Spectroscopy of Rubbers and Rubbery Materials

Spectroscopy of Rubbers and Rubbery Materials
Author: Victor M. Litvinov
Publisher: iSmithers Rapra Publishing
Total Pages: 666
Release: 2002
Genre: Science
ISBN: 9781859572801

This book deals with the application of spectroscopic techniques for characterisation of chemical and physical structures in viscoelastic materials, such as unvulcanised elastomers and their vulcanisates, various rubbery materials and some plastics, which when blended with particular additives (plasticisers) behave like rubbers. Analysis of the rubbery materials is complicated by the fact that rubbery products, such as tyres, tubes, seals, V-belts and hoses, contain in the rubbery matrix a significant amount of various compounds, i.e., fillers, vulcanising agents, antioxidants and plasticisers. Due to the complex composition, no single technique can provide a good understanding of the effect of chemical and physical structures on the functional properties of rubbery materials. Thus spectroscopy has become a powerful tool for the determination of polymer structures. The most comprehensive information on chemical and physical structures in relation to material properties can be obtained by using a combination of macroscopic techniques and methods that provide information on the molecular level. frequently used for analysis of rubbery materials, i.e., various methods of nuclear magnetic resonance (NMR) and optical spectroscopy. The main objective of this present book is to discuss a wide range of applications of the spectroscopic techniques for the analysis of rubbery materials. The book brings together the various spectroscopic techniques for obtaining the following information: chemical structure of rubbery materials, network structure analysis, heterogeneity of rubbery materials, physical properties of rubbery materials, functional properties and stability of rubbery materials, processing of rubbery materials and quality control. The contents of this book are of interest to chemists, physicists, material scientists and technologists who seek a better understanding of rubbery materials.

Natural Rubber Materials

Natural Rubber Materials
Author: Sabu Thomas
Publisher: Royal Society of Chemistry
Total Pages: 635
Release: 2013-11-27
Genre: Technology & Engineering
ISBN: 1849737649

The combination of its unique morphology, physical properties, cost effectiveness and environmental friendliness make natural rubber an appealing constituent for many materials and applications. This comprehensive two volume set covers the synthesis, characterization and applications of natural rubber based blends, interpenetrating polymer networks, composites and nanocomposites. Volume 1 covers different types of natural rubber-based blends and IPNs as well as manufacturing methods, thermo mechanical characterization techniques, life cycle analysis and their applications. Volume 2 focuses on natural rubber-based composites and Nanocomposites including the different types of fillers, the filler-matrix reinforcement mechanisms, manufacturing techniques, and applications. This is the first book to consolidate the current state of the art information on natural rubber based materials with contributions from established international experts in the field. The book provides a "one stop" reference resource for professionals, researchers, industrial practitioners, graduate students, and senior undergraduates in the fields of polymer science and engineering, materials science, surface science, bioengineering and chemical engineering.

Rubber Analysis

Rubber Analysis
Author: Martin J. Forrest
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 360
Release: 2019-04-01
Genre: Technology & Engineering
ISBN: 3110640287

Rubber analysis plays a vital part in ensuring that manufactured products are fit for purpose. This comprehensive, application-based book with up-to-date referencing covers all important applications and subject area associated with the analysis of rubber compounds and rubber products. Includes characterization of rubber polymers, rubber fumes, identification of extractables and leachables, as well as reverse engineering on compounded products.

Epoxidised Natural Rubber

Epoxidised Natural Rubber
Author: Siti Salina Sarkawi
Publisher: Springer Nature
Total Pages: 328
Release: 2023-06-03
Genre: Technology & Engineering
ISBN: 9811988366

This book is a complete guide to epoxidized natural rubber covering from the epoxidation chemistry, production process, raw rubber and compound properties, mixing recommendations as its applications in tire, engineering, general and industrial rubber goods, latex based products such as adhesive, foam and paint as well as sustainability or life cycle analysis of ENR rubber. Hence, it is useful for readers either from the industry which looking for specific product application and properties, or scientists and academicians working on their research using the ENR in their study for reference and guidance.

