Preparation Characterisation And Reactivity Of Low Oxidation State D Block Metal Complexes Stabilised By Extremely Bulky Amide Ligands
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| Author | : Jamie Hicks |
| Publisher | : Springer |
| Total Pages | : 214 |
| Release | : 2016-10-24 |
| Genre | : Science |
| ISBN | : 9811029059 |
This thesis describes the synthesis and characterization of numerous metal-metal bonded complexes that are stabilized by extremely bulky amide ligands. It provides a comprehensive overview of the field, including discussions on groundbreaking complexes and reactions, before presenting in detail, exciting new findings from the PhD studies. The thesis appeals to researchers, professors and chemistry undergraduates with an interest in inorganic and/or organometallic chemistry.
| Author | : |
| Publisher | : |
| Total Pages | : 1006 |
| Release | : 2008 |
| Genre | : Dissertations, Academic |
| ISBN | : |
| Author | : |
| Publisher | : |
| Total Pages | : 774 |
| Release | : 2003 |
| Genre | : Dissertations, Academic |
| ISBN | : |
Theses on any subject submitted by the academic libraries in the UK and Ireland.
| Author | : Terrance John Hadlington |
| Publisher | : Springer |
| Total Pages | : 256 |
| Release | : 2017-02-14 |
| Genre | : Science |
| ISBN | : 3319518070 |
This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal–metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
| Author | : Michael Lappert |
| Publisher | : John Wiley & Sons |
| Total Pages | : 370 |
| Release | : 2008-12-23 |
| Genre | : Science |
| ISBN | : 9780470740378 |
Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power’s 1980 book “Metal and Metalloid Amides.” An introduction to the topic is followed by in-depth discussions of the amide compounds of: alkali metals alkaline earth metals zinc, cadmium and mercury the transition metals group 3 and lanthanide metals group 13 metals silicon and the group 14 metals group 15 metals the actinide metals Accompanied by a substantial bibliography, this is an essential guide for researchers and advanced students in academia and research working in synthetic organometallic, organic and inorganic chemistry, materials chemistry and catalysis.
| Author | : Frank Albert Cotton |
| Publisher | : |
| Total Pages | : 832 |
| Release | : 1993 |
| Genre | : Science |
| ISBN | : |
Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included
| Author | : Kenneth D. Karlin |
| Publisher | : John Wiley & Sons |
| Total Pages | : 641 |
| Release | : 2004-03-24 |
| Genre | : Science |
| ISBN | : 047146077X |
This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 50 continues to report recent advances with a significant, up-to-date selection of contributions on topics such as the following: Structural and mechanistic investigations in asymmetric copper; Catalyzed reactions; Phenoxyl radical complexes; Synthesis of large pore zeolites and molecular sieves; Inorganic nanoclusters with fullerene-like structure and nanotubes
| Author | : Silvia Diez-Gonzalez |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 637 |
| Release | : 2016-11-04 |
| Genre | : Science |
| ISBN | : 1782626816 |
In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.
| Author | : Philip P. Power |
| Publisher | : John Wiley & Sons |
| Total Pages | : 288 |
| Release | : 2018-07-04 |
| Genre | : Science |
| ISBN | : 1119477840 |
The newest volume in the authoritative Inorganic Syntheses book series provides users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely inorganic and organometallic compounds that can be used in reactions to develop new materials, drug targets, and bio-inspired chemical entities.
| Author | : Sjoerd Harder |
| Publisher | : Springer |
| Total Pages | : 282 |
| Release | : 2013-07-20 |
| Genre | : Science |
| ISBN | : 3642362702 |
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
