Flexible Polymer Chains in Elongational Flow

Flexible Polymer Chains in Elongational Flow
Author: Tuan Q. Nguyen
Publisher: Springer Science & Business Media
Total Pages: 413
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 3642582524

The behavior of polymer solutions in simple shear flows has been the subject of considerable research in the past. On the other hand, reports on polymers in elongational flow have appeared comparatively recently in the literature. Elongational flow with an inherent low vorticity is known to be more effective in extending polymer chains than simple shear flow and thus is more interesting from the point of view of basic (molecular chain dynamics at high deformation) and applied polymer science (rheology, fiber extrusion, drag reduction, flow through porous media). Undoubtly, one landmark in the field of polymer dynamics in elongational flow was the notion of critical strain-rate for chain extension, initially put forward by A. Peterlin (1966) and later refined into the "coil-stretching" transition by P. G. de Gennes and H. Hinch (1974). In the two decades which followed, significant progress in the understanding of chain conformation in "strong" flow has been accomplished through a combination of advances in instrumentation, computation techniques and theoretical studies. As a result of the multidisciplinary nature of the field, information on polymer chains in "strong" flow is accessible only from reviews and research papers scattered in disparate scientific journals. An important objective of this book is to remedy that situation by providing the reader with up-to-date knowledge in a single volume. The editors therefore invited leading specialists to provide both fundamental and applied information on the multiple facets of chain deformation in elongational flow.

Polymer Mechanochemistry

Polymer Mechanochemistry
Author: Roman Boulatov
Publisher: Springer
Total Pages: 443
Release: 2015-10-17
Genre: Technology & Engineering
ISBN: 3319228250

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

Polymer Solutions

Polymer Solutions
Author: Iwao Teraoka
Publisher: John Wiley & Sons
Total Pages: 355
Release: 2004-04-07
Genre: Science
ISBN: 0471460761

Polymer Solutions: An Introduction to Physical Properties offers a fresh, inclusive approach to teaching the fundamentals of physical polymer science. Students, instructors, and professionals in polymer chemistry, analytical chemistry, organic chemistry, engineering, materials, and textiles will find Iwao Teraoka’s text at once accessible and highly detailed in its treatment of the properties of polymers in the solution phase. Teraoka’s purpose in writing Polymer Solutions is twofold: to familiarize the advanced undergraduate and beginning graduate student with basic concepts, theories, models, and experimental techniques for polymer solutions; and to provide a reference for researchers working in the area of polymer solutions as well as those in charge of chromatographic characterization of polymers. The author’s incorporation of recent advances in the instrumentation of size-exclusion chromatography, the method by which polymers are analyzed, renders the text particularly topical. Subjects discussed include: Real, ideal, Gaussian, semirigid, and branched polymer chains Polymer solutions and thermodynamics Static light scattering of a polymer solution Dynamic light scattering and diffusion of polymers Dynamics of dilute and semidilute polymer solutions Study questions at the end of each chapter not only provide students with the opportunity to test their understanding, but also introduce topics relevant to polymer solutions not included in the main text. With over 250 geometrical model diagrams, Polymer Solutions is a necessary reference for students and for scientists pursuing a broader understanding of polymers.

Liquid Crystal Elastomers

Liquid Crystal Elastomers
Author: Mark Warner
Publisher: Oxford University Press
Total Pages: 423
Release: 2007-04-05
Genre: Mathematics
ISBN: 9780199214860

This text is a primer for liquid crystals, polymers, rubber and elasticity. It is directed at physicists, chemists, material scientists, engineers and applied mathematicians at the graduate student level and beyond.

The Physics of Deformation and Fracture of Polymers

The Physics of Deformation and Fracture of Polymers
Author: A. S. Argon
Publisher: Cambridge University Press
Total Pages: 535
Release: 2013-03-07
Genre: Science
ISBN: 0521821843

A physical, mechanism-based presentation of the plasticity and fracture of polymers, covering industrial scale applications through to nanoscale biofluidic devices.

Innovative Polymeric Adsorbents

Innovative Polymeric Adsorbents
Author: Kyoichi Saito
Publisher: Springer
Total Pages: 193
Release: 2018-04-05
Genre: Technology & Engineering
ISBN: 9811085633

This book presents the reader with a story-based narrative of discovery and development of radiation-induced graft polymerization. The report presented here accomplishes this by relating the inspiring account of research and development based on long-term collaboration among a professor, an engineer, and an entrepreneur. Their goal, ultimately successful, was to come up with a method for grafting functional polymer chains onto existing trunk polymers. The desired outcome was to produce feasible forms for practical use as adsorbents such as porous hollow-fiber membranes, porous sheets, nonwoven fabrics, and fibers. Adsorbents that specifically and efficiently bind to target ions and molecules are essential for capturing uranium species in seawater and antibody drugs in biological fluids and for removing metal ions from ultrapure water and radioactive cesium ions from contaminated water. This unique volume, with its clearly written text and many illustrative figures and diagrams, demonstrates the advantages of the high-adsorption capacity and rate and the easy handling of new polymeric adsorbents over conventional adsorbents. The dynamic behavior of graft chains as described here is certain to appeal especially to chemists, physicists, and material scientists as well as to other readers with an interest in this valuable subject.

Single Polymer Chain Elongation by Atomic Force Microscopy

Single Polymer Chain Elongation by Atomic Force Microscopy
Author: Jason Bemis
Publisher:
Total Pages: 37
Release: 1998
Genre:
ISBN:

We have investigated the elastic deformation of single polystyrene-b-poly-2-vinyl-pyridine chains from spun cast films by Atomic Force Microscopy (AFM). A non-linear elastic response is shown to be present hundreds of nanometers above the bulk surface. The length of the elastic response monotonically increases with molecular weight of the polymer. These non-linear elastic responses are fit to worm like chain (WLC) and freely joined chain (FJC) models giving persistence and Kuhn lengths of approximately 5A. The entropic models reveal that the polymer chains are stretched to 80-90% of their contour length before the attachment to the tip is ruptured.

Constitutive Models for Rubber

Constitutive Models for Rubber
Author: Al Dorfmann
Publisher: CRC Press
Total Pages: 334
Release: 1999-01-01
Genre: Technology & Engineering
ISBN: 9789058091130

This text aims to enable the experience accumulated by engineers and the research community in materials science, continuum mechanics and applied mathematics to be shared. In this way, the design and analysis of rubber components using the Finite Element Method should be enhanced.