Non-Noble Metal Catalysis

Non-Noble Metal Catalysis
Author: Robertus J. M. Klein Gebbink
Publisher: John Wiley & Sons
Total Pages: 610
Release: 2019-04-29
Genre: Technology & Engineering
ISBN: 3527340610

An expert overview of current research, applications, and economic and environmental advantages The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals?enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental concepts and computational methods to industrial applications and reaction classes. Recognized experts in organometallic chemistry and homogeneous catalysis, the authors present a comprehensive overview of the conceptual and practical aspects of non-noble metal catalysts. Examination of topics including non-innocent ligands, proton-coupled electron transfer, and multi-nuclear complexes provide essential background information, while areas such as kinetic lability and lifetimes of intermediates reflect current research and shifting trends in the field. This timely book demonstrates the efficacy of base metal catalysts in the pharmaceutical, fine-chemical, and agrochemical industries, addressing both environmental and economic concerns. Providing essential conceptual and practical exploration, this valuable resource: -Illustrates how unravelling new reactivity patterns can lead to new catalysts and new applications -Highlights the multiple advantages of using non-noble metals in homogenous catalysis -Demonstrates how the availability of non-noble metal catalysis reduces costs and leads to immense savings for the chemical industry -Reveals how non-noble metal catalysis are more sustainable than noble metals such as palladium or platinum Non-Noble Metal Catalysis: Molecular Approaches and Reactions is an indispensable source of up-to-date information for catalytic chemists, organic chemists, industrial chemists, organometallic chemists, and those seeking to broaden their knowledge of catalytic chemistry.

Oxide Surfaces

Oxide Surfaces
Author:
Publisher: Elsevier
Total Pages: 677
Release: 2001-05-21
Genre: Science
ISBN: 0080538312

The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.

Noble and Precious Metals

Noble and Precious Metals
Author: Mohindar Seehra
Publisher: BoD – Books on Demand
Total Pages: 432
Release: 2018-07-04
Genre: Technology & Engineering
ISBN: 1789232929

The use of copper, silver, gold and platinum in jewelry as a measure of wealth is well known. This book contains 19 chapters written by international authors on other uses and applications of noble and precious metals (copper, silver, gold, platinum, palladium, iridium, osmium, rhodium, ruthenium, and rhenium). The topics covered include surface-enhanced Raman scattering, quantum dots, synthesis and properties of nanostructures, and its applications in the diverse fields such as high-tech engineering, nanotechnology, catalysis, and biomedical applications. The basis for these applications is their high-free electron concentrations combined with high-temperature stability and corrosion resistance and methods developed for synthesizing nanostructures. Recent developments in all these areas with up-to-date references are emphasized.

Fuel Cells: Technologies for Fuel Processing

Fuel Cells: Technologies for Fuel Processing
Author: Dushyant Shekhawat
Publisher: Elsevier
Total Pages: 569
Release: 2011-03-18
Genre: Technology & Engineering
ISBN: 0444535640

Fuel Cells: Technologies for Fuel Processing provides an overview of the most important aspects of fuel reforming to the generally interested reader, researcher, technologist, teacher, student, or engineer. The topics covered include all aspects of fuel reforming: fundamental chemistry, different modes of reforming, catalysts, catalyst deactivation, fuel desulfurization, reaction engineering, novel reforming concepts, thermodynamics, heat and mass transfer issues, system design, and recent research and development. While no attempt is made to describe the fuel cell itself, there is sufficient description of the fuel cell to show how it affects the fuel reformer. By focusing on the fundamentals, this book aims to be a source of information now and in the future. By avoiding time-sensitive information/analysis (e.g., economics) it serves as a single source of information for scientists and engineers in fuel processing technology. The material is presented in such a way that this book will serve as a reference for graduate level courses, fuel cell developers, and fuel cell researchers. - Chapters written by experts in each area - Extensive bibliography supporting each chapter - Detailed index - Up-to-date diagrams and full colour illustrations

Supported Metals in Catalysis

Supported Metals in Catalysis
Author: James Arthur Anderson
Publisher: World Scientific
Total Pages: 581
Release: 2012
Genre: Science
ISBN: 184816677X

With contributions from experts in supported metal catalysis, from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to a thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as Naphtha reforming, the book also includes emerging areas where supported metal catalysis will make significant contributions in future developments, such as fuel cells and fine chemicals synthesis. The second edition of Supported Metals in Catalysis comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter, and as such, it is a must-have for anyone working in the field of heterogeneous catalysis.

Non-Noble Metal Fuel Cell Catalysts

Non-Noble Metal Fuel Cell Catalysts
Author: Zhongwei Chen
Publisher: John Wiley & Sons
Total Pages: 448
Release: 2014-04-03
Genre: Technology & Engineering
ISBN: 3527664920

Written and edited by top fuel cell catalyst scientists and engineers from both industry and academia, this is the first book to provide a complete overview of this hot topic. It covers the synthesis, characterization, activity validation and modeling of different non-noble metal electrocatalysts, as well as their integration into fuel cells and their performance validation, while also discussing those factors that will drive fuel cell commercialization. With its well-structured approach, this is a must-have for researchers working on the topic, and an equally valuable companion for newcomers to the field.

