Non Aqueous Solutions
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| Author | : Kosuke Izutsu |
| Publisher | : John Wiley & Sons |
| Total Pages | : 432 |
| Release | : 2009-09-22 |
| Genre | : Science |
| ISBN | : 9783527629169 |
An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
| Author | : Victor Gutmann |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 181 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 3709181941 |
Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.
| Author | : Ludwig Frederick Audrieth |
| Publisher | : |
| Total Pages | : 304 |
| Release | : 1953 |
| Genre | : Solvents |
| ISBN | : |
| Author | : C Westcott |
| Publisher | : Elsevier |
| Total Pages | : 185 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0323160603 |
pH Measurements is a seven-chapter simplified text on obtaining a high degree of accuracy in practical pH measurement. The introductory chapter of this book relates the principles of pH measurements to the actual measurement. This chapter specifically tackles the factors involved in the measurement and what magnitude of effect does each factor have on the measurement. These topics are followed by discussions on the components of pH equipment and technique, including the electrodes and buffers. A chapter considers the general approach of pH measurements and illustrates with examples of some common difficult samples. The concluding chapter shows the isolation and correction a pH equipment malfunction. pH equipment operators and users will find this book rewarding.
| Author | : K. Burger |
| Publisher | : Elsevier |
| Total Pages | : 269 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0444597514 |
Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.
| Author | : B. Trémillon |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 291 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 9401021236 |
Arising no doubt from its pre-eminence as a natural liquid, water has always been considered by chemists as the original solvent in which very varied chemical reactions can take place, both for preparational and for analytical purposes. This explains the very long-standing interest shown in the study of aqueous solutions. In this con nection, it must be stressed that the theory of Arrhenius and Ostwald (1887-1894) on electrolytic dissociation, was originally devised solely for solutions in water and that the first true concept of acidity resulting from this is linked to the use of this solvent. The more recent development of numerous physico-chemical measurement methods has made possible an increase of knowledge in this area up to an extremely advanced degree of systematization. Thus today we have available both a very large amount of experimental data, together with very refined methods of deduction and of quantitative treatment of chemical reactions in solution which enable us to make the fullest use of this data. Nevertheless, . it appears quite evident at present that there are numerous chemical processes which cannot take place in water, and that its use as a solvent imposes 2 INTRODUCTION limitations. In order to overcome these limitations, it was natural that interest should be attracted to solvents other than water and that the new possibilities thus opened up should be explored.
| Author | : J. B. Gill |
| Publisher | : Elsevier |
| Total Pages | : 131 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483155714 |
Non-Aqueous Solutions — 5 is a collection of lectures presented at the Fifth International Conference on Non-Aqueous Solutions held in Leeds, England, on July 5-9, 1976. The papers explore reactions in non-aqueous solutions as well as the thermodynamic and kinetic properties of non-aqueous solutions. Examples of the use of spectroscopic techniques are presented, and solutions in molten salts are given. Metals in solution and liquid metal solutions are also considered. This book is comprised of 12 chapters and begins with a review of a general scheme which considers the species formed by cation-electron and electron-electron interactions at dilute to moderate concentrations, along with the influence of the solvent and the metal on these interactions. The discussion then shifts to the application of electron spin resonance spectroscopy to the study of solvation; the influence of solvent properties on ligand substitution mechanisms of labile complexes; and the effect of acidity on chemical reactions in molten salts. Subsequent chapters deal with the chemistry of solutions of salts in liquid alkali metals; preferential solvation in kinetics; and the use of non-aqueous solvents for preparation and reactions of nitrogen halogen compounds. Results of Raman spectroscopic studies of non-aqueous solutions and spectroscopic studies of coordination compounds formed in molten salts are also presented. This monograph will be of interest to chemists.
| Author | : Peter Stilbs |
| Publisher | : Walter de Gruyter GmbH & Co KG |
| Total Pages | : 462 |
| Release | : 2019-08-19 |
| Genre | : Technology & Engineering |
| ISBN | : 3110551659 |
Diffusion and Eletrophoretic NMR experiments resolve chemical compounds based on their molecular motion. This publication introduces the basics of these methods and explains how they can be used to measure the size of molecules and aggregates, to determine degree of polymerization and to solve other chemical problems. Supplied with many case studies, the book is a must-have for students and researchers who work with practical NMR measurements.
| Author | : Thomas Cudworth Waddington |
| Publisher | : |
| Total Pages | : 594 |
| Release | : 1965 |
| Genre | : Nonaqueous solvents |
| ISBN | : |
| Author | : Azariah Thomas Lincoln |
| Publisher | : |
| Total Pages | : 92 |
| Release | : 1899 |
| Genre | : Electrolytes |
| ISBN | : |
