Reactivity and Transport of Heavy Metals in Soils

Reactivity and Transport of Heavy Metals in Soils
Author: H. Magdi Selim
Publisher: CRC Press
Total Pages: 234
Release: 1996-10-09
Genre: Technology & Engineering
ISBN: 9780873714730

The fate of heavy metal particles in the environment is important because they tend to be reactive, mobile, and highly toxic. Reactivity and Transport of Heavy Metals in Soils examines the sometimes complex interactions that occur between metals and the soil they occupy. It discusses basic kinetic concepts and covers the predictability and consequences of metal-soil interactions. This practical guide presents and explains heavy metal issues crucial to hazardous waste site cleanup, including:

Geochemical and Hydrological Reactivity of Heavy Metals in Soils

Geochemical and Hydrological Reactivity of Heavy Metals in Soils
Author: H. Magdi Selim
Publisher: CRC Press
Total Pages: 386
Release: 2003-03-26
Genre: Technology & Engineering
ISBN: 0203009606

The hydrological and geochemical interactions between clay minerals and organic matter in soils directly influence the reaction, behavior, and mobility of heavy metals in soils. Geochemical and Hydrological Reactivity of Heavy Metals in Soils is one of few books that comprehensively illustrates this cause-and-effect relationship. It highlights anal

Metal Speciation and Contamination of Soil

Metal Speciation and Contamination of Soil
Author: Herbert E. Allen
Publisher: CRC Press
Total Pages: 384
Release: 1994-11-29
Genre: Technology & Engineering
ISBN: 9780873716970

Metal Speciation and Contamination of Soil provides a thorough overview of the biogeochemical processes governing the behavior, transport, and bioavailability of heavy metals in contaminated soils and suggests alternative approaches for effective remediation. This important new book contains contributions from experts in various disciplines who explore the issues from theoretical, experimental, and pragmatic perspectives. Topics include redox chemistry, kinetics of metal reactions, spectroscopic characterization of metal ion reactions at surface, modeling hydrologic transport phenomena and colloid-associated transport of metals through the soil profile to ground water, and remediation alternatives.

Transport & Fate of Chemicals in Soils

Transport & Fate of Chemicals in Soils
Author: H. Magdi Selim
Publisher: CRC Press
Total Pages: 356
Release: 2014-09-17
Genre: Science
ISBN: 146655794X

During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field. The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides. Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.

Competitive Sorption and Transport of Heavy Metals in Soils and Geological Media

Competitive Sorption and Transport of Heavy Metals in Soils and Geological Media
Author: H. Magdi Selim
Publisher: CRC Press
Total Pages: 420
Release: 2016-04-19
Genre: Science
ISBN: 1439880158

Most reported incidents of soil contamination include an array of heavy metals species rather than a single ion. The various interactions in these multicomponent or multiple-ion systems significantly impact the fate and transport of heavy metals, and competition for sorption sites on soil matrix surfaces is a common phenomenon. Because of this, con

Geochemical and Hydrological Reactivity of Heavy Metals in Soils

Geochemical and Hydrological Reactivity of Heavy Metals in Soils
Author: H. Magdi Selim
Publisher: CRC Press
Total Pages: 503
Release: 2003-03-26
Genre: Technology & Engineering
ISBN: 1135463271

The hydrological and geochemical interactions between clay minerals and organic matter in soils directly influence the reaction, behavior, and mobility of heavy metals in soils. Geochemical and Hydrological Reactivity of Heavy Metals in Soils is one of few books that comprehensively illustrates this cause-and-effect relationship. It highlights anal

Heavy Metals Release in Soils

Heavy Metals Release in Soils
Author: H. Magdi Selim
Publisher: CRC Press
Total Pages: 266
Release: 2001-06-15
Genre: Technology & Engineering
ISBN: 9781420032611

Understanding the mechanisms associated with metal complexes and the sequestering metal contaminants in the environment is essential for effective remediation. Heavy Metal Release in Soils describes and quantifies desorption/release kinetics and dissolution reactions in the release of heavy metals from soil. The book focuses on: New techniques - microscopic surface techniques, NMR and electrophoresis, XAFS, SFM, and time-resolved ATR-FTIR Theoretical analysis and kinetic approaches - adsorption/desorption hysteresis, competitive sorption and transport, multi-component models, speciation kinetics, isotherms and soil and metal parameters, and the role of soil properties on transport Applications - arsenic speciation and mobility in contaminated soils, modeling activity of CD, Zn, and Cu in contaminated soils, and in situ chemical immobilization A timely addition to the literature, this book highlights the desorption/release mechanisms for the purpose of resolving remediation dilemmas in contaminated environments. It gives you the added advantage of case studies at both the microscopic and macroscopic scales, and provides both experimental and numerical investigations. With contributions from an international panel of authors, Heavy Metals Release in Soils fills a gap in the current literature concerned with subsurface contaminant fate and transport processes.

Fate and Transport of Heavy Metals in the Vadose Zone

Fate and Transport of Heavy Metals in the Vadose Zone
Author: I.K. Iskandar
Publisher: CRC Press
Total Pages: 350
Release: 1999-04-23
Genre: Science
ISBN: 9780849341120

The chapters of this book were originally presented at the Fourth International Conference on the Biogeochemistry of Trace Elements, in June 1997 at Berkeley, California. The results of that symposium are now available to assist both specialists and those concerned with broader environmental issues. The first four chapters of Fate and Transport of Heavy Metals in the Vadose Zone are devoted to sorption-desorption processes. Subjects include the kinetics of trace metal sorption-desorption, adsorption of nickel and their isotherms, cadmium reactions, and retention mechanisms of both linear and nonlinear types. The next three sections describe complexation and speciation processes. The authors consider the effect of humic and fulvic acids, the binding of copper with organic matter, and the rate of dissolved selenium. Chapters eight through eleven scrutinize the bioavailability and retention of heavy metals and their mobility in the vadose zone. Twelve details plant-available concentration levels for heavy metals in the vadose zone. The last section relates case studies that are relevant to environmental affairs. Features

Principles of Contaminant Transport in Soils

Principles of Contaminant Transport in Soils
Author: Raymond Nen Yong
Publisher: Elsevier Science & Technology
Total Pages: 352
Release: 1992
Genre: Science
ISBN:

Waste generation and disposal; Soil composition; Wastes and contaminants; Soil-water interaction and relations; Contaminant-soil interaction; Soil permeability: characteristics and laboratory measurements; Evaluation of adsorption and diffusion; Contaminant transport modelling: solute transport; Contaminant transport modelling: transport of non-aqueous phase liquids.