One Electron Transfer Reactions Of Low Valent Transition Metal Complexes
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Redox-Active Ligands
Author | : Marine Desage-El Murr |
Publisher | : John Wiley & Sons |
Total Pages | : 373 |
Release | : 2024-01-31 |
Genre | : Science |
ISBN | : 352783088X |
Redox-Active Ligands Authoritative resource showcasing a new family of ligands that can lead to better catalysts and promising applications in organic synthesis Redox-Active Ligands gives a comprehensive overview of the unique features of redox-active ligands, describing their structure and synthesis, the characterization of their coordination complexes, and important applications in homogeneous catalysis. The work reflects the diversity of the subject by including ongoing research spanning coordination chemistry, organometallic chemistry, bioinspired catalysis, proton and electron transfer, and the ability of such ligands to interact with early and late transition metals, lanthanides, and actinides. The book is divided into three parts, devoted to introduction and concepts, applications, and case studies. After the introduction on key concepts related to the field, and the different types of ligands and complexes in which ligand-centered redox activity is commonly observed, mechanistic and computational studies are described. The second part focuses on catalytic applications of redox-active complexes, including examples from radical transformations, coordination chemistry and organic synthesis. Finally, case studies of redox-active guanidine ligands, and of lanthanides and actinides are presented. Other specific sample topics covered include: An overview of the electronic features of redox-active ligands, covering their historical perspective and biological background The versatility and mode of action of redox-active ligands, which sets them apart from more classic and tunable ligands such as phosphines or N-heterocyclic carbenes Preparation and catalytic applications of complexes of stable N-aryl radicals Metal complexes with redox-active ligands in H+/e- transfer transformations By providing up-to-date information on important concepts and applications, Redox-Active Ligands is an essential reading for researchers working in organometallic and coordination chemistry, catalysis, organic synthesis, and (bio)inorganic chemistry, as well as newcomers to the field.
Electron Transfer Reactions of Complex Ions in Solution
Author | : Henry Taube |
Publisher | : Elsevier |
Total Pages | : 113 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0323161138 |
Electron Transfer Reactions of Complex Ions in Solution covers the significant development of some important area of electron transfer reactions of complex ions. This four-chapter book emerged from a series of lectures at the Polytechnic Institute of Brooklyn in November and December 1967. Chapter I presents research studies in cation hydration. This chapter describes principal methods for composition determination of the first coordination spheres of the aquo ions. Chapter II examines the distinction between reactions in which electron transfer takes place from one primary bond system to another. Chapter III discusses some aspects of ligand effects in electron-transfer reactions. This chapter demonstrates that differences in the behavior of systems can be expected at least in the extremes of mechanisms. Chapter IV deals with the history, principles and applications of the induced electron-transfer effect. This book is of great value to electrochemists, students, and researchers.
Induced Electron Transfer in Systems of Transition Metal Ions and Complexes
Author | : Mary Ellen Foley |
Publisher | : |
Total Pages | : 132 |
Release | : 1982 |
Genre | : Cobalt compounds |
ISBN | : |
Substitution and Excited State Electron Transfer Reactions of Transition Metal Complexes in Organized Media
Author | : Russell Hunter Schmehl |
Publisher | : |
Total Pages | : 446 |
Release | : 1980 |
Genre | : Charge transfer |
ISBN | : |
The Organometallic Chemistry of the Transition Metals
Author | : Robert H. Crabtree |
Publisher | : John Wiley & Sons |
Total Pages | : 600 |
Release | : 2005-06-14 |
Genre | : Science |
ISBN | : 0471718750 |
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Excited-state Electron-transfer Reactions of Transition Metal Complexes
Author | : David Gordon Taylor |
Publisher | : |
Total Pages | : 232 |
Release | : 1979 |
Genre | : Excited state chemistry |
ISBN | : |