Reaction Kinetics And The Development And Operation Of Catalytic Processes
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| Author | : G.F. Froment |
| Publisher | : Elsevier |
| Total Pages | : 663 |
| Release | : 2001-04-03 |
| Genre | : Science |
| ISBN | : 0080540295 |
Reaction Kinetics and the Development and Operation of Catalytic Processes is a trendsetter. The Keynote Lectures have been authored by top scientists and cover a broad range of topics like fundamental aspects of surface chemistry, in particular dynamics and spillover, the modeling of reaction mechanisms, with special focus on the importance of transient experimentation and the application of kinetics in reactor design. Fundamental and applied kinetic studies are well represented. More than half of these deal with transient kinetics, a new trend made possible by recent sophisticated experimental equipment and the awareness that transient experimentation provides more information and insight into the microphenomena occurring on the catalyst surface than steady state techniques. The trend is not limited to purely kinetic studies since the great majority of the papers dealing with reactors also focus on transients and even deliberate transient operation. It is to be expected that this trend will continue and amplify as the community becomes more aware of the predictive potential of fundamental kinetics when combined with detailed realistic modeling of the reactor operation.
| Author | : M. Albert Vannice |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 257 |
| Release | : 2006-04-09 |
| Genre | : Science |
| ISBN | : 0387259724 |
Describes how to conduct kinetic experiments with heterogeneous catalysts, analyze and model the results, and characterize the catalysts Detailed analysis of mass transfer in liquid phase reactions involving porous catalysts. Important to the fine chemicals and pharmaceutical industries so it has appeal to many researchers in both industry and academia (chemical engineering and chemistry departments
| Author | : Dmitry Yu Murzin |
| Publisher | : Elsevier |
| Total Pages | : 754 |
| Release | : 2016-06-04 |
| Genre | : Technology & Engineering |
| ISBN | : 0444634630 |
Catalytic Kinetics: Chemistry and Engineering, Second Edition offers a unified view that homogeneous, heterogeneous, and enzymatic catalysis form the cornerstone of practical catalysis. The book has an integrated, cross-disciplinary approach to kinetics and transport phenomena in catalysis, but still recognizes the fundamental differences between different types of catalysis. In addition, the book focuses on a quantitative chemical understanding and links the mathematical approach to kinetics with chemistry. A diverse group of catalysts is covered, including catalysis by acids, organometallic complexes, solid inorganic materials, and enzymes, and this fully updated second edition contains a new chapter on the concepts of cascade catalysis. Finally, expanded content in this edition provides more in-depth discussion, including topics such as organocatalysis, enzymatic kinetics, nonlinear dynamics, solvent effects, nanokinetics, and kinetic isotope effects. - Fully revised and expanded, providing the latest developments in catalytic kinetics - Bridges the gaps that exist between hetero-, homo- and enzymatic-catalysis - Provides necessary tools and new concepts for researchers already working in the field of catalytic kinetics - Written by internationally-renowned experts in the field - Examples and exercises following each chapter make it suitable as an advanced course book
| Author | : G.F. Froment |
| Publisher | : Elsevier |
| Total Pages | : 611 |
| Release | : 1997-09-03 |
| Genre | : Technology & Engineering |
| ISBN | : 0080530621 |
Many processes of the chemical industry are based upon heterogeneous catalysis. Two important items of these processes are the development of the catalyst itself and the design and optimization of the reactor. Both aspects would benefit from rigorous and accurate kinetic modeling, based upon information on the working catalyst gained from classical steady state experimentation, but also from studies using surface science techniques, from quantum chemical calculations providing more insight into possible reaction pathways and from transient experimentation dealing with reactions and reactors. This information is seldom combined into a kinetic model and into a quantitative description of the process. Generally the catalytic aspects are dealt with by chemists and by physicists, while the chemical engineers are called upon for mechanical aspects of the reactor design and its control. The symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis" aims at illustrating a more global and concerted approach through a number of prestigious keynote lectures and severely screened oral and poster presentations.
| Author | : Michel Boudart |
| Publisher | : Elsevier |
| Total Pages | : 263 |
| Release | : 2014-05-16 |
| Genre | : Science |
| ISBN | : 1483183971 |
Kinetics of Chemical Processes details the concepts associated with the kinetic study of the chemical processes. The book is comprised of 10 chapters that present information relevant to applied research. The text first covers the elementary chemical kinetics of elementary steps, and then proceeds to discussing catalysis. The next chapter tackles simplified kinetics of sequences at the steady state. Chapter 5 deals with coupled sequences in reaction networks, while Chapter 6 talks about autocatalysis and inhibition. The seventh chapter describes the irreducible transport phenomena in chemical kinetics. The next two chapters discuss the correlations in homogenous kinetics and heterogeneous catalysis, respectively. The last chapter covers the analysis of reaction networks. The book will be of great use to students, researchers, and practitioners of scientific disciplines that deal with chemical reaction, particularly chemistry and chemical engineering.
