Polymer Melt Rheology And Flow Birefringence Volume 6 Of Polymers Properties And Applications
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Author | : Hermann Janeschitz-Kriegl |
Publisher | : Springer Science & Business Media |
Total Pages | : 538 |
Release | : 2012-12-06 |
Genre | : Technology & Engineering |
ISBN | : 3642688225 |
The present monograph is intended as an introduction into a field which certainly did not receive proper attention in the past. It is one of the aims of this book to verify this suppo sition. The author hopes to show that the technique of the measurement of flow birefringence can fulfil an important com plementary task in polymer melt rheology. From this point it is expected that the present monograph will attract the atten tion of polymer scientists in general, and of rheologists and process engineers in particular. Certainly, the fourth chapter will appeal to the latter group. As a teacher in polymer science and technology the author wants to address also the group of the graduate students. In fact, the standard knowledge acquired during usual university studies in chemistry, physics or engineering does not enable a quick start of research activities in the field of polymer melt rheology. Certainly, in this typically interdisciplinary field everyone can lay emphasis on matters which are familar to hirn because of his preceding education. Significant research activities, however, can only be generated on the basis of a more universal knowledge. In the absence of this knowledge beginners have to rely upon the guidance of their supervisors for an unduly long period. Otherwise they take the risk of losing too much of their costly time. This holds in particular for the experimentalists who cannot be dispensed from being familiar with the necessary theoretical background.
Author | : Takeo Araki |
Publisher | : CRC Press |
Total Pages | : 480 |
Release | : 1998-03-03 |
Genre | : Science |
ISBN | : 9780824701420 |
Offers an overview of recent advances in multiphase polymeric materials, ranging from theoretical aspects of polymer miscibility and phase separation kinetics to bulk, surface and interface properties in polymeric materials. This work considers the possibility of a nondestructive methodology to investigative multiphase polymers based mainly on a scattering technique that is sensitive to changes in the phase behaviour of multicomponent polymer systems.
Author | : W. L. Hawkins |
Publisher | : Springer Science & Business Media |
Total Pages | : 129 |
Release | : 2012-12-06 |
Genre | : Technology & Engineering |
ISBN | : 3642693768 |
The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended sufficiently to meet design requirements for long-term applications. Polymers degrade by a wide variety of mechanisms, several of which affect all polymers through to varying degree. This monograph will concentrate on those degradation mechanisms which result from reactions of polymers with oxygen in its various forms and which are accelerated by heat and/or radiation. Those stabilization mechanisms are discussed which are based on an understanding of degradation reaction mechanisms that are reasonably well established. The stabilization of polymers is still undergoing a transition from an art to a science as mechanisms of degradation become more fully developed. A scientific approach to stabilization can only be approached when there is an understanding of the reactions that lead to degradation. Stabilization against biodegradation and burning will not be discussed since there is not a clear understanding of how polymers degrade under these conditions.
Author | : |
Publisher | : |
Total Pages | : 1332 |
Release | : 1998 |
Genre | : English imprints |
ISBN | : |
Author | : K.L. Mittal |
Publisher | : Springer Science & Business Media |
Total Pages | : 450 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 1461308437 |
This volume documents the proceedings of the Symposium on Polymers in Information Storage Technology held as a part of the American Chemical Society meeting in Los Angeles, September 25-30, 1988. It should be recorded here that this symposium was cosponsored by the Division of Polymeric Materials: Science and Engineering, and the Division of Polymer Chemistry. Polymers are used for a variety of purposes in both optical and magnetic information storage technologies. For example, polymers find applications as substrate, for storing information directly, as protective coating, as lubricant, and as binder in magnetic media. In the last few years there has been a high tempo of research activity dealing with the many ramifications of polymers in the exciting arena of information storage. Concomitantly, we decided to organize this symposium and I believe this was the premier event on this topic. This symposium was conceived and organized with the following objectives in mind: (1) to bring together those actively involved (polymer chemists, polymer physicists, photochemists, surface and colloid chemists, tribo10gists and so on) in the various facets of this topic; (2) to provide a forum for discussion of latest R&D activity in this technology; (3) to provide an opportunity for cross-pollination of ideas; and (4) to identify and highlight areas, within the broad purview of this topic, which needed intensified or accelerated R&D efforts.
