Nanostructured Silica Aerogel
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| Author | : Pradip B. Sarawade |
| Publisher | : LAP Lambert Academic Publishing |
| Total Pages | : 220 |
| Release | : 2011-01 |
| Genre | : |
| ISBN | : 9783844301168 |
In recent years, interest in the preparation and characterization of the na-noporous materials has grown due to their distinctive properties and potential applications. Among them, silica aerogel are transparent, highly porous and lightest synthetic solids. Silica aerogels, prepared by sol-gel method followed by supercritical drying, have various extraordinary properties viz. low density ( 20 mg/cm3) and thermal conductivity (0.05 W/mK), low sound velocity ( 100 m/s) and large surface area (> 1500 m2/g). Due to this unique combination of properties, aerogels are considered as a new class solid state porous material having various scientific and technological applications like super insulating transparent fillers in double walled windows, catalytic supports, Cerenkov detectors, filters and containers for capturing of micrometeorites in space. However, economic large-scale industrial production of silica aerogels is hampered by expensive supercritical drying methods. The present book describes the results of detailed studies made on the synthesis and characterization of silica aerogels and related nano-porous materials by various methods and precursors at ambient pressure.
| Author | : Cinzia Buratti |
| Publisher | : |
| Total Pages | : 0 |
| Release | : 2019 |
| Genre | : Aerogels |
| ISBN | : 9781536153293 |
Silica translucent aerogels are unique materials able to improve the thermal insulation performance of buildings without compromising daylight transmission. The aim of the book is to give a general overview on state of the art research on translucent aerogels and their applications in buildings and to provide a data set about thermal and physical properties, useful in buildings' energy performance simulation and design.Silica aerogels are nanostructured solid materials made of approximately 96% air and 4% silica. They show a thermal conductivity in the 0.012-0.020 W/mK range and excellent optical properties, especially visible transmission. They come in granular and monolithic form. Granular aerogels are relatively easy to produce and less expensive than monolithic panes, but show worse optical and thermal performance. Monolithic aerogels enable vision through the material, but their fabrication process is not developed at an industrial scale.The book collects the contributions of experts in the field of translucent aerogels from all over the world. The contents of the eight chapters are detailed as follows:Chapter 1 is the contribution from Union College, Schenectady (USA). The chapter reviews the chemical approaches to silica wet gels preparation, the drying methods used to yield monoliths, and the challenges and limitations associated with its production.Chapter 2 is a contribution from EMPA, Dübendorf (Switzerland). It is a review of current state of the art research on silica aerogel granulate production, including raw materials selection, hydrophobization strategies, and drying methodologies. Chapter 3 is a contribution from Takenaka Corporation, Tokyo (Japan). The main techniques for the optical properties evaluation are described and data are provided. An original application of translucent aerogels in buildings and future research topics are also proposed.Chapter 4 is a contribution from Recep Tayyip Erdogan University, Rize and Ataturk University, Erzurum (Turkey). A review of the thermal properties of aerogels is provided, highlighting their better performance when compared to conventional and superinsulation materials.Chapter 5 is a contribution from the University of Perugia, Perugia (Italy). The acoustic properties of both granular and monolithic systems are investigated. For example, the influence of granule size and layer thickness that is deepened for granular aerogels is discussed, while for the monolithic form, the little data that is currently available is reported on. Chapter 6 is a contribution from the University of Tuscia, Viterbo (Italy) and Buro Happold Ltd, London (UK). It is focused on Life Cycle Assessment of silica aerogel, showing the research challenges in understanding its environmental impact, lower than the one of conventional thermal insulating glazing systems.Chapter 7 is a contribution from the University of Lyon and INSA-Lyon, Lyon (France). An overview of measurement methods and modeling tools available in literature is provided and a summary of the main mechanical properties of both monolithic and granular aerogels is reported on.Chapter 8 is a contribution from the Norwegian University of Science and Technology, Trondheim and SINTEF, Trondheim (Norway). Authors present their experimental investigations on various aerogel systems in different building envelopes (new aerogel glass material, aerogel-incorporated concrete, and so forth).