Infrared Spectra of Rubbers, Plastics and Thermoplastic Elastomers

Infrared Spectra of Rubbers, Plastics and Thermoplastic Elastomers
Author: Yvonne Davies
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 444
Release: 2019-12-16
Genre: Science
ISBN: 3110645750

This handbook collects over 800 infrared spectra of rubbers, plastics and thermoplastics elastometers. It contains five different libraries: rubbers in transmission spectroscopy, rubbers in pyrolysate spectroscopy, plastics in transmission spectroscopy, plastics in pyrolysate spectroscopy, and rubbers and plastics in single-bounce ATR spectroscopy. This is an invaluable reference for the rubbers and plastics industry.

Pyrolysis-gas Chromatography/mass Spectrometry Of Polymeric Materials (Second Edition)

Pyrolysis-gas Chromatography/mass Spectrometry Of Polymeric Materials (Second Edition)
Author: Peter Kusch
Publisher: World Scientific
Total Pages: 383
Release: 2023-08-28
Genre: Science
ISBN: 1800613008

Readers will find many practical applications of pyrolysis-GC/MS as well as R&D usage in this newly revised and expanded edition. Detailed experimental descriptions for the identification of synthetic polymers and copolymers are included. This volume presents the current state of analytical pyrolysis, and contains full identification of several classes of polymers/copolymers and biopolymers that readers will find helpful. Structures and functions of various types of pyrolyzers are explored, as well as the results of the pyrolysis-gas chromatographic-mass spectrometric identification of synthetic polymers/copolymers and biopolymers at 700°C.Practical applications of this hyphenated technique, detailing the analysis of microplastics, failure analysis in the automotive industry and solutions for technological problems are provided. Numerous practical applications of pyrolysis-GC/MS, for industrial and R&D usage, will be of benefit to Chemists and Engineers, as well as for students of Chemistry and Polymer Sciences.

Analysis of Rubber and Rubber-like Polymers

Analysis of Rubber and Rubber-like Polymers
Author: M.J. Loadman
Publisher: Springer Science & Business Media
Total Pages: 392
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401144354

The first edition of this book (1958) described an analytical situation which had existed for a number of years for maintaining quality control on vulcanizates of natural rubber although the situation had recently been disturbed by the introduction of a range of synthetic rubbers which required identification and quantitative estimation. For the former purpose 'wet' chemistry, based on various imperfectly understood organic reactions, was pressed into service. Alongside this was the first introduction of instrumental analysis, using the infrared spectra of either the polymers or, more usually, their pyrolytic products to 'fingerprint' the material. The identification of a range of organic accelerators, antioxidants and their derivatives which had been intro duced during the 1920s and 30s was, in the first edition, dealt with by a combination of column chromatography and infrared spectroscopy or by paper chromatography. Quantitative procedures were, however, still classical in the tradition of gravimetric or volumetric assays with an initially weighed sample yielding, after chemical manipulation, a carefully precipitated, dried and weighed end product, or a solution of known composition whose weight or titre, as a percentage of the initial sample, quantified the function being determined. The second edition of this work (1968) consolidated the newer techni ques which had been introduced in the first without adding to them although, in other applications of analytical chemistry, instrumental analysis had already brought about a transformation in laboratory practice.

Handbook of Polymer Science and Technology

Handbook of Polymer Science and Technology
Author: Nicholas Cheremisinoff
Publisher: CRC Press
Total Pages: 766
Release: 2023-07-21
Genre: Technology & Engineering
ISBN: 1000938484

This handbook focuses on physical, structural, and compositional properties of elastomeric materials and plastics. It provides a broad overview of the physical and physicochemical properties of synthetic rubbers that are used in conventional cured applications.

Single-Sided NMR

Single-Sided NMR
Author: Federico Casanova
Publisher: Springer Science & Business Media
Total Pages: 254
Release: 2011-01-28
Genre: Technology & Engineering
ISBN: 3642163076

This book describes the design of the first functioning single-sided tomograph, the related measurement methods, and a number of applications in medicine, materials science, and chemical engineering. It will be the first comprehensive account of this new device and its applications. Among the key advances of this method is that images can be obtained in much shorter times than originally anticipated, and that even vector maps of flow fields can be measured although the magnetic fields are highly inhomogeneous. Furthermore, the equipment is small, mobile and affordable to small and medium enterprises and can be located in doctors’ offices.

Monitoring Polymerization Reactions

Monitoring Polymerization Reactions
Author: Wayne F. Reed
Publisher: John Wiley & Sons
Total Pages: 493
Release: 2013-12-02
Genre: Technology & Engineering
ISBN: 1118733975

Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.