| Author | : S. Suresh |
| Publisher | : CRC Press |
| Total Pages | : 544 |
| Release | : 2014-12-18 |
| Genre | : Science |
| ISBN | : 1466558857 |
This book explores a balance between energy and material, applied to chemical reactors with catalysis, to achieve a given purpose. It includes the fundamentals of chemical reaction engineering and explains reactor design fundamentals. The book spans the full range-from the fundamentals of kinetics and heterogeneous catalysis via modern experimental and theoretical results of model studies-to their equivalent large-scale industrial production processes. It also includes significant developments, with recent research case studies and literature.
| Author | : G.F. Froment |
| Publisher | : Elsevier |
| Total Pages | : 491 |
| Release | : 1999-03-18 |
| Genre | : Science |
| ISBN | : 0080540279 |
The symposium "Reaction Kinetics and the Development of Catalytic Processes" is the continuation of the very successful International Symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis", held in September 1997 in Antwerp, Belgium. These proceedings contain a unique series of top level plenary lectures mainly focused on• the dynamics of catalytic surfaces• the interaction of the reacting molecules with the solid catalyst• the elementary steps of reaction pathways and molecular kinetics.Surface science techniques, molecular modeling, transient kinetic studies, sophisticated and specific reactors are included to a growing extent in the kinetic modeling and the development of catalytic processes. How this is practiced today and how it will evolve in the coming years, and what benefit can be expected for a more fundamentally based approach is the aim of the symposium.
| Author | : Michel Boudart |
| Publisher | : Princeton University Press |
| Total Pages | : 241 |
| Release | : 2014-07-14 |
| Genre | : Science |
| ISBN | : 1400853338 |
This book is a critical account of the principles of the kinetics of heterogeneous catalytic reactions in the light of recent developments in surface science and catalysis science. Originally published in 1984. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.
| Author | : Jorge Ancheyta |
| Publisher | : John Wiley & Sons |
| Total Pages | : 309 |
| Release | : 2017-08-07 |
| Genre | : Science |
| ISBN | : 1119226643 |
A practical approach to chemical reaction kinetics—from basic concepts to laboratory methods—featuring numerous real-world examples and case studies This book focuses on fundamental aspects of reaction kinetics with an emphasis on mathematical methods for analyzing experimental data and interpreting results. It describes basic concepts of reaction kinetics, parameters for measuring the progress of chemical reactions, variables that affect reaction rates, and ideal reactor performance. Mathematical methods for determining reaction kinetic parameters are described in detail with the help of real-world examples and fully-worked step-by-step solutions. Both analytical and numerical solutions are exemplified. The book begins with an introduction to the basic concepts of stoichiometry, thermodynamics, and chemical kinetics. This is followed by chapters featuring in-depth discussions of reaction kinetics; methods for studying irreversible reactions with one, two and three components; reversible reactions; and complex reactions. In the concluding chapters the author addresses reaction mechanisms, enzymatic reactions, data reconciliation, parameters, and examples of industrial reaction kinetics. Throughout the book industrial case studies are presented with step-by-step solutions, and further problems are provided at the end of each chapter. Takes a practical approach to chemical reaction kinetics basic concepts and methods Features numerous illustrative case studies based on the author’s extensive experience in the industry Provides essential information for chemical and process engineers, catalysis researchers, and professionals involved in developing kinetic models Functions as a student textbook on the basic principles of chemical kinetics for homogeneous catalysis Describes mathematical methods to determine reaction kinetic parameters with the help of industrial case studies, examples, and step-by-step solutions Chemical Reaction Kinetics is a valuable working resource for academic researchers, scientists, engineers, and catalyst manufacturers interested in kinetic modeling, parameter estimation, catalyst evaluation, process development, reactor modeling, and process simulation. It is also an ideal textbook for undergraduate and graduate-level courses in chemical kinetics, homogeneous catalysis, chemical reaction engineering, and petrochemical engineering, biotechnology.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 97 |
| Release | : 1992-02-01 |
| Genre | : Science |
| ISBN | : 0309045843 |
The impact of catalysis on the nation's economy is evidenced by the fact that catalytic technologies generate U.S. sales in excess of $400 billion per year and a net positive balance of trade of $16 billion annually. This book outlines recent accomplishments in the science and technology of catalysis and summarizes important likely challenges and opportunities on the near horizon. It also presents recommendations for investment of financial and human resources by industry, academe, national laboratories, and relevant federal agencies if the nation is to maintain continuing leadership in this fieldâ€"one that is critical to the chemical and petroleum processing industries, essential for energy-efficient means for environmental protection, and vital for the production of a broad range of pharmaceuticals.
