asfari
Publisher: Springer Science & Business Media
Total Pages: 692
Release: 2007-05-08
Genre: Science
ISBN: 0306475227

Calixarene chemistry, at the turn of the millennium, is a field approaching true maturity. In many areas, applications are real and important, and the arsenal of structures based on calixarenes provides tools effective in numerous areas of supramolecular chemistry. In this book, chapters contributed by a broad spectrum of international authors provide a variety of perspectives upon the progress and future of calixarene chemistry. Issues covered in depth include: Calixarene synthesis, with all its subtleties and sophistication. Forces at play in the inclusion of neutral and charged molecules by calixarenes. Theoretical analyses of calixarene properties. Dynamics and thermodynamics of calixarenes and their complexes. Nanocomposite construction based on calixarene aggregates. Calixarenes on surfaces. Analytical applications of calixarenes. Catalysis by calixarenes and their complexes. Resource recovery and waste treatment with calixarenes. New directions in calixarene chemistry. Hetero- and homo-calixarenes. Bioactive calixarenes. Coordination chemistry of calixarenes. Calixarenes in the solid state.

Stable Radicals

Stable Radicals
Author: Robin Hicks
Publisher: John Wiley & Sons
Total Pages: 628
Release: 2011-08-02
Genre: Science
ISBN: 111995696X

Stable radicals - molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques - have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science.

Modern Inorganic Synthetic Chemistry

Modern Inorganic Synthetic Chemistry
Author: Ruren Xu
Publisher: Elsevier
Total Pages: 612
Release: 2011-01-13
Genre: Science
ISBN: 0444535993

The contributors to this book discuss inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions. They go on to describe the synthesis, preparation and assembly of six important categories of compounds with wide coverage of distinct synthetic chemistry systems

Molecular Materials and Functional Polymers

Molecular Materials and Functional Polymers
Author: Werner J. Blau
Publisher: Springer Science & Business Media
Total Pages: 191
Release: 2011-06-28
Genre: Technology & Engineering
ISBN: 3709162769

The articles in this book summarize the work presented at the final workshop of the COST (European Cooperation in the Field of Scientific and Technical Research) Action on Molecular Materials and Functional Polymers for Advanced Devices, which was held in June 2000 in Patras, Greece. The collection gives an excellent overview of the state-of-the-art in this field and the progress made by the coordinated research projects. The results range over the synthesis, physical properties, and applications of molecular materials (nanotubes, fullerenes, phthalocyanines), inorganic and inorganic-organic hybrid materials, and functional polymers (electronic conduction, photoluminiscence, optical storage, photovoltaic devices).

Whistler Phenomena

Whistler Phenomena
Author: C. Ferencz
Publisher: Springer Science & Business Media
Total Pages: 772
Release: 2001-06-30
Genre: Medical
ISBN: 9780792369950

In this volume, the authors present theoretical explanations for a few basic problems connected with the propagation of extra wide band, short impulses in linear media, and with the propagation of whistlers and megawhistlers in plasmas. In addition, the book provides an overview of ground and space based measurements, digital processing and signal analysis. The theoretical treatment in this volume is original in the sense that, unlike former solutions, the authors present a fundamentally non-monochromatic approach. A key feature of this approach is the application of the `Laplace Transformation' and the `Method of Inhomogeneous Basic Modes' to solve Maxwell's equations. It is shown that when the obtained theoretical results are applied to digital recordings, the wave analysis process becomes so flexible that it can also be used to investigate other wave propagation problems. These are both terrestrial phenomena (like atmospheric and seismic activity, buried target detection, etc.) and phenomena in space (planetary, interplanetary, plasmaspheric, whistler and megawhistler propagation). The book is aimed at a technical and professional audience working on whistler science and/or wave propagation problems.

Metal-Organic and Organic Molecular Magnets

Metal-Organic and Organic Molecular Magnets
Author: Peter Day
Publisher: Royal Society of Chemistry
Total Pages: 333
Release: 2007-10-31
Genre: Science
ISBN: 1847551394

Traditionally, magnetic materials have been metals or, if inorganic compounds such as oxides, of continuous lattice type. However, in recent years chemists have synthesized increasing numbers of crystalline solids based on molecular building blocks in the form of coordination and organometallic complexes or purely organic molecules, which exhibit spontaneous magnetization. In striking contrast to conventional magnets, these materials are made from solutions close to room temperature rather than by metallurgical or ceramic methods. This book, which originates from contributions to a Discussion Meeting of The Royal Society of London, brings together many of the leading international practitioners in the field, who survey their own recent work and place it in the context of the wider fields of magnetism and supramolecular chemistry. All aspects of molecular-based magnets are addressed, including synthesis, structure-property relations and physical properties. Contents include details of the characterization of the first purely organic ferromagnet, the synthesis of high coercivity materials and a unique description of new materials with Curie temperatures well above ambient. A coherent survey of this rapidly developing field for the more general reader, Metal-Organic and Organic Molecular Magnets will also be welcomed by researchers and lecturers in materials science and inorganic or solid state chemistry.