Catalysis By Gold

Catalysis By Gold
Author: Geoffrey C Bond
Publisher: World Scientific
Total Pages: 383
Release: 2006-08-15
Genre: Science
ISBN: 1908979852

Gold has traditionally been regarded as inactive as a catalytic metal. However, the advent of nanoparticulate gold on high surface area oxide supports has demonstrated its high catalytic activity in many chemical reactions. Gold is active as a heterogeneous catalyst in both gas and liquid phases, and complexes catalyse reactions homogeneously in solution. Many of the reactions being studied will lead to new application areas for catalysis by gold in pollution control, chemical processing, sensors and fuel cell technology. This book describes the properties of gold, the methods for preparing gold catalysts and ways to characterise and use them effectively in reactions. The reaction mechanisms and reasons for the high activities are discussed and the applications for gold catalysis considered./a

CO2 Hydrogenation Catalysis

CO2 Hydrogenation Catalysis
Author: Yuichiro Himeda
Publisher: John Wiley & Sons
Total Pages: 322
Release: 2021-06-28
Genre: Technology & Engineering
ISBN: 3527346635

A guide to the effective catalysts and latest advances in CO2 conversion in chemicals and fuels Carbon dioxide hydrogenation is one of the most promising and economic techniques to utilize CO2 emissions to produce value-added chemicals. With contributions from an international team of experts on the topic, CO2 Hydrogenation Catalysis offers a comprehensive review of the most recent developments in the catalytic hydrogenation of carbon dioxide to formic acid/formate, methanol, methane, and C2+ products. The book explores the electroreduction of carbon dioxide and contains an overview on hydrogen production from formic acid and methanol. With a practical review of the advances and challenges in future CO2 hydrogenation research, the book provides an important guide for researchers in academia and industry working in the field of catalysis, organometallic chemistry, green and sustainable chemistry, as well as energy conversion and storage. This important book: Offers a unique review of effective catalysts and the latest advances in CO2 conversion Explores how to utilize CO2 emissions to produce value-added chemicals and fuels such as methanol, olefins, gasoline, aromatics Includes the latest research in homogeneous and heterogeneous catalysis as well as electrocatalysis Highlights advances and challenges for future investigation Written for chemists, catalytic chemists, electrochemists, chemists in industry, and chemical engineers, CO2 Hydrogenation Catalysis offers a comprehensive resource to understanding how CO2 emissions can create value-added chemicals.

Volatile Organic Compounds in the Atmosphere

Volatile Organic Compounds in the Atmosphere
Author: R M Harrison
Publisher: Royal Society of Chemistry
Total Pages: 156
Release: 2007-10-31
Genre: Science
ISBN: 1847552315

Interest in volatile organic compounds (VOCs) as air pollutants has increased dramatically in recent years. This book covers a number of very topical issues concerning VOCs, including stratospheric ozone depletion due to CFCs, and the properties of alternative substances; the role of VOCs in the photochemical formation of lower atmosphere (tropospheric) ozone; and the problem of the direct toxicity of VOCs such as benzene and formaldehyde. This Issue reviews our current knowledge of VOCs, drawing upon the expertise of renowned experts and major national and international research programmes. It examines man-made and natural sources, as well as pathways and chemical reactions in the atmosphere. It also looks closely at the sources and concentrations of VOCs indoors, where humans are most likely to be exposed to them. Volatile Organic Compounds in the Atmosphere describes techniques used for the calculation of emissions inventories and strategies for control, and explores the many Government policy matters relating to VOCs. It provides readers with in-depth, clearly explained coverage of the many complex scientific and policy issues surrounding VOCs in the atmosphere.

Novel Non-Precious Metal Electrocatalysts for Oxygen Electrode Reactions

Novel Non-Precious Metal Electrocatalysts for Oxygen Electrode Reactions
Author: Hui Yang
Publisher: MDPI
Total Pages: 190
Release: 2019-11-01
Genre: Science
ISBN: 303921540X

Research on alternative energy harvesting technologies, conversion and storage systems with high efficiency, cost-effective and environmentally friendly systems, such as fuel cells, rechargeable metal-air batteries, unitized regenerative cells, and water electrolyzers has been stimulated by the global demand on energy. The conversion between oxygen and water plays a key step in the development of oxygen electrodes: oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), processes activated mostly by precious metals, like platinum. Their scarcity, their prohibitive cost, and declining activity greatly hamper large-scale applications. This issue reports on novel non-precious metal electrocatalysts based on the innovative design in chemical compositions, structure, and morphology, and supports for the oxygen reaction.