| Author | : Mahesh Sachithanadam |
| Publisher | : Springer |
| Total Pages | : 149 |
| Release | : 2016-01-13 |
| Genre | : Technology & Engineering |
| ISBN | : 9811004404 |
This book explores the improvement in thermal insulation properties of protein-based silica aerogel composites fabricated by a novel, inexpensive and feasible method. The resulting material exhibits polymeric foam behavior including high compressibility, super-hydrophobic qualities and excellent strain recovery in addition to low thermal conductivity. The fabrication methodologies are explained in great detail and represented in flowcharts for easy reference and understanding. This monograph gives readers a new perspective on composite fabrication using methods other than the traditional ones and explores the endless ways of altering the composition to modify the properties of the silica aerogel composites. Applications for this novel composite are diverse and range from those in the pharmaceutical and aerospace industries to the oil and gas industries.
| Author | : Michel Andre Aegerter |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 929 |
| Release | : 2011-06-10 |
| Genre | : Technology & Engineering |
| ISBN | : 1441975896 |
Aerogels are the lightest solids known. Up to 1000 times lighter than glass and with a density as low as only four times that of air, they show very high thermal, electrical and acoustic insulation values and hold many entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal and ceramic materials, etc. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation and household uses are being developed with an estimated annual market growth rate of around 70% until 2015. The Aerogels Handbook summarizes state-of-the-art developments and processing of inorganic, organic, and composite aerogels, including the most important methods of synthesis, characterization as well as their typical applications and their possible market impact. Readers will find an exhaustive overview of all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and most recent advances towards applications and commercial products, some of which are commercially available today. Key Features: •Edited and written by recognized worldwide leaders in the field •Appeals to a broad audience of materials scientists, chemists, and engineers in academic research and industrial R&D •Covers inorganic, organic, and composite aerogels •Describes military, aerospace, building industry, household, environmental, energy, and biomedical applications among others
| Author | : Aftab Aslam Parwaz Khan |
| Publisher | : Elsevier |
| Total Pages | : 398 |
| Release | : 2021-05-29 |
| Genre | : Science |
| ISBN | : 0128208988 |
Advances in Aerogel Composites for Environmental Remediation presents both contextual information aboutaerogels and details about their application in environmental remediation. A wide variety of aerogels are discussed, rangingfrom common to advanced and from natural to synthetic. By exploring ongoing research and developments in the environmentalremediation technologies using aerogel and its composites, this book addresses common day-to-day environmental problemsand presents solutions to the use of aerogel materials. The chapters discuss fabrication of various aerogel composites, alongwith their design and applications toward different environmental remediation technologies. Additionally, the properties andadvantages of aerogels are compared and contrasted to those of traditional materials. Given the consistent increase in environmental pollution, there is an urgent need to explore new materials for advances in remediationtechnology. Advances in Aerogel Composites for Environmental Remediation brings researchers and practitionersin the fields of environmental remediation, environmental science, and engineering to the forefront of remediation technologieswith a thorough breakdown of the benefits of and techniques relevant to aerogel composites. Covers basic properties, unique properties, and fabrication techniques of aerogels, from basic silica aerogels topresent-day conventional aerogels Discusses most of the major environmental remediation techniques and the advantages of using aerogels for theseremediation techniques in comparison to using traditional methods Presents future prospects for utilizing aerogels in modern day-to-day life and in the fabrication of tangible new products
| Author | : Antonella D'Alessandro |
| Publisher | : CRC Press |
| Total Pages | : 260 |
| Release | : 2020-01-22 |
| Genre | : Medical |
| ISBN | : 1000586901 |
Many books on new smart materials are available, but specialized analysis of particular topics is still in high demand. This multiauthor book focuses on applying nanotechnology to cement-based materials to make numerous engineering applications possible. The addition of novel smart nanofillers allows the development of multifunctional composite materials, not just limited to improving mechanical strength, but also including several enhanced features. Special attention is devoted to types of nano-inclusions, novel techniques to mix components, and analysis of properties that can be achieved by paste, mortar, or concrete if added with nanofillers. Among these properties, the capability of self-sensing is very promising. Moreover, the use of phase-changing materials improves the energy efficiency of nanocomposites, resulting in important applications in engineering. Particular attention is also focused on energy harvesting and electromagnetic shielding properties. Comprehensive and up to date, this is an important reference book that not only provides in-depth information about recent developments and perspectives in this field but also discusses topics that promise major developments in the near future.
