Organoboranes For Syntheses
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| Author | : Donald S. Matteson |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 417 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 3642797091 |
This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.
| Author | : Thomas Onak |
| Publisher | : Elsevier |
| Total Pages | : 373 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0323153615 |
Organoborane Chemistry deals with the chemistry of organoboranes, with emphasis on compounds containing a carbon-boron bond. The structure and physical properties of organoboranes are discussed, along with the reactions of three-coordinate and four-coordinate organoboranes, organodiboranes, and other organopolyboranes such as organotetraboranes and organopentaborane compounds. Comprised of seven chapters, this book begins with an overview of multistep synthetic or degradative reactions involving organoboron compounds, along with the nomenclature for such compounds. The next chapter examines the structure and physical properties of organoboranes, with emphasis on boron-carbon bond lengths, electronic transitions, and molecular orbital calculations. Subsequent chapters focus on three-coordinate and four-coordinate organoboranes, together with their synthesis, reactions, and properties; hydroboration and dehydroboration of organodiboranes; and the synthesis, reactions, and physical properties of other organopolyboranes such as organotetraboranes, organopentaborane compounds, and organodecaborane compounds. The final chapter is devoted to cyclic boron-carbon systems and the applications of organoboron compounds. This monograph should be of interest to organic chemists.
| Author | : P. Veeraraghavan Ramachandran |
| Publisher | : |
| Total Pages | : 272 |
| Release | : 2001 |
| Genre | : Medical |
| ISBN | : |
This book examines the recent advances in the art of organic synthesis via organoboranes. The volume includes a wide range of topics in asymmetric synthesis, such as reduction, aldol reaction, allyboration, homologation, and cyclopropanation. Additional subjects include Suzuki coupling, amino acid synthesis, fluoro-organic synthesis, boron catalysts for stereoselective transformations, heterocyclic synthesis and novel borohydride reagents.
| Author | : Elena Fernández |
| Publisher | : Springer |
| Total Pages | : 334 |
| Release | : 2015-03-04 |
| Genre | : Science |
| ISBN | : 3319130544 |
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
| Author | : Herbert Charles Brown |
| Publisher | : Wiley-Interscience |
| Total Pages | : 312 |
| Release | : 1975 |
| Genre | : Science |
| ISBN | : |
| Author | : Ranjit S. Dhillon |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 582 |
| Release | : 2007-05-01 |
| Genre | : Science |
| ISBN | : 3540490760 |
This book offers a systematic compilation of the vast data available to synthetic chemists. It provides easy access to the necessary information required for chemical transformations.
| Author | : Herbert C. Brown |
| Publisher | : Cornell University Press |
| Total Pages | : 488 |
| Release | : 2019-06-30 |
| Genre | : Science |
| ISBN | : 1501741438 |
The leading researcher in the uses of boranes in organic synthesis here reviews his work over the past thirty-five years, covering such areas as steric strains, the nonclassical ion problem, selective reductions, hydroboration, and the organoboranes as synthetic intermediates. But more than an exposition of enormous accomplishment, the book is a scientific autobiography that will provide chemists with historical perspective on their profession. The author's detailed narrative of his own research experiences not only adds to the understanding of the present state of the study of boranes, but will serve as a stimulus to imaginative research in the future.
| Author | : Thomas Baumgartner |
| Publisher | : John Wiley & Sons |
| Total Pages | : 557 |
| Release | : 2018-03-12 |
| Genre | : Science |
| ISBN | : 1119235979 |
Showcases the highly beneficial features arising from the presence of main group elements in organic materials, for the development of more sophisticated, yet simple advanced functional materials Functional organic materials are already a huge area of academic and industrial interest for a host of electronic applications such as Organic Light-Emitting Diodes (OLEDs), Organic Photovoltaics (OPVs), Organic Field-Effect Transistors (OFETs), and more recently Organic Batteries. They are also relevant to a plethora of functional sensory applications. This book provides an in-depth overview of the expanding field of functional hybrid materials, highlighting the incredibly positive aspects of main group centers and strategies that are furthering the creation of better functional materials. Main Group Strategies towards Functional Hybrid Materials features contributions from top specialists in the field, discussing the molecular, supramolecular and polymeric materials and applications of boron, silicon, phosphorus, sulfur, and their higher homologues. Hypervalent materials based on the heavier main group elements are also covered. The structure of the book allows the reader to compare differences and similarities between related strategies for several groups of elements, and to draw crosslinks between different sections. The incorporation of main group elements into functional organic materials has emerged as an efficient strategy for tuning materials properties for a wide range of practical applications Covers molecular, supramolecular and polymeric materials featuring boron, silicon, phosphorus, sulfur, and their higher homologues Edited by internationally leading researchers in the field, with contributions from top specialists Main Group Strategies towards Functional Hybrid Materials is an essential reference for organo-main group chemists pursuing new advanced functional materials, and for researchers and graduate students working in the fields of organic materials, hybrid materials, main group chemistry, and polymer chemistry.
| Author | : H. Nöth |
| Publisher | : Elsevier |
| Total Pages | : 128 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483157903 |
Boron Chemistry contains the selected lectures presented at the Third International Meeting on Boron Chemistry held at Munich & Ettal, FRG on July 5-9, 1976. Separating nine papers as chapters, this book discusses effects of orbital vacancies in boron compounds, the aminoboronation reaction, and the cyclic coordination of boron compounds. This text also explores the organoboranes in synthesis and analysis; the synthesis, structure, and chemical reactions of metalloboranes; and studies of the smaller boron hydrides and their derivatives.
| Author | : Matthew G Davidson |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 555 |
| Release | : 2007-10-31 |
| Genre | : Science |
| ISBN | : 1847550649 |
The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.
