Oxidation Of Organic Compounds By Dioxiranes
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Author | : Waldemar Adam |
Publisher | : John Wiley & Sons |
Total Pages | : 684 |
Release | : 2009-04-27 |
Genre | : Science |
ISBN | : 0470454075 |
A Comprehensive Monograph on Dioxirane Oxidations The oxidation of organic compounds is one of the most important methods for the introduction and manipulation of functional groups. Among the most modern of these transformations is the use of the fascinating family of oxidants known as dioxiranes. A dioxirane can, by transferring one of its oxygen atoms to organic substrates, effect a remarkable array of oxidative processes such as epoxidation, C-H insertion, and heteroatom (N, S, P, I) oxidation. In addition to their versatility, dioxiranes can be generated catalytically under mild conditions and produce no toxic waste stream as part of the oxidation process. Moreover, some of the most exciting recent developments involve the enantioselective introduction of oxygen atoms via chiral dioxiranes. This book represents the first single volume dedicated to the comprehensive coverage of the myriad of oxidations of organic compounds performed by dioxiranes. The contents of this book are extracted from comprehensive reviews of the topics contained in the Organic Reactions series and cover the oxidation of alkenes and the oxidation of all other organic substrates. In addition, updated lists of references for each of the chapters are provided, bringing the literature coverage up to June 2008. The authors of these chapters are among the pioneers of dioxirane chemistry and draw on extensive firsthand knowledge of the subject. As with all Organic Reactions content, the presentation emphasizes the preparative aspects of the reactions and pays particular attention throughout to substrate scope, limitations, structural and electronic influences, and stereochemical aspects. For the student or experienced practitioner, both general guidelines for carrying out the reactions as well as detailed experimental procedures are provided. Most importantly, all known examples of dioxirane oxidations have been compiled in easy-to-scan tables covering over 500 pages. Oxidation of Organic Compounds by Dioxiranes is an indispensable working resource for organic and medicinal chemists as well as anyone wishing to own the definitive treatise on this fascinating and useful class of oxidants.
Author | : Larry E. Overman |
Publisher | : John Wiley & Sons |
Total Pages | : 713 |
Release | : 2007-11-27 |
Genre | : Science |
ISBN | : 0470223979 |
Dental Implants for Hygienists and Therapists An essential handbook for dental hygienists and therapists seeking a comprehensive resource covering dental implants Dental Implants for Hygienists and Therapists delivers an accessible and informative exploration of the fundamental principles of tooth replacement with dental implants, as well as the science and theory that underlies modern implants, and the factors impacting their success and survival. The book offers robust guidance on the assessment of peri-implant tissues in health and in disease, an evidence-based approach to their management, and instruction on when a referral should be made. It also covers function and anatomy in health and disease around dental implants and the supporting tissues as well as the factors that influence predictability and patient management. This book includes: Thorough introductions to the history of dental implants and osseointegration, including the difference between success and survival Comprehensive exploration of one-piece and two-piece implant systems, patient selection and indications for implant treatment Practical discussions of surgical (including augmentation) and prosthodontic protocols and peri-implant tissues In-depth examinations of maintenance care, including the management of peri-implant disease with non-surgical and surgical treatment, and the role of the hygienist Dental Implants for Hygienists and Therapists is invaluable to dental hygienists and therapists seeking a one-stop resource on dental implantology
Author | : Vilen Antonovsky |
Publisher | : CRC Press |
Total Pages | : 572 |
Release | : 2005-10 |
Genre | : Science |
ISBN | : |
The monograph originally reviews and systematizes the majority of questions in physical chemistry of organic peroxides. It presents a broad set of data on various parameters of peroxides, their interdependencies and decomposition properties are generally discussed. The experimental data on various structures of peroxides and their features, and the practical application are considered.
Author | : Vishnu Ji Ram |
Publisher | : Elsevier |
Total Pages | : 504 |
Release | : 2019-06-05 |
Genre | : Science |
ISBN | : 0081011911 |
Heterocycles are ubiquitously present in nature and occupy a unique place in organic chemistry as they are part of the DNA and haemoglobin that make life possible. The Chemistry of Heterocycles covers an introduction to the topic, followed by a chapter on the nomenclature of all classes of isolated, fused and polycyclic heterocycles. The third chapter delineates the highly strained three membered N,O and S containing aromatic and non-aromatic heterocycles with one and more than one similar and dissimilar heteroatom. The four-membered heterocycles are abundantly present in various natural and synthetic products of pharmacological importance. This chapter describes the natural abundance, synthesis, chemical reactivity, structural features and their medicinal importance. This class of compounds are present as sub-structures in penicillin and cytotoxic Taxol. Lastly, a chapter on the natural abundance, synthesis, chemical reactivity and pharmacological importance of 5-membered heterocycles with N,O,S heteroatom is covered. The chemistry of heterocycles with mixed heteroatom such as, N-S, N-O, N-S etc. is also described. - Gives in-depth, clear information about various systems of nomenclature along with widely acceptable IUPAC system for naming various classes of heterocycles - Provides complete information about natural occurrences, synthesis, chemical reactivity, pharmacological importance of heterocycles and their application in material science - Highly relevant for graduate students and researchers, providing updated information about various isolated and fused N,O and,S containing heterocycles
Author | : J.H. Clark |
Publisher | : Springer Science & Business Media |
Total Pages | : 573 |
Release | : 2012-12-06 |
Genre | : Technology & Engineering |
ISBN | : 9401106231 |
Political pressure has translated into legislation requiring industry to reduce waste. There is an unprecedented opportunity for chemists to develop and apply new methods that result in waste reduction, and this book describes examples of new chemical methods used to reduce waste at source and to treat toxic waste.
