Spectroscopy Of The Transition State Region In Hydrogen Transfer Reactions
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| Total Pages | : 6 |
| Release | : 1994 |
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The research supported by this grant is centered on probing the spectroscopy and dynamics of a variety of transient species using two anion photodetachment techniques: photoelectron spectroscopy and zero electron kinetic energy spectroscopy. Most of the research effort was devoted to the transition state spectroscopy of reactions involving H atom abstraction by fluorine atoms. We have also measured electron affinities of several radicals, and have characterized several of the excited electronic states O3 for the first time. Finally, we have begun studying weakly bound clusters in which a halide ion is solvated by known number of CO2 molecules.
| Author | : I. M. Waller |
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| Total Pages | : 18 |
| Release | : 1990 |
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We have developed a method for probing the transition state region of a neutral bimolecular reaction via photodetachment of a stable negative ion similar in structure to the neutral transition state. In several cases, we have found that the photoelectron spectrum of the hydrogen-bonded anion AHB( - ) exhibits resolved vibrational structure which can be assigned to an unstable (AHB) complex located near the transition state for the hydrogen transfer reaction A + HB yields HA + B. The results described previously were obtained with a fixed-frequency negative ion photoelectron spectrometer. Here we report considerably higher resolution results for IHI( - ) obtained on a recently constructed threshold photodetachment spectrometer. In this experiment, mass-selected ions are photodetached with a tunable pulsed laser, and only those photoelectrons produced with nearly zero kinetic energy are detected as a function of laser wavelength. The threshold photodetachment spectrum of IHI( - ) shows considerably more structure than was observed in the lower resolution photoelectron spectrum. In particular, we observe narrow (30 cm) peaks due to long-lived states of the (IHI) complex which lie well above the I + HI(v=0) asymptote. Keywords: Molecular rotation, Excitation. (AW).
| Author | : Takayuki Fueno |
| Publisher | : CRC Press |
| Total Pages | : 348 |
| Release | : 1999-07-22 |
| Genre | : Science |
| ISBN | : 9789056992163 |
The transition state is the critical configuration of a reaction system situated at the highest point of the most favorable reaction path on the potential-energy surface, its characteristics governing the dynamic behavior of reacting systems decisively. This text presents an accurate survey of current theoretical investigations of chemical reactions, with a focus on the nature of the transition state. Its scope ranges from general basic theories associated with the transition states, to their computer-assisted applications, through to a number of reactions in a state-of-the-art fashion. It covers various types of gas-phase elementary reactions, as well as some specific types of chemical processes taking place in the liquid phase. Also investigated is the recently developing transition state spectroscopy. This text will not only serve as a contemporary reference book on the concept of the transition state, but will also assist the readers in gaining valuable key principles regarding the essence of chemical kinetics and dynamics.
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| Total Pages | : 422 |
| Release | : 1992 |
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The transition state region of a neutral bimolecular reaction may be experimentally investigated by photoelectron spectroscopy of an appropriate negative ion. The photoelectron spectrum provides information on the spectroscopy and dynamics of the short lived transition state and may be used to develop model potential energy surfaces that are semi-quantitative in this important region. The principles of bound [yields] bound negative ion photoelectron spectroscopy are illustrated by way of an example: a full analysis of the photoelectron bands of CN[sup [minus]], NCO[sup [minus]] and NCS[sup [minus]]. Transition state photoelectron spectra are presented for the following systems Br + HI, Cl + HI, F + HI, F + CH[sub 3]0H, F + C[sub 2]H[sub 5]OH, F + OH and F + H[sub 2]. A time dependent framework for the simulation and interpretation of the bound [yields] free transition state photoelectron spectra is subsequently developed and applied to the hydrogen transfer reactions Br + HI, F + OH [yields] O([sup 3]P, [sup 1]D) + HF and F + H[sub 2]. The theoretical approach for the simulations is a fully quantum-mechanical wave packet propagation on a collinear model reaction potential surface. The connection between the wavepacket time evolution and the photoelectron spectrum is given by the time autocorrelation function. For the benchmark F + H[sub 2] system, comparisons with three-dimensional quantum calculations are made.
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| Total Pages | : 548 |
| Release | : 1995 |
| Genre | : Aeronautics |
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| Total Pages | : 7 |
| Release | : 1990 |
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During the three years of this grant, a negative ion time-of-flight photoelectron spectrometer was constructed and used in a series of novel experiments designed to probe the transition state region in chemical reactions. In addition, conventional photoelectron spectra of several anions with high electron binding energies were obtained. Cold negative ions are produced in an ion source based on a pulsed free jet expansion. The ions are mass selected using a time of flight mass spectrometer. Ions of the desired mass are then photodetached with a pulsed, fixed-frequency laser, and the kinetic energy distribution of the ejected photoelectrons is determined by a second time-of- flight system. This allows us to map out the vibrational and electronic energy levels of the neutral species created by photodetachment of the mass-selected anions.
| Author | : Nicholas Leo Pivonka |
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| Total Pages | : 256 |
| Release | : 2002 |
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| Author | : Don Wesley Arnold |
| Publisher | : |
| Total Pages | : 506 |
| Release | : 1994 |
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| Total Pages | : 490 |
| Release | : 1993 |
| Genre | : Power resources |
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| Total Pages | : 504 |
| Release | : 1991 |
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Negative ion photodetachment is a versatile tool for the production and study of transient neutral species such as reaction intermediates and free radicals. Photodetachment of the stable XHY− anion provides a direct spectroscopic probe of the transition state region of the potential energy surface for the neutral hydrogen transfer reaction X + HY --> XH + Y, where X and Y are halogen atoms. The technique is especially sensitive to resonances, which occur at a specific energy, but the spectra also show features due to direct scattering. We have used collinear adiabatic simulations of the photoelectron spectra to evaluate trail potential energy surfaces for the biomolecular reactions and have extended the adiabatic approach to three dimensions and used it to evaluate empirical potential energy surfaces for the I + Hl and Br + HI reactions. In addition, we have derived an empirical, collinear potential energy surface for the Br + HBr reaction that reproduces our experimental results and have extended this surface to three dimensions. Photodetachment of a negative ion can be also used to study neutral free radicals. We have studied the vibrational and electronic spectroscopy of CH2NO2 by photoelectron spectroscopy of CH2NO2−, determining the electron affinity of CH2NO2, gaining insight on the bonding of the 2B1 ground state and observing the 2A2 excited state for the first time. Negative ion photodetachment also provides a novel and versatile source of mass-selected, jet-cooled free radicals. We have studied the photodissociation of CH2NO2 at 270, 235, and 208 nm, obtaining information on the dissociation products by measuring the kinetic energy release in the photodissociation.
