Orbital Angular Momentum Of Of Electron States With Reduced Rotational Symmetry
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Solid State Physics
| Author | : Henry Ehrenreich |
| Publisher | : Academic Press |
| Total Pages | : 193 |
| Release | : 2004-07-17 |
| Genre | : Science |
| ISBN | : 0080865224 |
Solid state physics is the branch of physics that is primarily devoted to the study of matter in its solid phase, especially at the atomic level. This prestigious serial presents timely and state-of-the-art reviews pertaining to all aspects of solid state physics.
Angular Momentum
| Author | : William J. Thompson |
| Publisher | : John Wiley & Sons |
| Total Pages | : 475 |
| Release | : 2008-09-26 |
| Genre | : Science |
| ISBN | : 3527617833 |
Develops angular momentum theory in a pedagogically consistent way, starting from the geometrical concept of rotational invariance. Uses modern notation and terminology in an algebraic approach to derivations. Each chapter includes examples of applications of angular momentum theory to subjects of current interest and to demonstrate the connections between various scientific fields which are provided through rotations. Includes Mathematica and C language programs.
Fundamentals of Molecular Symmetry
| Author | : P.R. Bunker |
| Publisher | : CRC Press |
| Total Pages | : 358 |
| Release | : 2018-10-03 |
| Genre | : Science |
| ISBN | : 0429837003 |
Winner of a 2005 CHOICE Outstanding Academic Book Award Molecular symmetry is an easily applied tool for understanding and predicting many of the properties of molecules. Traditionally, students are taught this subject using point groups derived from the equilibrium geometry of the molecule. Fundamentals of Molecular Symmetry shows how to set up symmetry groups for molecules using the more general idea of energy invariance. It is no more difficult than using molecular geometry and one obtains molecular symmetry groups. The book provides an introductory description of molecular spectroscopy and quantum mechanics as the foundation for understanding how molecular symmetry is defined and used. The approach taken gives a balanced account of using both point groups and molecular symmetry groups. Usually the point group is only useful for isolated, nonrotating molecules, executing small amplitude vibrations, with no tunneling, in isolated electronic states. However, for the chemical physicist or physical chemist who wishes to go beyond these limitations, the molecular symmetry group is almost always required.
Concepts of Materials Science
| Author | : Adrian P. Sutton |
| Publisher | : Oxford University Press |
| Total Pages | : 150 |
| Release | : 2021-06-30 |
| Genre | : Science |
| ISBN | : 0192661582 |
All technologies depend on the availability of suitable materials. The progress of civilisation is often measured by the materials people have used, from the stone age to the silicon age. Engineers exploit the relationships between the structure, properties and manufacturing methods of a material to optimise their design and production for particular applications. Scientists seek to understand and predict those relationships. This short book sets out fundamental concepts that underpin the science of materials and emphasizes their relevance to mainstream chemistry, physics and biology. These include the thermodynamic stability of materials in various environments, quantum behaviour governing all matter, and active matter. Others include defects as the agents of change in crystalline materials, materials at the nanoscale, the emergence of new science at increasing length scales in materials, and man-made materials with properties determined by their structure rather than their chemistry. The book provides a unique insight into the essence of materials science at a level suitable for pre-university students and undergraduates of materials science. It will also be suitable for graduates in other subjects contemplating postgraduate study in materials science. Professional materials scientists will also find it stimulating and occasionally provocative.
Atomic and Molecular Radiative Processes
| Author | : Vladimir Krainov |
| Publisher | : Springer |
| Total Pages | : 273 |
| Release | : 2019-07-03 |
| Genre | : Science |
| ISBN | : 3030219550 |
This book describes selected problems in contemporary spectroscopy in the context of quantum mechanics and statistical physics. It focuses on elementary radiative processes involving atomic particles (atoms, molecules, ions), which include radiative transitions between discrete atomic states, the photoionization of atoms, photorecombination of electrons and ions, bremsstrahlung, photodissociation of molecules, and photoattachment of electrons to atoms. In addition to these processes, the transport of resonant radiation in atomic gases and propagation of infrared radiation in molecular gases are also considered. The book subsequently addresses applied problems such as optical pumping, cooling of gases via laser resonance radiation, light-induced drift of gas atoms, photoresonant plasma, reflection of radio waves from the ionosphere, and detection of submillimeter radiation using Rydberg atoms. Lastly, topical examples in atmospheric and climate change science are presented, such as lightning channel glowing, emission of the solar photosphere, and the greenhouse phenomenon in the atmospheres of the Earth and Venus. Along with researchers, both graduate and undergraduate students in atomic, molecular and atmospheric physics will find this book a useful and timely guide.