Author | : Navjeet Kaur |
Publisher | : Elsevier |
Total Pages | : 328 |
Release | : 2024-01-06 |
Genre | : Science |
ISBN | : 0443135843 |
3-membered heterocyclic rings offer an unusual combination of synthetic flexibility, reactivity, and atom economy. The main challenge for synthetic chemists, both in academia and industry, is the search for efficient approaches to target molecules. This book presents several methodologies for the synthesis of three-membered heterocyclic compounds and the readers will defiantly gain knowledge about the topic. With Three-Membered Heterocycle Synthesis, readers have detailed information about the synthesis of three-membered heterocyclic compounds. It comprehensively describes three-membered heterocyclic compounds synthesis, allowing the audience to quickly assess possible synthetic approaches. - Covers the applications of three-membered heterocycles - Includes comprehensive descriptions of heterocycle synthesis - Highlights methodologies for the synthesis of three-membered heterocycles - Analyzes several types and families of compounds, with a large set of recent examples in the field
Author | : Wolfgang A. Herrmann |
Publisher | : Springer |
Total Pages | : 152 |
Release | : 1993-03-05 |
Genre | : Science |
ISBN | : |
1. H. Heaney: Novel Organic Peroxygen Reagents for Use in Organic Synthesis 2. R. Sheldon: Homogeneous and Heterogeneous Catalytic Oxidations with Peroxide Reagents 3. W. Adam, L. Hadjiarapoglou: Oxidation Chemistry Made Easy 4. E. H]ft: Enantioselective Epoxidation with Peroxidic Oxygen 5. S. Warwel, M. Sojka, M. R}sch gen. Klaas: Synthesis of Dicarboxylic Acids by Transition-Metal Catalyzed Oxidative Cleavage of Terminal-Unsaturated Fatty Acids 6. J. Fossey, J. Sorba, D.Lefort: Peracide and Free Radicals: A Theoretical and Experimental Approach 7. K. Dear: Cleaning-up Oxidations with Hydrogen Peroxide
Author | : Michael B. Smith |
Publisher | : John Wiley & Sons |
Total Pages | : 2146 |
Release | : 2020-02-19 |
Genre | : Science |
ISBN | : 1119371805 |
The completely revised and updated, definitive resource for students and professionals in organic chemistry The revised and updated 8th edition of March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure explains the theories of organic chemistry with examples and reactions. This book is the most comprehensive resource about organic chemistry available. Readers are guided on the planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions The opening chapters of March's Advanced Organic Chemistry, 8th Edition deal with the structure of organic compounds and discuss important organic chemistry bonds, fundamental principles of conformation, and stereochemistry of organic molecules, and reactive intermediates in organic chemistry. Further coverage concerns general principles of mechanism in organic chemistry, including acids and bases, photochemistry, sonochemistry and microwave irradiation. The relationship between structure and reactivity is also covered. The final chapters cover the nature and scope of organic reactions and their mechanisms. This edition: Provides revised examples and citations that reflect advances in areas of organic chemistry published between 2011 and 2017 Includes appendices on the literature of organic chemistry and the classification of reactions according to the compounds prepared Instructs the reader on preparing and conducting multi-step synthetic reactions, and provides complete descriptions of each reaction The 8th edition of March's Advanced Organic Chemistry proves once again that it is a must-have desktop reference and textbook for every student and professional working in organic chemistry or related fields. Winner of the Textbook & Acadmic Authors Association 2021 McGuffey Longevity Award.
Author | : |
Publisher | : John Wiley & Sons |
Total Pages | : 1518 |
Release | : 2007-02-06 |
Genre | : Science |
ISBN | : 0470862750 |
The Chemistry of Peroxides is a new volume in the Chemistry of Functional Groups series. This series covers all aspects of organic chemistry with each volume containing chapters on: General and theoretical aspects Computational approaches Thermodynamics and kinetics NMR and ESR Mass Spectrometry Spectroscopies Analytical aspects Reaction mechanisms Syntheses Biological effects Environmental effects Industrial applications Edited by Zvi Rappoport, this series provides outstanding reviews on all aspects of functional groups in analytical, physical, synthetic and applied chemistry.
Author | : |
Publisher | : |
Total Pages | : 386 |
Release | : 2003 |
Genre | : Chemistry |
ISBN | : |