Author | : Wiley |
Publisher | : John Wiley & Sons |
Total Pages | : 1605 |
Release | : 2012-12-03 |
Genre | : Technology & Engineering |
ISBN | : 1118582837 |
The book provides comprehensive, up-to-date information on the physical properties of polymers including, viscoelasticity, flammability, miscibility, optical properties, surface properties and more. Containing carefully selected reprints from the Wiley's renowned Encyclopedia of Polymer Science and Technology, this reference features the same breadth and quality of coverage and clarity of presentation found in the original.
Author | : Hugo Sol |
Publisher | : Springer Science & Business Media |
Total Pages | : 244 |
Release | : 2012-12-06 |
Genre | : Technology & Engineering |
ISBN | : 9400914717 |
Euromech 357 took place in the nice authentic monastery 'Rolduc' in Kerkrade, Holland. The objective was to bring together researchers to present their latest advancements in the relatively new domain of Material properties identification by Mixed Numerical Experimental Methods (MMM). MMM are a modem and increasingly powerful way to determine the values of unknown parameters in a numerical model by observations made on real physical test structures. Starting from the measurement of output values (like displacements, stresses, velocities, vibrations, .. ) of the real physical test structure, MMM try to update parameters in the numerical model in such a way that the computed observations match the experimental observations. It was shown clearly at the colloquium that the combined use of numerical analysing tools and sophisticated measurement techniques has created an extra degree of freedom for the design of experiments and has led to new approaches for material characterisation. The colloquium was attended by 39 participants coming from 12 different European countries. We had 23 oral presentations on the different topics of the above mentioned sessions. Each presentation was followed by an intensive discussion. Du~ to the informal atmosphere and the limited number of participants, the discussions were very lively and fruitful. The opportunity to continue to discuss common problems after dinner in a reserved place was also offered to the Euromech participants. This opportunity and the fact that the monastery was isolated (nobody could escape!) created an excellent platform for discussions and personal contacts.
Author | : Lawrence E. Nielsen |
Publisher | : |
Total Pages | : 222 |
Release | : 1977 |
Genre | : Technology & Engineering |
ISBN | : |
Author | : Frederick R. Eirich |
Publisher | : Academic Press |
Total Pages | : 662 |
Release | : 2014-05-12 |
Genre | : Technology & Engineering |
ISBN | : 1483272982 |
Rheology: Theory and Applications, Volume 5 focuses on overtly fluid behavior of polymers, including the theory of large deformations, thermoelastic effects, elastic phenomena observed during the extrusion of polymeric melts, and theories of the structure of liquids and glasses. The selection first elaborates on the application of large deformation theory to the thermomechanical behavior of rubberlike polymers and unstable flow of molten polymers. Discussions focus on the mechanism proposed for unstable flow, ripple and associated effects, direct observation of waviness phenomena, empirical behavior of porous, unfilled, and filled rubberlike polymers, and problems connected with the interpretation of mechanical response parameters. The text then examines elasticity effects in polymer extrusion and strength and extensibility of elastomers. The publication takes a look at free volume and polymer rheology and studies of the deformation of crystalline polymers. Topics include the contribution of the two orientation processes to the birefringence, deformation of superstructure, rate of orientation of crystalline regions, free volume and physical state, glass transition and free volume, and reappraisal of time-temperature superposition. The manuscript also elaborates on the deformation and dissipative processes in high polymeric solids and the thermodynamics of deformation. The selection is a vital source of data for researchers interested in the theories and applications of rheology.
Author | : Alan I. Nakatani |
Publisher | : |
Total Pages | : 386 |
Release | : 1995 |
Genre | : Science |
ISBN | : |
Examines recent advances in understanding the structures of polymer melts, polymer solutions, block copolymers, liquid crystalline polymers, colloid suspensions, and multiphase systems subjected to flow. Reports on advances in instrumental techniques, characterization, theories, and applications. An overview chapter provides a guide and reference source to related reviews and identifies similarities in flow behavior between various materials science disciplines.