Self Assembly Of Metallo Supramolecular Coordination Complexes
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Supramolecular Coordination Complexes
Author | : Sankarasekaran Shanmugaraju |
Publisher | : Elsevier |
Total Pages | : 498 |
Release | : 2022-10-28 |
Genre | : Science |
ISBN | : 0323907059 |
Supramolecular Coordination Complexes: Design, Synthesis, and Applications discusses the growth of the field and explores the advantages, opportunities and latest applications of supramolecular complexes. Beginning with an introduction to design principles, synthetic methods, and post-synthetic functionalization of supramolecular complexes, the book goes on to compile the different analytical and computational modeling methods used to understand the structure and functional properties of supramolecular structures. Applications of supramolecular complexes in biomedicine, sensing, catalysis and materials are then explored in detail. Drawing on the knowledge of a global team of experts, this book provides a wealth of interesting information for students and researchers working in the design, synthesis or application of such complexes. Discusses cutting-edge approaches for the investigation of supramolecular coordination chemistry Summarizes a varied range of supramolecular coordination, complex designs and applications Highlights the interdisciplinary connections between supramolecular chemistry and the fields of biology and materials science
Metallomacrocycles
Author | : Hai-Bo Yang |
Publisher | : Royal Society of Chemistry |
Total Pages | : 304 |
Release | : 2018-10-05 |
Genre | : Science |
ISBN | : 1782628584 |
A comprehensive overview of metallomacrocycles from designing complex functional metallosupramolecular systems to their applications.
Molecular Self-Assembly
Author | : Alex Li Dequan |
Publisher | : CRC Press |
Total Pages | : 472 |
Release | : 2012-12-20 |
Genre | : Science |
ISBN | : 9814316776 |
In the past several decades, molecular self-assembly has emerged as one of the main themes in chemistry, biology, and materials science. This book compiles and details cutting-edge research in molecular assemblies ranging from self-organized peptide nanostructures and DNA-chromophore foldamers to supramolecular systems and metal-directed assemblies, even to nanocrystal superparticles and self-assembled microdevices
Metallo-Supramolecular Polymers
Author | : Masayoshi Higuchi |
Publisher | : Springer Nature |
Total Pages | : 89 |
Release | : 2019-11-12 |
Genre | : Technology & Engineering |
ISBN | : 4431568913 |
This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
Molecular Self-Assembly
Author | : Makoto Fujita |
Publisher | : Springer |
Total Pages | : 255 |
Release | : 2003-09-04 |
Genre | : Science |
ISBN | : 354046591X |
Self-assembly is undoubtedly a topic of special interest in current chemistry and is related to very wide scientific areas. Recent progress in this field seems to be featured by the construction of well-defined discrete systems exploiting complementary hydrogen bonding as well as coordination bonding. Seven leading international experts introduce the current topics in this very interesting field, focusing on two major subjects: organic assemblies and inorganic assemblies. All researchers who are interested in molecular recognition, material science, nanotechnology, and supramolecular chemistry will welcome this book as an inspiring source for creative research ideas.
Functional Metallosupramolecular Materials
Author | : John George Hardy |
Publisher | : Royal Society of Chemistry |
Total Pages | : 417 |
Release | : 2015-07-13 |
Genre | : Technology & Engineering |
ISBN | : 1782622675 |
There is great interest in metallosupramolecular materials because of their use in magnetic, photonic and electronic materials. Functional Metallosupramolecular Materials focuses on the applications of these materials covering the chemistry underlying the synthesis of a variety of ligands to coordinate various metal ions and the generation of 2D and 3D materials based on these constructs. The book starts by looking at different metallosupramolecular systems including naturally occurring functional metallosupramolecular materials; DNA-based metallosupramolecular materials; metallopolymers; metallogels as well as functional materials based on MOFs. Subsequent chapters then systematically cover the different applications such as molecular computation, spin-crossover, light harvesting and as photocatalysts for the production of solar fuels. The book provides an overview of functional metallosupramolecular materials that will be of interest to graduate students, academics and industrial chemists interested in supramolecular chemistry, materials science and the materials applications.
Anion Coordination Chemistry
Author | : Kristin Bowman-James |
Publisher | : John Wiley & Sons |
Total Pages | : 644 |
Release | : 2012-03-27 |
Genre | : Science |
ISBN | : 3527639519 |
Building on the pioneering work in supramolecular chemistry from the last 20 years or so, this monograph addresses new and recent approaches to anion coordination chemistry. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of anion complexes, sensing devices are presented and computational studies addressed to aid with the understanding of the different driving forces responsible for anion complexation. The reader is promised an actual picture of the state of the art for this exciting and constantly evolving field of supramolecular anion coordination chemistry. The topics range from ion channels to selective sensors, making it attractive to all researchers and PhD students with an interest in supramolecular chemistry.
Metallofoldamers
Author | : Galia Maayan |
Publisher | : John Wiley & Sons |
Total Pages | : 446 |
Release | : 2013-01-18 |
Genre | : Science |
ISBN | : 1118517431 |
Metallofoldamers are oligomers that fold into three-dimensional structures in a controlled manner upon coordination with metal ions. Molecules in this class have shown an impressive ability to form single-handed helical structures and other three-dimensional architectures. Several metallofoldamers have been applied as sensors due to their selective folding when binding to a specific metal ion, while others show promise for applications as responsive materials on the basis of their ability to fold and unfold upon changes in the oxidation state of the coordinated metal ion, and as novel catalysts. Metallofoldamers: From Helicates to Biomimetic Architectures describes the variety of interactions between oligomers and metal species, with a focus on non-natural synthetic molecules. Topics covered include: the major classes of foldamers and their folding driving force metalloproteins and metalloenzymes helicates: self-assembly, structure and applications abiotic metallo-DNA metallo-PNA and iDNA metallopeptides interactions of biomimetic oligomers with metal ions applications of metallofoldamers