| Author | : C. Jeffrey Brinker |
| Publisher | : Academic Press |
| Total Pages | : 925 |
| Release | : 2013-10-22 |
| Genre | : Technology & Engineering |
| ISBN | : 0080571034 |
Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing presents the physical and chemical principles of the sol-gel process. The book emphasizes the science behind sol-gel processing with a chapter devoted to applications. The first chapter introduces basic terminology, provides a brief historical sketch, and identifies some excellent texts for background reading. Chapters 2 and 3 discuss the mechanisms of hydrolysis and condensation for nonsilicate and silicate systems. Chapter 4 deals with stabilization and gelation of sols. Chapter 5 reviews theories of gelation and examines the predicted and observed changes in the properties of a sol in the vicinity of the gel point. Chapter 6 describes the changes in structure and properties that occur during aging of a gel in its pore liquor (or some other liquid). The discussion of drying is divided into two parts, with the theory concentrated in Chapter 7 and the phenomenology in Chapter 8. The structure of dried gels is explored in Chapter 9. Chapter 10 shows the possibility of using the gel as a substrate for chemical reactions or of modifying the bulk composition of the resulting ceramic by performing a surface reaction (such as nitridation) on the gel. Chapter 11 reviews the theory and practice of sintering, describing the mechanisms that govern densification of amorphous and crystalline materials, and showing the advantages of avoiding crystallization before sintering is complete. The properties of gel-derived and conventional ceramics are discussed in Chapter 12. The preparation of films is such an important aspect of sol-gel technology that the fundamentals of film formation are treated at length in Chapter 13. Films and other applications are briefly reviewed in Chapter 14. Materials scientists and researchers in the field of sol-gel processing will find the book invaluable.
| Author | : Lorna J. Gibson |
| Publisher | : Cambridge University Press |
| Total Pages | : 536 |
| Release | : 1997 |
| Genre | : Science |
| ISBN | : 9780521499118 |
In this new edition of their classic work on Cellular Solids, the authors have brought the book completely up to date, including new work on processing of metallic and ceramic foams and on the mechanical, electrical and acoustic properties of cellular solids. Data for commercially available foams are presented on material property charts; two new case studies show how the charts are used for selection of foams in engineering design. Over 150 references appearing in the literature since the publication of the first edition are cited. The text summarises current understanding of the structure and mechanical behaviour of cellular materials, and the ways in which they can be exploited in engineering design. Cellular solids include engineering honeycombs and foams (which can now be made from polymers, metals, ceramics and composites) as well as natural materials, such as wood, cork and cancellous bone.
| Author | : Leslie H. Sperling |
| Publisher | : John Wiley & Sons |
| Total Pages | : 815 |
| Release | : 2015-02-02 |
| Genre | : Technology & Engineering |
| ISBN | : 1119103746 |
An Updated Edition of the Classic Text Polymers constitute the basis for the plastics, rubber, adhesives, fiber, and coating industries. The Fourth Edition of Introduction to Physical Polymer Science acknowledges the industrial success of polymers and the advancements made in the field while continuing to deliver the comprehensive introduction to polymer science that made its predecessors classic texts. The Fourth Edition continues its coverage of amorphous and crystalline materials, glass transitions, rubber elasticity, and mechanical behavior, and offers updated discussions of polymer blends, composites, and interfaces, as well as such basics as molecular weight determination. Thus, interrelationships among molecular structure, morphology, and mechanical behavior of polymers continue to provide much of the value of the book. Newly introduced topics include: Nanocomposites, including carbon nanotubes and exfoliated montmorillonite clays The structure, motions, and functions of DNA and proteins, as well as the interfaces of polymeric biomaterials with living organisms The glass transition behavior of nano-thin plastic films In addition, new sections have been included on fire retardancy, friction and wear, optical tweezers, and more. Introduction to Physical Polymer Science, Fourth Edition provides both an essential introduction to the field as well as an entry point to the latest research and developments in polymer science and engineering, making it an indispensable text for chemistry, chemical engineering, materials science and engineering, and polymer science and engineering students and professionals.
| Author | : Radha R. Gupta |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 649 |
| Release | : 2013-04-17 |
| Genre | : Science |
| ISBN | : 3662077574 |
This advanced text-cum-reference book presents a comprehensive account of the syntheses, reactions, properties and applications of all the most significant classes of heterocyclic compounds. This second volume in the series is an essential tool not only for advanced undergraduates and graduates, but also for academic and industrial researchers in organic, medicinal, pharmaceutical, dye and agricultural chemistry.
