Pressure-Induced Phase Transformations

Pressure-Induced Phase Transformations
Author: Daniel Errandonea
Publisher:
Total Pages: 224
Release: 2020-09-04
Genre:
ISBN: 9783039368167

This book is a printed edition of the Special Issue of Crystals entitled Pressure-Induced Phase Transformations. It includes selected articles on the behavior of matter under high-pressure and high-temperature conditions, describing and discussing contemporary achievements, which were selected based on their relevance and scientific quality.

Pressure-Induced Phase Transformations (Volume II)

Pressure-Induced Phase Transformations (Volume II)
Author: Daniel Errandonea
Publisher: Mdpi AG
Total Pages: 0
Release: 2023-08-25
Genre: Science
ISBN: 9783036585642

The study of phase transitions in materials under high pressure and high temperature is a very active research field. In the last few decades, many important discoveries have been made thanks to the development of experimental techniques and computer simulation methods. Many of these achievements affect various research fields ranging from solid-state physics, chemistry, and materials science to geophysics. They not only involve deepening knowledge on solid-solid phase transitions, but also a better understanding of melting under compression. These modern discoveries, as well as the impact of pressure on structural, chemical, and physical properties, are central to the current Special Issue. Amongst other topics, it places particular emphasis on phase transitions and their effects on different physical properties.

Phase Transitions in Solids Under High Pressure

Phase Transitions in Solids Under High Pressure
Author: Vladimir Davydovich Blank
Publisher: CRC Press
Total Pages: 455
Release: 2013-10-25
Genre: Science
ISBN: 1466594241

The use of high-pressure techniques has become popular for studying the nature of substances and phenomena occurring in them, especially as a means of obtaining new materials (synthesis under high pressure) and processing known materials (hydroextrusion). A product of many years of research by the authors and their colleagues, Phase Transitions in Solids under High Pressure discusses the relationships of phase transformations in solids under high pressure, the mechanism of these transformations, crystal geometry, the effect of deformation, the conditions of formation, and preservation of the high-pressure phases under normal pressure. The book begins with an introduction that describes the relationship of the thermodynamics of phase transformations and the kinetics of the transformations. This is followed by a chapter explaining the equipment and mostly original procedures for investigating phase transformation in solids under high hydrostatic and quasi-hydrostatic pressures. The book covers phase transformations under high pressure in a wide temperature range in the elements carbon, silicon, germanium, titanium, zirconium, iron, gallium, and cerium as well as in titanium- and iron-based alloys and AIBVII, AIIBVI, and AIIIBV compounds. In addition, the book examines the kinetics of phase transformations in iron-based alloys in isobaric–isothermal conditions. The authors present results for phase transformations in deformation under high pressure, describe several non-trivial effects associated with phase transformations under high pressure, and analyze the kinetics and hysteresis of high-temperature and low-temperature phase transformations. They conclude by describing the role of investigations under high pressure for determining general relationships governing phase transformations in solids.

Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds

Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds
Author: Francisco Javier Manjon
Publisher: Springer Science & Business Media
Total Pages: 248
Release: 2014-01-21
Genre: Technology & Engineering
ISBN: 3642403670

This book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragonal structures, and other structures like layered and wurtzite-type modifications. A systematic analysis of the behavior of cubic (spinel), tetragonal (defect chalcopyrites and stannites) and other crystal modifications of AB2X4 compounds under hydrostatic pressure is performed. The behavior of AIIAl2S4, AIIGa2S4, AIIAl2Se4 and AIIGa2Se4 compounds with defective tetragonal structures, compounds with layered and wurtzite structures under hydrostatic pressure and the pressure dependence of the band gap, lattice parameters, interatomic distances, vibrational modes and pressure-induced phase transitions is discussed. Many of these compounds, except oxide spinels, undergo a pressure-induced phase transition towards the rocksalt-type structure. The phase transition is preceded by disorder in the cation sublattice. The dependence of the transition pressure to the rocksalt-type structure as a function of the compound ionicity and the size criterion is analyzed. At high pressures, all ordered-vacancy compounds are found to exhibit a band anticrossing between several conduction bands that leads to a strong decrease of its pressure coefficient and consequently to a strong non-linear pressure dependence of the direct bandgap energy. Theoretical studies of phase transitions in several ordered-vacancy compounds reveal that the existence of ordered vacancies alter the cation-anion bond distances and their compressibilities. The book is written for students, Ph D. students and specialists in materials science, phase transitions and new materials.