The Physics of Low-dimensional Semiconductors
| Author | : John H. Davies |
| Publisher | : Cambridge University Press |
| Total Pages | : 460 |
| Release | : 1998 |
| Genre | : Science |
| ISBN | : 9780521484916 |
The composition of modern semiconductor heterostructures can be controlled precisely on the atomic scale to create low-dimensional systems. These systems have revolutionised semiconductor physics, and their impact on technology, particularly for semiconductor lasers and ultrafast transistors, is widespread and burgeoning. This book provides an introduction to the general principles that underlie low-dimensional semiconductors. As far as possible, simple physical explanations are used, with reference to examples from actual devices. The author shows how, beginning with fundamental results from quantum mechanics and solid-state physics, a formalism can be developed that describes the properties of low-dimensional semiconductor systems. Among numerous examples, two key systems are studied in detail: the two-dimensional electron gas, employed in field-effect transistors, and the quantum well, whose optical properties find application in lasers and other opto-electronic devices. The book includes many exercises and will be invaluable to undergraduate and first-year graduate physics or electrical engineering students taking courses in low-dimensional systems or heterostructure device physics.
Physics of the Interstellar and Intergalactic Medium
| Author | : Bruce T. Draine |
| Publisher | : Princeton University Press |
| Total Pages | : 568 |
| Release | : 2011 |
| Genre | : Science |
| ISBN | : 0691122148 |
An essential resource for graduate students and astrophysicists This is a comprehensive and richly illustrated textbook on the astrophysics of the interstellar and intergalactic medium—the gas and dust, as well as the electromagnetic radiation, cosmic rays, and magnetic and gravitational fields, present between the stars in a galaxy and also between galaxies themselves. Topics include radiative processes across the electromagnetic spectrum; radiative transfer; ionization; heating and cooling; astrochemistry; interstellar dust; fluid dynamics, including ionization fronts and shock waves; cosmic rays; distribution and evolution of the interstellar medium; and star formation. While it is assumed that the reader has a background in undergraduate-level physics, including some prior exposure to atomic and molecular physics, statistical mechanics, and electromagnetism, the first six chapters of the book include a review of the basic physics that is used in later chapters. This graduate-level textbook includes references for further reading, and serves as an invaluable resource for working astrophysicists. Essential textbook on the physics of the interstellar and intergalactic medium Based on a course taught by the author for more than twenty years at Princeton University Covers radiative processes, fluid dynamics, cosmic rays, astrochemistry, interstellar dust, and more Discusses the physical state and distribution of the ionized, atomic, and molecular phases of the interstellar medium Reviews diagnostics using emission and absorption lines Features color illustrations and detailed reference materials in appendices Instructor's manual with problems and solutions (available only to teachers)
A Textbook of Inorganic Chemistry – Volume 1
| Author | : Mandeep Dalal |
| Publisher | : Dalal Institute |
| Total Pages | : 480 |
| Release | : 2017-01-01 |
| Genre | : Science |
| ISBN | : 8193872002 |
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Magnetism and Superconductivity
| Author | : Laurent-Patrick Levy |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 470 |
| Release | : 2013-06-29 |
| Genre | : Science |
| ISBN | : 3662042711 |
This up-to-date work presents a modern vision of magnetism and superconductivity covering both microscopic and phenomenological aspects. The basic information is illustrated with the help of current research topics such as the quantum Hall effect or mesoscopic aspects of superconductivity.
