Nitrenes
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Author | : Eric Scriven |
Publisher | : Elsevier |
Total Pages | : 557 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0323146236 |
Azides and Nitrenes: Reactivity and Utility provides information pertinent to the fundamentals aspects of the chemistry of azides and nitrenes. This book discusses the mechanism and synthetic applications of alkyl azides. Organized into 10 chapters, this book begins with an overview of the properties and chemistry of alkyl azides and alkylnitrenes. This text then examines the various pathways to the preparation of vinyl azides. Other chapters consider the magnetic resonance spectrum of phenyl azide, which may be taken as a representative to which more complex examples can be related. This book discusses as well the acyl azides and acylnitrenes that have their nitrogen function attached to electron-withdrawing groups not possessing a heteroatom bearing an unshared electron pair next to the nitrogen function. The final chapter deals with the main uses for organic azides involved in photochemical cross-linking of polymeric systems. This book is a valuable resource for chemists, spectroscopists, and theoreticians.
Author | : Michael P. Doyle |
Publisher | : Springer Nature |
Total Pages | : 381 |
Release | : 2023-08-09 |
Genre | : Science |
ISBN | : 3031367359 |
This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.
Author | : Walter Lwowski |
Publisher | : |
Total Pages | : 490 |
Release | : 1970 |
Genre | : Science |
ISBN | : |
Author | : Daniel E. Falvey |
Publisher | : John Wiley & Sons |
Total Pages | : 598 |
Release | : 2013-04-10 |
Genre | : Science |
ISBN | : 1118560876 |
Featuring contributions respected leaders in the field, Nitrene and Nitrenium Ions is the first comprehensive book to explore the role of reactive intermediate nitrene and nitrenium ions in chemistry and biochemistry. Covering a broad range of topics, including ultrafast studies, computational studies, behavior in aqueous solution, electronic structures, and reactions with aromatic compounds, this valuable resource will empower graduate students and researchers to better understand and expand their synthetic utility.
Author | : Madan R.L. |
Publisher | : S. Chand Publishing |
Total Pages | : 486 |
Release | : |
Genre | : Science |
ISBN | : 9352533038 |
This textbook has been designed to meet the needs of B.Sc. First Semester students of Chemistry as per the new UGC Model Curriculum - Choice Based Credit System (CBCS). With its traditional approach to the subject, this textbook lucidly explains principles of chemistry. Important topics such as atomic structure, chemical bonding, molecular structure, fundamentals of organic chemistry, stereochemistry and aliphatic hydrocarbons are aptly discussed to give an overview of inorganic and organic chemistry. Laboratory work has also been included to help students achieve solid conceptual understanding and learn experimental procedures.
Author | : Michael B. Smith |
Publisher | : John Wiley & Sons |
Total Pages | : 2146 |
Release | : 2020-02-19 |
Genre | : Science |
ISBN | : 1119371805 |
The completely revised and updated, definitive resource for students and professionals in organic chemistry The revised and updated 8th edition of March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure explains the theories of organic chemistry with examples and reactions. This book is the most comprehensive resource about organic chemistry available. Readers are guided on the planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions The opening chapters of March's Advanced Organic Chemistry, 8th Edition deal with the structure of organic compounds and discuss important organic chemistry bonds, fundamental principles of conformation, and stereochemistry of organic molecules, and reactive intermediates in organic chemistry. Further coverage concerns general principles of mechanism in organic chemistry, including acids and bases, photochemistry, sonochemistry and microwave irradiation. The relationship between structure and reactivity is also covered. The final chapters cover the nature and scope of organic reactions and their mechanisms. This edition: Provides revised examples and citations that reflect advances in areas of organic chemistry published between 2011 and 2017 Includes appendices on the literature of organic chemistry and the classification of reactions according to the compounds prepared Instructs the reader on preparing and conducting multi-step synthetic reactions, and provides complete descriptions of each reaction The 8th edition of March's Advanced Organic Chemistry proves once again that it is a must-have desktop reference and textbook for every student and professional working in organic chemistry or related fields. Winner of the Textbook & Acadmic Authors Association 2021 McGuffey Longevity Award.
Author | : |
Publisher | : Academic Press |
Total Pages | : 439 |
Release | : 1992-08-17 |
Genre | : Science |
ISBN | : 0080576400 |
Advances in Heterocyclic Chemistry
Author | : Metin Balcı |
Publisher | : John Wiley & Sons |
Total Pages | : 644 |
Release | : 2021-12-01 |
Genre | : Science |
ISBN | : 3527349642 |
An accessible and step-by-step exploration of organic reaction mechanisms In Reaction Mechanisms in Organic Chemistry, eminent researcher Dr. Metin Balci delivers an excellent textbook for understanding organic reaction mechanisms. The book offers a way for undergraduate and graduate students to understand???rather than memorize???the principles of reaction mechanisms. It includes the most important reaction types, including substitution, elimination, addition, pericyclic, and C-C coupling reactions. Each chapter contains problems and accompanying solutions that cover central concepts in organic chemistry. Students will learn to understand the foundational nature of ideas like Lewis acids and bases, electron density, the mesomeric effect, and the inductive effect via the use of detailed examples and an expansive discussion of the concept of hybridization. Along with sections covering aromaticity and the chemistry of intermediates, the book includes: A thorough introduction to basic concepts in organic reactions, including covalent bonding, hybridization, electrophiles and nucleophiles, and inductive and mesomeric effects Comprehensive explorations of nucleophilic substitution reactions, including optical activity and stereochemistry of SN2 reactions Practical discussions of elimination reactions, including halogene elimination and Hofmann elimination In-depth examinations of addition reactions, including the addition of water to alkenes and the epoxidation of alkenes Perfect for students of chemistry, biochemistry, and pharmacy, Reaction Mechanisms in Organic Chemistry will also earn a place in the libraries of researchers and lecturers in these fields seeking a one-stop resource on organic reaction mechanisms.
Author | : Stefan Bräse |
Publisher | : John Wiley & Sons |
Total Pages | : 537 |
Release | : 2010-02-01 |
Genre | : Science |
ISBN | : 0470519983 |
Most current state-of-the-art overview of this important class of compounds, encompassing many new and emerging applications The number of articles on organic azides continues to increase tremendously; on average, there are more than 1000 new publications a year Covers basic chemistry as well as state-of-the-art applications in life science and materials science World-ranked authors describe their own research in the wider context of azide chemistry Includes a chapter on safe synthesis and handling (azides can decompose explosively)
Author | : Madan R.L. |
Publisher | : S. Chand Publishing |
Total Pages | : 982 |
Release | : 2022 |
Genre | : |
ISBN | : 8194771781 |
An outgrowth of more than three decades of classroom teaching experience, this book provides a comprehensive treatment of the subject. It comprises three parts; Inorganic, Organic and Physical Chemistry. Illustrations and diagrams are provided to help students in understanding the chemical structures and reactions. This book will meet the requirements of undergraduate students of B.Sc. First Year of all Indian universities.