Phase Transitions in Cell Biology

Phase Transitions in Cell Biology
Author: Gerald H. Pollack
Publisher: Springer Science & Business Media
Total Pages: 187
Release: 2008-08-15
Genre: Medical
ISBN: 1402086512

Phase transitions occur throughout nature. The most familiar example is the one that occurs in water – the abrupt, discontinuous transition from a liquid to a gas or a solid, induced by a subtle environmental change. Practically magical, the ever-so-slight shift of temperature or pressure can induce an astonishing transition from one entity to another entity that bears little resemblance to the first. So "convenient" a feature is seen throughout the domains of physics and chemistry, and one is therefore led to wonder whether it might also be common to biology. Indeed, many of the most fundamental cellular processes are arguably attributable to radical structural shifts triggered by subtle changes that cross a critical threshold. These processes include transport, motion, signaling, division, and other fundamental aspects of cellular function. Largely on the basis of this radical concept, a symposium was organized in Poitiers, France, to bring together people who have additional evidence for the role of phase transitions in biology, and this book is a compendium of some of the more far-reaching of those presentations, as well as several others that seemed to the editors to be compelling. The book should be suitable for anyone interested in the nature of biological function, particularly those who tire of lumbering along well trodden pathways of pursuit, and are eager to hear something fresh. The book is replete with fresh interpretations of familiar phenomena, and should serve as an excellent gateway to deeper understanding.

Phase Transformations of Elements Under High Pressure

Phase Transformations of Elements Under High Pressure
Author: E. Yu Tonkov
Publisher: CRC Press
Total Pages: 390
Release: 2018-10-08
Genre: Science
ISBN: 1420037609

As laboratories replace heavy hydraulic presses and bulky high-pressure chambers with miniature diamond anvils, traditional heaters with laser heating, and continue to improve methods of shock compression, there has been considerable new data obtained from the high-pressure, high-temperature modification of pure elements. The dense metallic modification of elements shows the potential for achieving superconductivity akin to theoretical predictions. Phase Transformations of Elements Under High Pressure contains the latest theoretical and experimental information on nearly 100 elements, including first-and second-phase transitions, melting lines, crystal structures of stable and metastable phases, stability of polymorphic modifications, and other useful properties and data. It emphasizes features such as changes in the liquid state, amorphization, and metallization, and provides temperature-pressure diagrams for every element. The book also describes the transitions of polymeric forms of fullerene, crystal modifications of elements stable under high pressures, and provides data that confirms their superconducting and magnetic properties. This handbook will be a lasting reference for scientists in a broad range of disciplines, including solid-state physics, chemistry, crystallography, mineralogy, and materials science.

Hybrid Organic-Inorganic Perovskites

Hybrid Organic-Inorganic Perovskites
Author: Li Wei
Publisher: John Wiley & Sons
Total Pages: 290
Release: 2020-10-19
Genre: Science
ISBN: 3527344314

Hybrid organic-inorganic perovskites (HOIPs) have attracted substantial interest due to their chemical variability, structural diversity and favorable physical properties the past decade. This materials class encompasses other important families such as formates, azides, dicyanamides, cyanides and dicyanometallates. The book summarizes the chemical variability and structural diversity of all known hybrid organic-inorganic perovskites subclasses including halides, azides, formates, dicyanamides, cyanides and dicyanometallates. It also presents a comprehensive account of their intriguing physical properties, including photovoltaic, optoelectronic, dielectric, magnetic, ferroelectric, ferroelastic and multiferroic properties. Moreover, the current challenges and future opportunities in this exciting field are also been discussed. This timely book shows the readers a complete landscape of hybrid organic-inorganic pervoskites and associated multifuctionalities.

Phase Transitions in Materials

Phase Transitions in Materials
Author: Brent Fultz
Publisher: Cambridge University Press
Total Pages: 589
Release: 2014-08-14
Genre: Science
ISBN: 1107067243

A clear, concise and rigorous textbook covering phase transitions in the context of advances in electronic structure and statistical mechanics.