Reactions of Organosulfur Compounds

Reactions of Organosulfur Compounds
Author: Eric Block
Publisher: Academic Press
Total Pages: 336
Release: 2013-10-22
Genre: Science
ISBN: 1483216438

Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.

Organic Sulfur Compounds

Organic Sulfur Compounds
Author: N. Kharasch
Publisher: Elsevier
Total Pages: 637
Release: 2013-10-22
Genre: Science
ISBN: 1483224856

Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.

Organosulfur Chemistry in Asymmetric Synthesis

Organosulfur Chemistry in Asymmetric Synthesis
Author: Takeshi Toru
Publisher: John Wiley & Sons
Total Pages: 448
Release: 2008-09-08
Genre: Science
ISBN: 3527623248

In this first book to gather the information on this hot topic otherwise widely spread throughout the literature, experienced editors and top international authors cover everything the reader needs -- from the synthesis of chiral organosulfur compounds to applications and catalysis: * Asymmetric synthesis of chiral sulfinates and sulfoxides * Synthesis and use of chiral dithioacetal derivatives, ylids, chiral sulfoximines and sulfinamides * Use of chiral sulfoxides as ligands in catalysis * Asymmetric reactions of alpha-sulfenyl, alpha-sulfinyl and alpha-sulfonyl carbanions. As a result, readers will be able to improve their own performance in asymmetric synthesis.

Reactions of Sulfur with Organic Compounds

Reactions of Sulfur with Organic Compounds
Author: Mikhail Grigorʹevich Voronkov
Publisher: Springer
Total Pages: 450
Release: 1987-07-31
Genre: Science
ISBN:

This book, written by the eminent Russian organic chemist Professor M. G. Voronkov, exhaustively deals with the reactions of sulfur with organic compounds. It is the only book on the subject which covers both work readily available to Western scientists and research carried out by Russian workers. Since much of the work discussed in this volume is not readily accessible to Western scien tists, it will enable them to find hitherto "unpublished" research. In addition, Professor Voronkov has dealt with many reactions and processes of interest to the industrial chemist; e.g., there is an interesting section on sulfur dyes and related compounds, and the chemistry of vulcanization is lucidly discussed. Hence this book should be of value to both academic and industrial chemists inter ested in the chemistry and reactions of sulfur, and also to those synthetic chemists studying new pathways to organic compounds. The text has recently been updated and revised, and there are numerous references to publications up to and including 1980. An exhaustive index is provided to enable the reader to refer rapidly to any of the compounds, reactions, or processes discussed in the text.

Chemistry of Organosulfur Compounds

Chemistry of Organosulfur Compounds
Author: Leonid Isaakovich Belenʹkiĭ
Publisher: Ellis Horwood
Total Pages: 390
Release: 1990
Genre: Science
ISBN:

A review of the major methods of producing sulfur-organic compounds, which presents data related to their applications and methods of catalytic synthesis. There is also a discussion on the conversion of compounds which have applications in the processes of polymerization and vulcanization.

Organic Chemistry of Sulfur

Organic Chemistry of Sulfur
Author: S. Oae
Publisher: Springer Science & Business Media
Total Pages: 714
Release: 2012-12-06
Genre: Science
ISBN: 1468420496

In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.